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Synthesis of nickel-iron spinel by non-conventional methods

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Abstract

Nickel-iron black ceramic pigments of (Fe0.8Mg0.2)(Fe0.2Ni0.8Cr)O4 and (Fe0.8Mg0.1Zn0.1)(Fe0.2Ni0.8Cr)O4 compositions have been prepared by non conventional methods such as coprecipitation, microemulsion and polymeric gel routes (alkoxides hydrolysis-condensation), and compared with ceramic samples prepared by the solid state reaction from oxide precursors. The mineralising effect of a 2NaCl:NaF flux agent has been also analysed. Both non conventional methods and mineraliser presence increase the reactivity of the samples. The highest reactivity and the best black colour are obtained in the polymeric gel sample prepared from alkoxides; coprecipitated and microemulsion fired pigments are partially solubilised by glazes due to the small particle size exhibited, leading to brown colours.

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References

  1. G. Monrós, J.A. Badenes, A. García, and M.A. Tena, “El color de la cerámica: nuevos mecanismos para los nuevos procesados de la industria cerámica, (Publicacions de la Universitat Jaume I, Castellón, 2003) p 121.

    Google Scholar 

  2. M. Ocaña, A. Caballero, A.R. Gonzálex-Felipe, P. Tartaj, C. J. Serna, and R.I. Merino, J. Eur. Ceramic Soc. 19, 641 (1999).

    Article  Google Scholar 

  3. G. Nero, G. Cappelletti, S. Ardizzone, P. Fermo, and S. Gilardoni, J. European Ceramic Soc. 24(14), 3603 (2004).

    Article  CAS  Google Scholar 

  4. S. Ardizzone, L. Binaghi, G. Cappelletti, P. Fermo, and S. Gilardoni, Phys. Chem. Chemical Physics. 4, 5683 (2002).

    CAS  Google Scholar 

  5. J. Alarcón, J. Eur. Ceramic Soc. 20, 1749 (2000).

    Article  Google Scholar 

  6. J. Calbo, A. Mestre, A. García, M.A. Tena, M. Llusar, and G. Monrós, J. Sol-Gel Sci. Technol. 26, 191 (2003).

    Article  CAS  Google Scholar 

  7. A.C. Pierre, Am. Ceramic Soc. Bull. 70, 1281 (1991).

    CAS  Google Scholar 

  8. M. Kakihana, J. Sol-Gel Sci. Technol. 6, 7 (1996).

    Article  CAS  Google Scholar 

  9. F. Meyer, R. Hempelmann, S. Mathur, and M. Veith, J. Mater. Chem. 9, 1755 (1999).

    Article  CAS  Google Scholar 

  10. A. Garcia, M. Llusar, S. Sorlí, J. Calbo, M.A. Tena, and G. Monros, J. Eur. Ceramic Soc. 23, 1829 (2003).

    Article  CAS  Google Scholar 

  11. R.A. Eppler, Am. Ceramic Soc. Bull. 60(5), 562 (1981).

    CAS  Google Scholar 

  12. R.A. Eppler, Am. Ceramic Soc. Bull. 61, 847 (1982).

    CAS  Google Scholar 

  13. J. Calbo, S. Sorlí, M. Llusar, M.A. Tena, and G. Monrós, British Ceramic Trans. 103(1), 3 (2003).

    Article  CAS  Google Scholar 

  14. A. Escardino, S. Mestre, A. Barba, V. Beltrán, and A. Blasco, J. Am. Ceramic Soc. 86(6), 945 (2003).

    Article  CAS  Google Scholar 

  15. J. Calbo, M.A. Tena, G. Monrós, M. Llusar, R. Galindo, and J.A. Badenes, Am. Ceramic Soc. Bull. 84(12) (2005).

  16. CIE, Recommendations on Uniform Colour Spaces, Colour Difference Equations, Psychometrics Colour terms. Suplement n°2 of CIE Pub. N°15 (E1-1.31) 1971, Bureau Central de la CIE, Paris, (1978).

  17. V.C. Farner et al., The Infrared Spectra of Minerals, (edited by V.C. Farmer, Surrey, UK, 1974) p. 183.

  18. M. Kakihana, T. Naguno, M. Okanato, and H. Kakihana, J. Phys. Chem., 91, 6128 (1987).

    Article  CAS  Google Scholar 

  19. L. Catalán, G. Contreras, F. Ramos, D. Bedoya, M. Vicente, and G. Monrós, Communication to VI World Congress on Ceramic Tile Quality QUALICER 2000, Castellón (2000).

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Authors and Affiliations

  1. Inorganic Chemistry Area, Inorganic and Organic Chemistry Department, Jaume I University, Castellón, Spain

    J. Calbo, M. A. Tena, G. Monrós, M. Llusar & J. A. Badenes

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  1. J. Calbo
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  2. M. A. Tena
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  3. G. Monrós
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  4. M. Llusar
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  5. J. A. Badenes
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Correspondence to J. A. Badenes.

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Calbo, J., Tena, M.A., Monrós, G. et al. Synthesis of nickel-iron spinel by non-conventional methods. J Sol-Gel Sci Technol 38, 167–177 (2006). https://doi.org/10.1007/s10971-006-6573-1

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  • DOI: https://doi.org/10.1007/s10971-006-6573-1

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