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Influence of cerium concentration on the structure and properties of silica-methacrylate sol–gel coatings

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Abstract

The aim of this work was to study the effect of the incorporation of cerium nitrate in a silica-methacrylate sol–gel hybrid matrix reinforced with silica nanoparticles. Sols, coatings and powders have been studied, focusing specially in the determination of the redox ratio Ce3+/Ce4+ and films structure. Sols have been characterised using viscosity measurements and FT-IR spectroscopy, and powders and coatings obtained with different Ce contents through UV–Vis and FT-IR spectroscopy, TGA, TEM, AFM and FE-SEM. The goal was to reach the best compromise between maximum cerium concentration and coating stability to better understand the mechanisms acting in active anti-corrosive processes.

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Acknowledgments

This publication was generated in the frame of MULTIPROTECT project, funded by 6th Framework Programme of the European Community (Contract N° IP- 011783). Otherwise the JAE fellowship of Nataly Carolina Rosero-Navarro is thanked to CSIC. The authors are grateful to Lauran Pelaéz, Antonio Tomás and Eva Peiteado for their assistance with the experimental techniques.

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Author notes

  1. Sergio Antonio Pellice

    Present address: Instituto de Investigaciones en Ciencia y Tecnología de Materiales (CONICET), Mar del Plata, Argentina

Authors and Affiliations

  1. Instituto de Cerámica y Vidrio (CSIC), Madrid, Spain

    Nataly Carolina Rosero-Navarro, Yolanda Castro, Mario Aparicio, Sergio Antonio Pellice & Alicia Durán

  2. West Pomeranian University of Technology, Institute of Materials Science and Engineering, Szczecin, Poland

    Pawel Figiel, Roman Jedrzejewski & Anna Biedunkiewicz

Authors
  1. Nataly Carolina Rosero-Navarro
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  2. Pawel Figiel
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  3. Roman Jedrzejewski
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  4. Anna Biedunkiewicz
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  5. Yolanda Castro
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Correspondence to Nataly Carolina Rosero-Navarro.

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Rosero-Navarro, N.C., Figiel, P., Jedrzejewski, R. et al. Influence of cerium concentration on the structure and properties of silica-methacrylate sol–gel coatings. J Sol-Gel Sci Technol 54, 301–311 (2010). https://doi.org/10.1007/s10971-010-2194-9

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  • DOI: https://doi.org/10.1007/s10971-010-2194-9

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