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Sol–gel Al2O3 powders—matrix in solar thermal absorbers

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Abstract

Porous alumina powders for solar thermal applications, prepared by sol–gel were comparatively investigated, starting from an organo-metallic precursor (aluminum isopropoxide) and an inorganic precursor (aluminum chloride hexahydrate). As morphology controlling agents, HCl and poly (ethylene glycol) were added in the precursor solutions. X-Ray Diffraction, Atomic Force Microscopy, Differential Scanning Calorimetry, Fourier Transform Infrared Spectra and UV–VIS-NIR spectroscopy were used to characterize the materials. The chemical composition, the phase structure and morphological properties are influenced by the additive type and by the heat treatment temperature. The results shows that optimized conditions lead to high quality matrix for solar-thermal absorbers, with absorptance in the visible region varying from 0.13 to 0.47 and low thermal emittance (εT = 0.02–0.09) in the infrared region of the solar spectrum.

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References

  1. Souza Santos P, Souza Santos H, Toledo SP (2000) Mater. Research 3:104–114

    Google Scholar 

  2. O’Dell LA, Savin SLP, Chandwick AV, Smith ME (2007) Solid State Magn Reson 31:169–173

    Article  Google Scholar 

  3. Zuo C, Li Q, Peng G, Xing G (2011) Prog Nat Sci Mater Int 21:455–459

    Article  Google Scholar 

  4. Khang D, Liu-Snyder P, Pareta R, Lu J, Webster TJ (2009) Acta Biomater 5:1425–1432

    Article  CAS  Google Scholar 

  5. Ruhi G, Modi OP, Sinha ASK, Singh IB (2008) Corros Sci 50:639–649

    Article  CAS  Google Scholar 

  6. Macêdo MIF, Osawa CC, Bertran CA (2004) J Sol-Gel Sci Technol 30:135–140

    Article  Google Scholar 

  7. Khaleel A, Al-Mansouri S (2010) Colloids Surf A 369:272–280

    Article  CAS  Google Scholar 

  8. Ao Y, Yang Y, Yuan S, Hu H, Gu H, Chen G (2007) Ceram Int 33:1547–1550

  9. Rodríguez JA, Fernández-García M (2007) Synthesis, properties, and applications of oxide nanomaterials. Wiley, New Jersey

    Book  Google Scholar 

  10. Zu G, Shen J, Wei X, Ni X, Zhang Z, Wang J, Liu G (2011) J Non Cryst Solids 357:2903–2906

    Article  CAS  Google Scholar 

  11. Chandradass J, Balasubramanian M (2006) J Mater Process Technol 173:275–280

    Article  CAS  Google Scholar 

  12. Carlsson A, Möller K, Frei U, Brunold S, Köhl M (2000) Sol Energy Mater Sol Cells 61:223–238

    Article  CAS  Google Scholar 

  13. Xinkang D, Cong W, Tianmin W, Long Z, Buliang C, Ning R (2008) Thin Solid Films 516:3971–3977

    Article  Google Scholar 

  14. Leivo J, Lindén M, Rosenholm JM, Ritola M, Teixeir CV, Levänen E, Mäntylä TA (2008) J Eur Ceram Soc 28:1749–1762

    Article  CAS  Google Scholar 

  15. Naik B, Ghosh NN (2009) Recent Pat Nanotechnol 3:213–224

    Article  CAS  Google Scholar 

  16. Ray JC, You KS, Ahn JW, Ahn WS (2007) Microporous Mesoporous Mater 100:183–190

    Article  CAS  Google Scholar 

  17. Guo W, Sun YW, Luo GS, Wang YJ (2005) Colloids Surf A 252:71–77

    Article  CAS  Google Scholar 

  18. Bayati MR, Zargar HR, Talimian A, Ziaee A, Molaei R (2010) Surf Coat Technol 205:2483–2489

    Article  CAS  Google Scholar 

  19. Li Z, Zhao J, Ren L (2012) Sol Energy Mater Sol Cells 105:90–95

    Article  CAS  Google Scholar 

  20. Li Z, Zhao J (2013) Appl Surf Sci 268:231–236

    Article  CAS  Google Scholar 

  21. Liu Y (2008) Thin Solid Films 516:1803–1808

    Article  CAS  Google Scholar 

  22. Tokudome Y, Nakanishi K, Kanamori K, Hanada T (2010) J Colloid Interface Sci 352:303–308

    Article  CAS  Google Scholar 

  23. Gawel B, Gawel K, Øye G (2010) Materials 3:2815–2833

    Article  CAS  Google Scholar 

  24. Duffie JA, Beckman WA (2006) Solar engineering of thermal processes, 3rd edn. Wiley, Hoboken

    Google Scholar 

  25. Horcas I, Fernandez R, Gomez-Rodriguez JM, Colchero J, Gomez-Herrero J, Baro AM (2007) Rev Sci Instrum 78:013705–1–013705–8

    Article  Google Scholar 

  26. Birkholz M (2006) Thin film analysis by x-ray scattering. Wiley-VCH Verlag GmbH & Co, KGaA, Weinheim

    Google Scholar 

  27. Cesiulis H, Bersirova O, Valiūnienė A, Prosyčevas I, Baltrūnas G (2004) Mater Sci 10:142–146

    Google Scholar 

  28. Sung DM, Kim YH, Park ED, Yie JE (2012) Catal Commun 20:63–67

    Article  CAS  Google Scholar 

  29. Thiruchitrambalam M, Palkar VR, Gopinathan V (2004) Mater Lett 58:3063–3066

    Article  CAS  Google Scholar 

  30. Tan H, Ding Y, Yang J (2010) J Sol-Gel Sci Technol 53:378–383

    Article  CAS  Google Scholar 

  31. Pretsch E, Bühlmann P, Badertscher M (2009) Structure determination of organic compounds. Tables of spectral data. Springer-Verlag, Berlin Heidelberg

    Google Scholar 

  32. Farooqa M, Hutchins MG (2002) Sol Energy Mater Sol Cells 71:523–535

    Article  Google Scholar 

  33. Barshilia HC, Kumar P, Rajam KS, Biswas A (2011) Sol Energy Mater Sol Cells 95:1707–1715

    Article  CAS  Google Scholar 

  34. Aguado J, Escola JM, Castro MC, Paredes B (2005) Microporous Mesoporous Mater 83:181–192

    Article  CAS  Google Scholar 

  35. Liu Q, Wang A, Wang X, Gao P, Wang X, Zhang T (2008) Microporous Mesoporous Mater 111:323–333

    Article  CAS  Google Scholar 

  36. Pan JH, Zhao XS, Lee WI (2011) Chem Eng J 170:363–380

    Article  CAS  Google Scholar 

  37. Liu Q, Wang A, Wang X, Zhang T (2007) Microporous Mesoporous Mater 100:35–44

    Article  CAS  Google Scholar 

  38. Gonzáles-Peňa V, Díaz I, Márquez-Alvares C, Sastre E, Pérez-Pariente J (2001) Microporous Mesoporous Mater 44–45:203–210

    Article  Google Scholar 

Download references

Acknowledgments

This paper is supported by the Sectoral Operational Programme Human Resources Development (SOP HRD), ID76945 financed from the European Social Fund and by the Romanian Government.

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Correspondence to Anca Duţã.

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Milea, C.A., Ienei, E., Bogatu, C. et al. Sol–gel Al2O3 powders—matrix in solar thermal absorbers. J Sol-Gel Sci Technol 67, 112–120 (2013). https://doi.org/10.1007/s10971-013-3056-z

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  • DOI: https://doi.org/10.1007/s10971-013-3056-z

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