Abstract
Calcium titanate (CaTiO3) nanoparticles with different average sizes were prepared by a polyacrylamide gel route, where the particle size was tailored by using different chelating agents. Scanning electron microscope observation shows that the samples prepared by using the chelating agents EDTA, acetic acid, tartaric acid, and citric acid have an average particle size of 25, 33, 36, and 55 nm, respectively. All the particles are regularly shaped like spheres. The bandgap energy of the four samples is measured to be 3.66–3.59 eV by ultraviolet (UV)–visible diffuse reflectance spectroscopy. The photocatalytic activity of the prepared CaTiO3 samples was evaluated by the degradation of methyl orange under 254 nm UV irradiation, revealing that they exhibit a good photocatalytic activity. Hydroxyl radicals are revealed, by the photoluminescence technique using terephthalic acid as a probe molecule, to be produced on the irradiated CaTiO3 nanoparticles and suggested to be the primary active species toward the dye degradation.
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Mills A, Davies RH, Worsley D (1993) Chem Soc Rev 22:417
Hoffmann MR, Martin ST, Choi WY, Bahneman DW (1995) Chem Rev 95:69
Jang JS, Borse PH, Lee JS, Lim KT, Jung OS, Jeong ED, Bae JS, Kim HG (2011) Bull Korean Chem Soc 32:95
Zhang H, Chen G, He X, Xu J (2012) J Alloys Compd 516:91
Shi J, Guo L (2012) Prog Nat Sci Mater Int 22:592
Puangpetch T, Sommakettarin P, Chavadej S, Sreethawong T (2010) Int J Hydrogen Energy 35:12428
Sun W, Zhang S, Wang C, Liu Z, Mao Z (2007) Catal Lett 119:148
Arbuj SS, Hawaldar RR, Varma S, Waghmode SB, Wani BN (2012) Sci Adv Mater 4:568
Lemański K, Gągor A, Kurnatowska M, Pązik R, Dereń PJ (2011) J Solid State Chem 184:2713
Fujiwara R, Sano H, Shimizu M, Kuwabara M (2009) J Lumin 129:231
Oliveira LH, de Moura AP, Mazzo TM, Ramírez MA, Cavalcante LS, Antonio SG, Avansi W, Mastelaro VR, Longo E, Varela JA (2012) Mater Chem Phys 136:130
Zhang F, Chena S, Lin C, Yin Y (2011) Appl Surf Sci 257:3092
Tan S, Yang P, Li C, Wang W, Wang J, Zhang M, Jing X, Lin J (2010) Solid State Sci 12:624
Cavalcantea LS, Marques VS, Sczancoski JC, Escote MT, Joya MR, Varela JA, Santos MRMC, Pizani PS, Longo E (2008) Chem Eng J 143:299
Zhang X, Zhang J, Ren X, Wang X (2008) J Solid State Chem 181:393
Yang X, Fu J, Jin C, Chen J, Liang C, Wu M, Zhou W (2010) J Am Chem Soc 132:14279
Sun JH, Yang H (2014) Ceram Int 40:6399
Yang H, Cao ZE, Shen X, Jiang JL, Wei ZQ, Dai JF, Feng WJ (2009) Mater Lett 63:665
Wang SF, Yang H, Xian T, Liu XQ (2011) Catal Commun 12:625
Zhu A, Wang J, Du Y, Zhao D, Gao Q (2012) Phys B 407:849
Morrison SR (1980) Electrochemistry at semiconductor and oxidized metal electrodes. Plenum Press, New York
Andersen T, Haugen HK, Hotop H (1999) J Phys Chem Ref Data 28:1511
Tachikawa T, Fujitsuka M, Majima T (2007) J Phys Chem C 111:5259
Arai T, Yanagida M, Konishi Y, Iwasaki Y, Sugihara H, Sayama K (2007) J Phys Chem C 111:7574
Acknowledgments
This work was supported by the National Natural Science Foundation of China (Grant No. 51262018) and the Hongliu Outstanding Talents Foundation of Lanzhou University of Technology (Grant No. J201205).
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Huo, Y.S., Yang, H., Xian, T. et al. A polyacrylamide gel route to different-sized CaTiO3 nanoparticles and their photocatalytic activity for dye degradation. J Sol-Gel Sci Technol 71, 254–259 (2014). https://doi.org/10.1007/s10971-014-3366-9
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DOI: https://doi.org/10.1007/s10971-014-3366-9