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Synthesis, characterization and study of photocatalytic activity of surface modified ZnO nanoparticles by PEG capping

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Abstract

Nanoparticles of bare and PEG (Polyethylene glycol) capped zinc oxide (ZnO) were synthesized by precipitation method. The photocatalytic activity of bare and modified ZnO nanoparticles was studied by monitoring the degradation of Rhodamine B (RhB). The results show that PEG capped ZnO nanoparticles has reduced photocatalytic activity than the bare ZnO nanoparticles. The reduction in the chemical oxygen demand (COD) and total organic carbon (TOC) results also revealed the reduced photocatalytic activity of PEG capped ZnO. The UV-shielding property was evaluated by measuring the transmittance which shows that both bare and PEG capped ZnO nanoparticles possess good UV-shielding ability.

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References

  1. Pivin JC, Socol G, Mihailescu I, Berthet P, Singh F, Patel MK et al (2008) Thin Solid Films 517:916

    Article  CAS  Google Scholar 

  2. Sato K, Katayama-Yoshida H (2000) Jpn J Appl Phys 39:555

    Article  Google Scholar 

  3. Li YQ, Fu SY, Mai YW (2006) Polymer 47:2127

    Article  CAS  Google Scholar 

  4. Wang RH, Xin JH, Tao XM (2005) Inorg Chem 44:3926

    Article  CAS  Google Scholar 

  5. Iwasaki T, Satoh M, Ichio S (2003) J Mater Process Technol 142:131

    Article  CAS  Google Scholar 

  6. Huang ZY, Barber T, Mills G, Morris MB (1994) J Phys Chem 98:12746

    Article  CAS  Google Scholar 

  7. Park OK, Kang YS (2005) Colloids Surf A Physicochem Eng A 257:261

    Article  Google Scholar 

  8. Liu Q, Xu Z, Finch JA, Egerton R (1998) Chem Mater 10:3936

    Article  CAS  Google Scholar 

  9. Lakhwani S, Rahaman MN (1999) J Mater Sci 34:3909

    Article  CAS  Google Scholar 

  10. Lin Y, Wang L, Lin JG et al (2003) Synth Met 135:769

    Article  Google Scholar 

  11. Chibowski S (1996) Adsorp SciTechnol 14:179

    CAS  Google Scholar 

  12. Chibowski S, Paszkiewicz M, Krupa M (2000) Powder Technol 107:251

    Article  CAS  Google Scholar 

  13. Chibowski S, Paszkiewicz M (2001) Adsorp Sci Technol 19:397

    Article  CAS  Google Scholar 

  14. Zhang YW, Tang M, Jin X et al (2003) Solid State Sci 5:435

    Article  CAS  Google Scholar 

  15. Sheng C, Liu F, Xiao HN (2004) Powder Technol 145:20

    Article  Google Scholar 

  16. Rudolf C, Hoffmann T, Jia SJ, Lars PH, Jeurgens C (2006) Mater Sci Eng C Biomim Mater Sens Syst 26:41

    Article  Google Scholar 

  17. Hoffmann RC, Bill J, Aldinger F (2004) J Am Ceram Soc 148:53

    CAS  Google Scholar 

  18. Yang XJ, Shi ZS, Xu XL (2002) Chin Phys Soc 51:2871

    CAS  Google Scholar 

  19. Zhang YW, Tang M, Jin X (2003) Solid State Sci 5:435

    Article  CAS  Google Scholar 

  20. Liu XX, Jin ZG, Bu SJ (2005) Mater Lett 59:3994

    Article  CAS  Google Scholar 

  21. Abdullah M, Morimoto T, Okuyama K (2003) Adv Funct Mater 13:800

    Article  CAS  Google Scholar 

  22. Liu XM, Zhou YC (2004) J Cryst Growth 270:527

    Article  CAS  Google Scholar 

  23. Sun HK, Luo M, Weng WJ, Cheng K, Du PY, Shen G, Han GR (2008) Nanotechnology 19:125603

    Article  Google Scholar 

  24. Hou XM, Zhou F, Liu WM (2006) Mater Lett 60:3786

    Article  CAS  Google Scholar 

  25. Liu JP, Huang XT, Li YY, Sulieman KM, Sun FL, He X (2006) Scr Mater 55:795

    Article  CAS  Google Scholar 

  26. Zhang Z, Mu J (2007) J Colloid Interface Sci 307:79

    Article  CAS  Google Scholar 

  27. Lepot N, VanBael MK, Van den Rul H, D’Haen J, Peeters R, Franco D, Mullens J (2007) Mater Lett 61:2624

    Article  CAS  Google Scholar 

  28. Jitianu M, Goia DV (2007) J Colloid Interface Sci 309:78

    Article  CAS  Google Scholar 

  29. Kodaira S, Lee SW, Kunitake T (2008) Chem Lett 37:168

    Article  CAS  Google Scholar 

  30. Luo C, Zhang Y, Zeng X, Zeng Y, Wang Y (2005) J Colloid Interface Sci 288:444

    Article  CAS  Google Scholar 

  31. Su W, Wei SS, Hu SQ, Tang JX (2009) J Hazard Mater 172:716

    Article  CAS  Google Scholar 

  32. Sudha M, Senthilkumar S, Hariharan R, Suganthi A, Rajarajan M (2012) J Sol-Gel Sci Technol 61:14

    Article  CAS  Google Scholar 

  33. Meng FK, Hong ZL, Arndt J, Li M, Zhi MJ, Yang F, Wu NQ (2012) Nano Res 5:213

    Article  CAS  Google Scholar 

  34. Ma TY, Yuan ZY, Cao JL (2010) Eur J Inorg Chem 5:716

    Article  Google Scholar 

  35. Cushing SK, Li JT, Meng FK, Senty TR, Suri S, Zhi MJ, Li M, Bristow AD, Wu NQ (2012) J Am Chem Soc 134:15033

    Article  CAS  Google Scholar 

  36. Silverstein RM, Bassler GC, Morrill TC (1981) Spectrometric identification of organic compounds, 4th edn. Wiley, New York

    Google Scholar 

  37. Santhiya D, Subramanian S, Natarajan KA et al (1999) J Colloid Interface Sci 216:143

    Article  CAS  Google Scholar 

  38. Liu XH, Yang J, Wang L et al (2000) Mater Sci Eng A 289:241

    Article  Google Scholar 

  39. Shan GY, Xiao XL, Wang X, Kong XG, Liu YC, Shan G (2006) J Colloid Interface Sci 298:172

    Article  CAS  Google Scholar 

  40. Musi S, Sari A, Popovi S (2008) J Alloys Compd 448:277

    Article  Google Scholar 

  41. Musi S, Drag D, Popovi S (2007) J Alloys Compd 429:242

    Article  Google Scholar 

  42. Andri M, Vergi S, Martinez-Gallego SM (1992) J Mater Sci 27:3756

    Article  Google Scholar 

Download references

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Correspondence to M. Rajarajan.

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Sudha, M., Senthilkumar, S., Hariharan, R. et al. Synthesis, characterization and study of photocatalytic activity of surface modified ZnO nanoparticles by PEG capping. J Sol-Gel Sci Technol 65, 301–310 (2013). https://doi.org/10.1007/s10971-012-2936-y

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  • DOI: https://doi.org/10.1007/s10971-012-2936-y

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