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Assessment of radiation hazards of white and grey Portland cements

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Abstract

Activity concentration of 232Th, 226Ra and 40K was determined in 11 white and 63 grey Portland cements by using gamma spectrometry. The potential γ-ray radiation hazards due to mentioned activity concentrations were assessed by following five approaches: internal hazard index, Hin, external hazard index, Hex, activity concentration index, I, absorbed dose rate, D, and effective dose, Ep. All of these showed results falling below threshold limits. Particularly, white cements exhibited slightly lower values than grey ones. The annual effective dose estimated for all the Portland cements falls within 0.10 mSv to 0.47 mSv (≤ 1 mSv: threshold criterion for building materials).

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References

  1. Rezola-Izaguirre J (1975) White Portland cement and its applications. Institute for Construction Sciences “Eduardo Torroja”, Madrid, Spain, p 396 (in Spanish)

  2. Commission Delegated Regulation (EU) (2018) …/…determining transitional Union-wide rules for harmonised free allocation of emission allowances pursuant to Article 10a of Directive 2003/87/EC of the European Parliament and of the Council, ANNEX I Benchmarks. Brussels, 19.12.2018, C/2018/8664 final. https://eur-lex.europa.eu/legal-content/EN/ALL/?uri=pi_com:C(2018)8664

  3. EN 197-1 (2011) Cement—Part 1: composition, specifications and conformity criteria for common cements. CEN, Brussels, Belgium

  4. UNE 80305:2012 (2001) White cements. The Spanish standardization Body, UNE, Madrid, Spain. (in Spanish). https://www.une.org/encuentra-tu-norma/busca-tu-norma/norma/?Tipo=N&c=N0048846

  5. International Commission on Illumination (1986) In: CIE Publication No. 15.2, second ed. The evaluation of whiteness, Colorimetry, CIE Central Bureau, Vienna, Austria, pp 36–38

  6. UNE 80117:2012 (2012) Methods of testing cements. Physical analysis. Colour determination in clinkers and white cements. The Spanish standardization Body, UNE, Madrid, Spain (in Spanish)

  7. Global Cement Directory (2015) The Global Cement Report™—12th edition

  8. Council Directive 2013/59/EURATOM (2014) Laying down basic safety standards for protection against the dangers arising from exposure to ionising radiation, and repealing Directives 89/618/Euratom, 90/641/Euratom, 96/29/Euratom, 97/43/Euratom and 2003/122/Euratom. Article 75 “Gamma radiation from building materials”. 2013, European Union. Official Journal of the European Union, 17.1.2014, L 13/31. p 73

  9. Sanjuán MA, Argiz C (2012) The new european standard on common cements specifications. EN-197-1:2011. Mater Constr 62:425–430

    Article  Google Scholar 

  10. Arafa W (2002) Permeability of radon-222 through some materials. Radiat Meas 35(3):207–211

    Article  CAS  Google Scholar 

  11. Zhang W, Ungar K, Chen J, St-Amant N, Tracy BL (2009) An accurate method for the determination of 226Ra activity concentrations in soil. J Radioanal Nucl Chem 280:561–567

    Article  CAS  Google Scholar 

  12. Mauring A, Gäfvert T (2013) Radon tightness of different sample sealing methods for gamma spectrometric measurements of 226Ra. Appl Radiat Isot 81:92–95

    Article  CAS  Google Scholar 

  13. Yang B, Ha Y, Li A, Zhou H, Wang F, Li W (2013) Optimisation design of cylindrical containers for improving the detection efficiency of a high-purity germanium detector using the LabSOCS. J Radioanal Nucl Chem 298(3):1673–1677

    Article  CAS  Google Scholar 

  14. Suarez-Navarro JA, Gascó C, Alonso MM, Blanco-Varela MT (2018) Use of Genie 2000 and Excel VBA to correct for γ-ray interference in the determination of NORM building material activity concentrations. Appl Radiat Isot 142:1–7

    Article  CAS  Google Scholar 

  15. Asghar M, Tufail M, Sabiha J, Abid A, Waqas M (2008) Radiological implications of granite of northern Pakistan. J Radiol Prot 28:387–399

    Article  CAS  Google Scholar 

  16. Beretka J, Mathew PJ (1985) Natural radioactivity of Australian building materials, industrial wastes and by-products. Health Phys 48:87–95

    Article  CAS  Google Scholar 

  17. Markkanen M (1995) Radiation dose assessments for materials with elevated natural radioactivity, report STUK-B-STO 32, Finnish Centre for Radiation and Nuclear Safety, Helsinki, Finland, p 38

  18. Sabiha J, Tufail M, Asghar M (2010) Hazard of NORM from phosphorite of Pakistan. J Hazard Mater 176:426–433

    Article  Google Scholar 

  19. Nuccetelli C, Risica S, D’Alessandro M, Trevisi R (2012) Natural radioactivity in building material in the European Union: robustness of the activity concentration index I and comparison with a room model. J Radiol Prot 32:349–358

    Article  CAS  Google Scholar 

  20. Bambynek W (1987) Uncertainty assignment in radionuclide metrology. In: Garcia M, Madurga G (eds) Proceedings of the first international summer School La Rabida, Huelva, Spain. World Scientific, New-Jersey

    Google Scholar 

  21. Trevisi R, Risica S, D’Alessandro M, Paradiso D, Nuccetelli C (2012) Natural radioactivity in building materials in the European Union: a database and an estimate of radiological significance. J Environ Radioact 105:11–20

    Article  CAS  Google Scholar 

  22. Kassi B, Boukhair A, Azkour K, Fahad M, Benjelloun M, Nourreddine A-M (2018) Assessment of exposure due to technologically enhanced natural radioactivity in various samples of Moroccan building materials. WJNST 08:176–189

    Article  Google Scholar 

  23. Turhan S (2008) Assessment of the natural radioactivity and radiological hazards in Turkish cement and its raw materials. J Environ Radioact 99:404–414

    Article  CAS  Google Scholar 

  24. Shoeib MY, Thabayneh KM (2014) Assessment of natural radiation exposure and radon exhalation rate in various samples of Egyptian building materials. J Radiat Res Appl Sci 7:174–181

    Article  CAS  Google Scholar 

  25. Al-Sulaiti H, Alkhomashi N, Al-Dahan N, Al-Dosari M, Bradley DA, Bukhari S, Matthews M, Regan PH, Santawamaitre T (2011) Determination of the natural radioactivity in Qatarian building materials using high-resolution gamma-ray spectrometry. Nucl Instrum Methods Phys Res B 652:915–919

    Article  CAS  Google Scholar 

  26. Manić G, Manić V, Nikezić D, Krstić D (2015) The dose of gamma radiation from building materials and soil. Nukleonika 60:951–958

    Article  Google Scholar 

  27. Najam LA, Tawfiq NF, Kitah FH (2013) Measurement of natural radioactivity in building materials used in IRAQ. AJBAS 7:56–66

    CAS  Google Scholar 

  28. Sharma N, Singh J, Esakki SC, Tripathi RM (2019) A study of the natural radioactivity and radon exhalation rate in some cements used in India and its radiological significance. J Radiat Res Appl Sci 9:47–56

    Article  Google Scholar 

  29. Petropoulos NP, Anagnostakis MJ, Simopoulos SE (2002) Photon attenuation, natural radioactivity content and radon exhalation rate of building materials. J Environ Radioact 61:257–269

    Article  CAS  Google Scholar 

  30. Damla N, Cevik U, Kobya AI, Celik A, Celik N, Van Grieken R (2010) Radiation dose estimation and mass attenuation coefficients of cement samples used in Turkey. J Hazard Mater 176:644–649

    Article  CAS  Google Scholar 

  31. Mujahid SA, Rahim A, Hussain S, Farooq M (2008) Measurements of natural radioactivity and radon exhalation rates from different brands of cement used in Pakistan. Radiat Prot Dosim 130:206–212

    Article  CAS  Google Scholar 

  32. El-Taher A, Makhluf S, Nossair A, Abdel Halim AS (2010) Assessment of natural radioactivity levels and radiation hazards due to cement industry. Appl Radiat Isot 68:169–174

    Article  CAS  Google Scholar 

  33. Puertas F, Alonso MM, Torres-Carrasco M, Rivilla P, Gasco C, Yagüe L, Suárez JA, Navarro N (2015) Radiological characterization of anhydrous/hydrated cements and geopolymers. Constr Build Mater 101:1105–1112

    Article  Google Scholar 

  34. Lee S-C, Kim C-K, Lee D-M, Kang H-D (2001) Natural radionuclides contents and radon exhalation rates in building materials used in South Korea. Radiat Prot Dosim 94:269–274

    Article  CAS  Google Scholar 

  35. Chinchón-Payá S, Piedecausa B, Hurtado S, Sanjuán MA, Chinchón S (2011) Radiological impact of cement, concrete and admixtures in Spain. Radiat Meas 46:734–735

    Article  Google Scholar 

  36. Stojanovska Z, Nedelkovski D, Ristova M (2010) Natural radioactivity and human exposure by raw materials and end product from cement industry used as building materials. Radiat Meas 45:969–972

    Article  CAS  Google Scholar 

  37. Bou-Rabee F, Bem H (1996) Natural radioactivity in building materials utilized in the state of Kuwait. J Radioanal Nucl Chem 213(2):143–149

    Article  CAS  Google Scholar 

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Acknowledgements

The authors would like to thank the coordination tasks of Marina Romay at OFICEMEN, and the participation of the Spanish cement companies’ members of that Association.

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Correspondence to Miguel Ángel Sanjuán.

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Sanjuán, M.Á., Suarez-Navarro, J.A., Argiz, C. et al. Assessment of radiation hazards of white and grey Portland cements. J Radioanal Nucl Chem 322, 1169–1177 (2019). https://doi.org/10.1007/s10967-019-06824-y

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