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Amorphous sol–gel SiO2 film for protection of an orthorhombic phase alloy against high temperature oxidation

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Abstract

Silica coating derived by sol–gel processing was deposited on an orthorhombic phase Ti–22Al–26Nb alloy by dip-coating technique. Isothermal oxidation at 800 and 900 °C and cyclic oxidation at 900 °C in static air of the coated and uncoated specimens were performed to investigate the effect of the silica coating on the oxidation behavior of the Ti–22Al–26Nb alloy by thermogravimetry, SEM and XRD. The average parabolic rate constants of the coated specimens were lower than those of uncoated ones. Additionally, the present film exhibited a beneficial effect on the cyclic oxidation resistance of the alloy in air. TiO2, Nb2TiO7 or AlNbO4 were the main phases formed on the alloy. The thin film could inhibit the growth of the oxides. The possible mechanism of the thin film on the oxidation behavior of the alloy was discussed.

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Acknowledgment

Financial support by the Education Bureau of Liaoning Province under the grant No. 05L 342 is gratefully acknowledged. We also thank Ph. D. K. Zhang (IMR, CAS) for providing the alloy.

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Authors and Affiliations

  1. College of Applied Chemistry, Shenyang Institute of Chemical Technology, Shenyang, 110142, China

    X. J. Zhang, S. Y. Zhao, C. X. Gao & S. J. Wang

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  1. X. J. Zhang
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  2. S. Y. Zhao
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  3. C. X. Gao
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  4. S. J. Wang
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Correspondence to X. J. Zhang.

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Zhang, X.J., Zhao, S.Y., Gao, C.X. et al. Amorphous sol–gel SiO2 film for protection of an orthorhombic phase alloy against high temperature oxidation. J Sol-Gel Sci Technol 49, 221–227 (2009). https://doi.org/10.1007/s10971-008-1863-4

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  • DOI: https://doi.org/10.1007/s10971-008-1863-4

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