Abstract
Strontium hexaferrite nanowires and nanotubes were synthesized in porous anodic aluminum oxide templates. Different solution-based synthesis techniques (spin coating, vacuum suction, and dip coating) were investigated. Strontium ferrite nanopowders were also synthesized by a similar sol–gel process. The morphology, structure, and composition of the embedded hexaferrite nanostructures were examined by field emission scanning electron microscope, X-ray diffraction, and transmission electron microscopy. Strontium ferrite wires with Fe/Sr ratios from 10 to 12 under different annealing temperatures of 500–700 °C were studied. The results showed that dip coating could produce fine and uniform strontium ferrite nanowires. The ratio of Fe/Sr of 11 and a calcination temperature of 650 °C were found to be optimum conditions. The produced material may be of importance for novel microwave-frequency nanoscale devices.
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Zlatkov B, Nikolic M, Aleksic O, Danninger H, Halwax E (2009) A study of magneto-crystalline alignment in sintered barium hexaferrite fabricated by powder injection molding. J Magn Magn Mater 321(4):330–335
Shang H, Wang J, Liu Q (2007) Synthesis and characterization of nanocrystalline BaFe 12 O 19 obtained by using glucose as a fuel. Mater Sci Eng A 456(1):130–132
Liu X, Wang J, Gan L-M, Ng S-C (1999) Improving the magnetic properties of hydrothermally synthesized barium ferrite. J Magn Magn Mater 195(2):452–459
Ghasemi A, Morisako A, Liu X (2008) Magnetic properties of hexagonal strontium ferrite thick film synthesized by sol–gel processing using SrM nanoparticles. J Magn Magn Mater 320(18):2300–2304
Brito P, Gomes R, Duque J, Macedo M (2006) SrFe12O19 prepared by the proteic sol–gel process. Phys B 384(1):91–93
Garcia RM, Ruiz ER, Rams EE (2001) Structural characterization of low temperature synthesized SrFe12O19. Mater Lett 50(2):183–187
Chaudhury S, Rakshit S, Parida S, Singh Z, Mudher KS, Venugopal V (2008) Studies on structural and thermo-chemical behavior of MFe 12 O 19 (s)(M = Sr, Ba and Pb) prepared by citrate–nitrate gel combustion method. J Alloy Compd 455(1):25–30
Zhong W, Ding W, Zhang N, Hong J, Yan Q, Du Y (1997) Key step in synthesis of ultrafine BaFe 12 O 19 by sol–gel technique. J Magn Magn Mater 168(1):196–202
Yongfei W, Qiaoling L, Cunrui Z, Hongxia J (2009) Preparation and magnetic properties of different morphology nano-SrFe12O19 particles prepared by sol–gel method. J Alloy Compd 467(1):284–287
Pullar RC, Bdikin IK, Bhattacharya AK (2012) Magnetic properties of randomly oriented BaM, SrM, Co2 Y, Co2 Z and Co2 W hexagonal ferrite fibres. J Eur Ceram Soc 32(4):905–913
Liu M, Shen X, Song F, Xiang J, Meng X (2011) Microstructure and magnetic properties of electrospun one-dimensional Al 3+-substituted SrFe12O19 nanofibers. J Solid State Chem 184(4):871–876
Gu F, Pan W, Liu Q, Wang J (2013) Electrospun magnetic SrFe12O19 nanofibres with improved hard magnetism. J Phys D Appl Phys 46(44):445003
Cao G, Liu D (2008) Template-based synthesis of nanorod, nanowire, and nanotube arrays. Adv Colloid Interface Sci 136(1–2):45–64. doi:10.1016/j.cis.2007.07.003
Huczko A (2000) Template-based synthesis of nanomaterials. Appl Phys A 70(4):365–376
Lukatskaya MR, Trusov LA, Eliseev AA, Lukashin AV, Jansen M, Kazin PE, Napolskii KS (2011) Controlled way to prepare quasi-1D nanostructures with complex chemical composition in porous anodic alumina. Chem Commun 47(8):2396–2398
Ebrahimi F, Yazdi SS, Najafabadi MH, Ashrafizadeh F (2015) Influence of nanoporous aluminum oxide interlayer on the optical absorptance of black electroless nickel–phosphorus coating. Thin Solid Films 592(Part A):88–93. doi:10.1016/j.tsf.2015.09.004
Oh HJ, Jang KW, Lee JH, Ki BS, Heo CH, Kwon SH, Chi CS (2006) Effects of annealing treatment of aluminum substrate on nanopore arrangements in anodic alumina. Solid State Phenomena 118:549–554. doi:10.4028/www.scientific.net/SSP.118.549
Liu Y, Wang TJ, Liu Y, Li XJ (2012) Mechanism for synthesizing barium hexagonal ferrite by sol–gel method. Adv Mater Res 549:105–108
Sürig C, Hempel K, Sauer C (1996) Influence of stoichiometry on hexaferrite structure. J Magn Magn Mater 157:268–269
Affleck L, Aguas MD, Parkin IP, Pankhurst QA, Kuznetsov MV (2000) Microstructural aspects of the self-propagating high temperature synthesis of hexagonal barium ferrites in an external magnetic field. J Mater Chem 10(8):1925–1932
Mali A, Ataie A (2005) Influence of Fe/Ba molar ratio on the characteristics of Ba-hexaferrite particles prepared by sol–gel combustion method. J Alloy Compd 399(1):245–250
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Ebrahimi, F., Ashrafizadeh, F., Bakhshi, S.R. et al. Synthesis and structure of strontium ferrite nanowires and nanotubes of high aspect ratio. J Sol-Gel Sci Technol 77, 708–717 (2016). https://doi.org/10.1007/s10971-015-3902-2
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DOI: https://doi.org/10.1007/s10971-015-3902-2