Abstract
Sol–gel derived alumina coating was developed on 9Cr–1Mo ferritic steel and their oxidation behaviour was studied at 750–900 °C in air atmosphere. The elemental composition of the coating was analyzed through energy dispersive X-ray analysis (EDX) while microstructure of the oxidized substrates was examined through scanning electron microscopy. EDX analysis confirmed the presence of alumina in the developed coating. Oxidation kinetics study indicated the occurrence of two orders of magnitude lower oxidation rate constant for the coated substrate as compared to uncoated substrate at 700 and 800 °C. However, an increase in oxidation rate was measured for the coated substrates at 850 °C and above temperature. Microstructural examination of the oxidized substrates indicated that comparatively thin, compact and less porous scale forms at the coated surfaces.
Graphical Abstract
In the present work, sol–gel derived alumina coating developed successfully on 9Cr–1Mo steel substrates. ES analysis through the coating confirmed the presence of alumina coating.
Oxidation kinetics study of the coated and uncoated substrates up to 900 °C in air atmosphere indicated a decrease of nearly two orders of magnitude lower oxidation rate for the coated substrate. Based on the elemental X-ray mapping and SEM of the oxidized sample, oxidation kinetics is discussed.
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References
Uhlig HH, Winston R (1985) Oxidation and tarnish in corrosion and corrosion control. Wiley-Interscience, New York
Brokeway L, Rowe A (1967) In: Saltsburg H (ed) Fundamentals of gas surface interaction. Academic Press, New York
Gronlund F (1956) J Chim Phys 53:660
Kofstad P (1988) High temperature corrosion. Elsevier Applied Science, London, p 382
Benard J, Grolund F, Oudar J, Duret M (1959) Z. Elektrochem 63:799
Uhlig HH (1956) Initial oxidation rate of metals and the logarithmic equation. Acta Metall 541:554
Cabrera N, Mott N (1949) Theory of the oxidation of metals. Rep Prog Phys 12:163–184
Klueh RL (2005) Elevated-temperature ferritic and martensitic steels and their applications to future nuclear reactors. Int Mater Rev 50:287–310
Lepingle V, Louis G, Allue D, Lefebvre B, Vandenberghe B (2008) Steam oxidation resistance of new 12 % Cr steel: comparison with some other ferritic steels. Corros Sci 50:1011–1019
Huntz AM, Reckmann A, Haunt C, Serverac C, Herbst M, Resende FCT, Sabioni AC (2007) Oxidation of AISI 304 and AISI 439 stainless steels. Mater Sci Eng A 447:266
Yoon KH, Cho YS, Kang DH (1998) Molten salts synthesis of lead based relaxers. J Mater Sci 33:2977–2984
Ennis PJ, Czyrsk-Filemonowicz A (2003) Recent advances in creep-resistant steels for power plant applications. Sadhana 28:709–730
Shukla AK, Gond D, Bharadwaj M, Puri D (2011) High temperature oxidation and hot corrosion behaviour of 9Cr 1Mo ferritic cold rolled steel in air at 900 °C under cyclic condition. J Miner Mater Charact Eng 10:1061
Fujita T (1992) Current progresses in advanced high Cr steel for high temperature applications. ISIJ 32:175–181
Metcalf E, Scarlin B (1998) Advanced high efficiency steam power plant. In: Proceedings of 6th Liege conference materials for advanced power engineering, vol 5. Julich, Germany 1.35
Wood GC, Wright IG, Hodgkless T, Whittle DP (1970) A comparison of the oxidation of Fe–Cr, Ni–Cr and Co–Cr alloys in oxygen and water vapour. Wrek Korr 21:900–910
Pint BA, Rakowski JM (2000) NACE. Houston, Orlando, p 259
Aguero A, Blas JG, Muelas R, Sachez A, Tsipas S (2001) Steam oxidation resistant coatings for steam turbine components: a feasibility study. Mater Sci Forum 369–372:939–946
Sundarajan T, Kuroda S, Abe F (2004) Steam oxidation studies on 50Ni-50Cr HVOF coatings on 9Cr–1Mo steel: change in structure and morphology across the coating/substrate interface. Mater Trans 45:1299–1305
Seal S, Roy SK, Bose SK (1994) Improvement in the oxidation behavior of austenitic stainless steel by superficially applied ceramic oxide coatings. Oxid Met 41:139
Lzumi K, Murakami M, Deguchi T, Morita A, Tohage N (1989) Zirconia coating on stainless steel sheets from organozirconium compound. J Am Ceram Soc 72:1465–1468
Kato K (1993) Enhancement of corrosion resistance of material through zirconia coatings. J Mater Sci 28:4033
Atik M, Zarzycki J (1994) Protection of 316L stainless steel by zirconia sol–gel coatings in 15 % H2SO4 solutions. J Mater Sci Lett 13:1301
Nazeri A, Trazaskoma PP, Bauer D (1997) Synthesis and properties of cerium and titanium oxide thin coating for corrosion protection of 304 stainless steel. J Sol Gel Sci Technol 10:317–331
Checmanwski J, Matraszec A, Szczygiel I, Szczygiel B (2013) High temperature oxidation of Fe Cr Al alloy with alumina–silica–ceria coatings deposited by sol–gel method. J Therm Anal Calorim 113:311–318
Fernandes SMC, Corea OV, Ramanathan LV (2014) Proceedings of the 5th international conference on nanotechnology: fundamentals and applications. Prague, Czech Republic, 11–13 Aug 2014 Paper No. 40
Ruhi G, Khare A, Singh M, Modi OP, Singh IB (2014) Hot corrosion resistances of nano-structured sol–gel alumina-coated 9Cr–1Mo ferritic steel in air/salt environment. Corrosion 70:130–136
Yoldas BE (1975) Alumina sol preparation from alkoxides. Am Ceram Soc Bull 51:289–290
Duvarci ÖÇ, Çiftçioğlu M, Güden M, Arıkut G (2004) Preparation and microstructural development of nanocrystalline titania and alumina. Key Eng Mat 264–268:2355–2358
Ruhi G, Modi OP, Singh IB, Jha AK, Yegneswaran AH (2006) Wear and electrochemical characterization of sol–gel alumina coating on chemically pre-treated mild steel substrate. Surf Coat Technol 201:1866–1872
Ruhi G, Modi OP, Singh IB (2009) Corrosion behaviour of nano structured sol–gel alumina coated 9Cr–1Mo ferritic steel in chloride bearing environment. Surf Coat Technol 204:359–365
Huntz AM (1999) J Mater Sci Lett 118:981
Chen RY, Yuen WYD (2003) Review of the high temperature oxidation of iron and carbon steel in air or oxygen. Oxid Met 59:433–468
Skalli A, Galerie A, Caillet M (1987) Kinetic and thermodynamic aspects of the thermal oxidation of a chromium–molybdenum steel (Fe 2.25 Cr 1 Mo). Solid State Ion 25:27–36
Kane RD High temperature gaseous corrosion. In: Graner SD, Covino BS (eds) Corrosion: fundamentals, testing and protection. 13 A ASM International pp. 230
Yang X, Pierre AC, Uhlmann DR (1988) TEM study of boehmite gels and their transformation to α-alumina. J Non Cryst Solids 100:371–377
Niranatlumpeng P, Ponton CV, Evans HE (2000) The failure of protective oxide on plasma-sprayed NiCrAlY overlay coatings. Oxid Met 53:241–258
Rapp RA, Devan JH, Douglass DL, Nordie PC, Pettit FS, Whittle DP (1981) High temperature corrosion in energy system. Mater Sci Eng 50:1–17
Liu PS, Liang KM, Zhou HY, Gu SR, Sun SF, Guan HR, Jin T, Yang KN (2001) Cyclic oxidation behavior of aluminide coatings on the Co-base superalloy DZ40M. Surf Coat Technol 145:75–79
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Authors are thankful to the director, CSIR-Advanced Materials and Processes Research Institute for providing experimental facilities. They are also thankful to Mr A. K. Khare of CSIR-AMPRI, Bhopal for his help in EDX analysis.
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Singh, I.B., Modi, O.P. & Ruhi, G. Development of sol–gel alumina coating on 9Cr–1Mo ferritic steel and their oxidation behavior at high temperature. J Sol-Gel Sci Technol 74, 685–691 (2015). https://doi.org/10.1007/s10971-015-3649-9
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DOI: https://doi.org/10.1007/s10971-015-3649-9