Abstract
Zinc aluminate compounds have been dispersed in silica matrix prepared by sol-gel method with different compositions for (1 − x)ZnAl2O4–xSiO2. Continuous stirring of ethylene glycol solution contained zinc nitrate, aluminium nitrate and silicon dioxide to produces gel precursor. Structural and morphological studies of (1 − x)ZnAl2O4–xSiO2 thin films were examined by field emission scanning electron microscopy (FESEM) and X-ray diffractometer (XRD) analysis. The FESEM images showed the spherical structures with porosity for (1 − x)ZnAl2O4–xSiO2 thin films. XRD analysis indicated that the crystallite size for (1 − x)ZnAl2O4–xSiO2 increased from 39.79 to 44.34 nm. Fourier transform infra-red analysis showed that the existence of H2O molecules and the presence of nitrate group within the samples. Dielectric permittivity (ε r ) of (1 − x)ZnAl2O4–xSiO2 samples were measured within frequency range from 1 Hz to 1 MHz. The dielectric permittivity, ε r decreased as frequency was applied to the sample. The performance of the patch antenna can be measured using return loss analysis. The highest result shows that the patch antenna resonated at frequency 3.46 GHz and gives −14.25 dB return loss bandwidth.
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Lei W, Lu W-Z, Liu D, Zhu J-H (2009) Phase evolution and microwave dielectric properties of (1 − x)ZnAl2O4 − xMg2TiO4 ceramics. J Am Ceram Soc 92(1):105–109. doi:10.1111/j.1551-2916.2008.02757.x
Mookiah P, Dandekar KR (2009) Metamaterial-substrate antenna array for MIMO communication system. Antennas Propagation IEEE Trans 57(10):3283–3292. doi:10.1109/tap.2009.2028638
Wei X, Chen D (2006) Synthesis and characterization of nanosized zinc aluminate spinel by sol-gel technique. Mater Lett 60(6):823–827. doi:10.1016/j.matlet.2005.10.024
Cheng P, Deng C, Gu M, Shangguan W (2007) Visible-light responsive zinc ferrite doped titania photocatalyst for methyl orange degradation. J Mater Sci 42(22):9239–9244. doi:10.1007/s10853-007-1902-5
Sampath SK, Cordaro JF (1998) Optical properties of zinc aluminate, zinc gallate, and zinc aluminogallate spinels. J Am Ceram Soc 81(3):649–654. doi:10.1111/j.1151-2916.1998.tb02385.x
Zawadzki M, Wrzyszcz J (2000) Hydrothermal synthesis of nanoporous zinc aluminate with high surface area. Mater Res Bull 35(1):109–114. doi:10.1016/S0025-5408(00)00185-9
Davis M, Gümeci C, Alsup R, Korzeniewski C, Hope-Weeks LJ (2012) Facile synthesis of zinc aluminate nanostructures through an epoxide driven sol-gel route. Mater Lett 73:139–142. doi:10.1016/j.matlet.2011.12.098
Simeone D, Dodane-Thiriet C, Gosset D, Daniel P, Beauvy M (2002) Order–disorder phase transition induced by swift ions in MgAl2O4 and ZnAl2O4 spinels. J Nucl Mater 300(2–3):151–160. doi:10.1016/S0022-3115(01)00749-8
Wu J-M, Lu W-Z, Lei W, Wang X-C (2011) Preparation of ZnAl2O4-based microwave dielectric ceramics and GPS antenna by aqueous gelcasting. Mater Res Bull 46(9):1485–1489. doi:10.1016/j.materresbull.2011.04.026
Jiang H, Liu HW, Yu H, Gao F, Liu J-M, Nan CW (2005) Dielectric behaviors of ZnFe2O4–SiO2 composite thin films prepared by sol-gel method. Int J Mod Phys B 19(15n17):2682–2686. doi:10.1142/S0217979205031523
Kim GS, Hyun SH, Park HH (2001) Synthesis of low-dielectric silica aerogel films by ambient drying. J Am Ceram Soc 84(2):453–455. doi:10.1111/j.1151-2916.2001.tb00677.x
Lin J, Chen H, Yuan Y, Ji Y (2011) Mechanochemically conjugated PMHS/nano-SiO2 hybrid and subsequent optimum grafting density study. Appl Surf Sci 257(21):9024–9032. doi:10.1016/j.apsusc.2011.05.093
Hong W-S, De Jonghe LC, Yang X, Rahaman MN (1995) Reaction sintering of ZnO–AI2O3. J Am Ceram Soc 78(12):3217–3224. doi:10.1111/j.1151-2916.1995.tb07957.x
van der Laag NJ, Snel MD, Magusin PCMM, de With G (2004) Structural, elastic, thermophysical and dielectric properties of zinc aluminate (ZnAl2O4). J Eur Ceram Soc 24(8):2417–2424. doi:10.1016/j.jeurceramsoc.2003.06.001
Valenzuela MA, Jacobs JP, Bosch P, Reijne S, Zapata B, Brongersma HH (1997) The influence of the preparation method on the surface structure of ZnAl2O4. Appl Catal A 148(2):315–324. doi:10.1016/S0926-860X(96)00235-9
Guilhaume N, Primet M (1994) Catalytic combustion of methane: copper oxide supported on high-specific-area spinels synthesized by a sol-gel process. J Chem Soc, Faraday Trans 90(11):1541–1545
Davar F, Salavati-Niasari M (2011) Synthesis and characterization of spinel-type zinc aluminate nanoparticles by a modified sol-gel method using new precursor. J Alloys Compd 509(5):2487–2492. doi:10.1016/j.jallcom.2010.11.058
Wu Y, Du J, Choy K-L, Hench LL, Guo J (2005) Formation of interconnected microstructural ZnAl2O4 films prepared by sol-gel method. Thin Solid Films 472(1–2):150–156. doi:10.1016/j.tsf.2004.07.084
Zhang L (2004) Preparation of multi-component ceramic nanoparticles (trans: Science GIM). Ohio State University
Hu C, Liu P (2013) Preparation and microwave dielectric properties of SiO2 ceramics by aqueous Sol-Gel technique. J Alloys Compd 559:129–133. doi:10.1016/j.jallcom.2012.11.168
Plocek J, Hutlová A, Nižňanský D, Buršík J, Rehspringer JL, Mička Z (2003) Preparation of ZnFe2O4/SiO2 and CdFe2O4/SiO2 nanocomposites by sol–gel method. J Non-Cryst Solids 315(1–2):70–76. doi:10.1016/S0022-3093(02)01595-8
Jenkins R, Snyder R (2012) Introduction to X-ray powder diffractometry, vol 267. Wiley-Interscience, New York
Abdullah H, Halim SA, Jannah AN (2012) Effect of disorder particles size of Nd on electrical transport on a bulk of Pr2/3Ba1/3MnO3. J Compos Mater. doi:10.1177/0021998311436020
Abdullah H, Halim SA (2009) Electrical and microstructural properties of (La1-xPrx)1/2Ba1/2MnO3 compounds. Sains Malaysiana 38(2):209–213
Kumar RT, Selvam NCS, Ragupathi C, Kennedy LJ, Vijaya JJ (2012) Synthesis, characterization and performance of porous Sr(II)-added ZnAl2O4 nanomaterials for optical and catalytic applications. Powder Technol 224:147–154. doi:10.1016/j.powtec.2012.02.044
Jamal E, Kumar D, Anantharaman MR (2011) On structural, optical and dielectric properties of zinc aluminate nanoparticles. Bull Mater Sci 34(2):251–259. doi:10.1007/s12034-011-0071-y
Duan X, Yuan D, Wang X, Xu H (2005) Synthesis and characterization of nanocrystalline zinc aluminum spinel by a new sol-gel method. J Sol-Gel Sci Technol 35(3):221–224. doi:10.1007/s10971-005-2359-0
Beier MJ, Hansen TW, Grunwaldt J-D (2009) Selective liquid-phase oxidation of alcohols catalyzed by a silver-based catalyst promoted by the presence of ceria. J Catal 266(2):320–330. doi:10.1016/j.jcat.2009.06.022
Wu KH, Chang YC, Wang GP (2004) Preparation of NiZn ferrite/SiO2 nanocomposite powders by sol-gel auto-combustion method. J Magn Magn Mater 269(2):150–155. doi:10.1016/S0304-8853(03)00585-7
Shokri B, Firouzjah Abbasi M, Hosseini SI (2009) FTIR analysis of silicon dioxide thin film deposited by metal organic-based PECVD. In: Proceedings of 19th international symposium on plasma chemistry society, Bochum, Germany, 26–31 August 2009
Chroma M, Pinkas J, Pakutinskiene I, Beganskiene A, Kareiva A (2005) Processing and characterization of sol-gel fabricated mixed metal aluminates. Ceram Int 31(8):1123–1130. doi:10.1016/j.ceramint.2004.11.012
Tareev B (1975) Physics of dielectric materials. Mir Publisher
Surendran KP, Santha N, Mohanan P, Sebastian MT (2004) Temperature stable low loss ceramic dielectrics in (1-x)ZnAl2O4-xTiO2 system for microwave substrate applications. Eur Phys J B Condens Matter Complex Syst 41(3):301–306. doi:10.1140/epjb/e2004-00321-8
Gopalan EV, Malini KA, Saravanan S, Kumar DS, Yoshida Y, Anantharaman MR (2008) Evidence for polaron conduction in nanostructured manganese ferrite. J Phys D Appl Phys 41:185005
Balanis CA (1982) Antenna theory: analysis and design/Constantine A. Balanis. Wiley, New York
Chen YC (2011) Microwave dielectric properties of (Mg(1-x)Cox)2SnO4 ceramics for application in dual-band inverted-E-shaped monopole antenna. IEEE Trans Ultrason Ferroelectr Freq Control 58(12):2531–2538
Acknowledgments
This project is fully carried out in the Laboratory of Photonics, Institute of Microengineering and Nanoelectronics (IMEN), Universiti Kebangsaan Malaysia. The performance of patch antenna was fully carried out in the Laboratory of Institute of Space Science (ANGKASA), Universiti Kebangsaan Malaysia.
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Abdullah, H., Zulfakar, M.S., Wan Jalal, W.N. et al. Synthesis and fabrication of (1 − x)ZnAl2O4–xSiO2 thin films to be applied as patch antennas. J Sol-Gel Sci Technol 69, 183–192 (2014). https://doi.org/10.1007/s10971-013-3202-7
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DOI: https://doi.org/10.1007/s10971-013-3202-7