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Production and isolation of 197m,gHg

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Abstract

A new procedure has been developed for isolating no-carrier-added 197m,gHg from 20 to 25 MeV α-particle irradiations of high purity Pt foils. A previously published procedure for isolation of 197m,gHg from 12 to 15 MeV proton irradiations of Au foils has been further characterized. From these procedures two separate methods have been established to isolate, with high separation factors, 197m,gHg from Pt to Au target materials.

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References

  1. Walther M, Lebeda O, Preusche S, Pietzsch H-J, Steinback J (2017) Theranostic mercury part 1: a new Hg/Au separation by a resin based method. AIP Conf Proc 1845:020023

    Article  CAS  Google Scholar 

  2. Walther M, Preusche S, Bartel S, Wunderlich G, Freudenberg R, Steinbach J, Pietzsch H-J (2015) Theranostic mercury: 197(m)Hg with high specific activity for imaging and therapy. Appl Radiat Isot 97:177–181

    Article  CAS  PubMed  Google Scholar 

  3. Greif RL, Sullivan WJ, Jacobs GS, Pitts RF (1956) Distribution of radiomercury administered as labelled chlormerodrin (Neohydrin) in the kidneys of rats and dogs. J Clin Investig 35:38–43

    Article  CAS  PubMed  Google Scholar 

  4. Mantricali B (1969) Brain scanning by means of 197Hg-labelled neohydrin. Psychiatr Neurol Neurochir 72:89–95

    Google Scholar 

  5. Chodil G, Jopson RC, Mark H, Swift CD, Thomas RG, Yates MK (1967) (p,n) and (p,2n) cross sections on nine elements between 7.0 and 15.0 MeV. Nucl Phys A 93:648–672

    Article  CAS  Google Scholar 

  6. Sudar S, Qaim SM (2006) Cross sections for the formation of 195Hgm,g, 197Hgm,g, and 196Aum,g in α and 3He-particle induced reactions on Pt: effect of level density parameters on the calculated isomeric cross-section ratio. Phys Rev C 73:034613

    Article  CAS  Google Scholar 

  7. Wilkniss PE, Beach LA, Marlow KW (1972) Production of carrier-free 197m,197Hg with a cyclotron. Radiochim Acta 17:110–113

    Article  CAS  Google Scholar 

  8. Hara T, Lio M, Hirata M, Karasawa T (1973) Cyclotron production of 197mHg and its use for lung tumor imaging. Int J Appl Radiat Isot 24:661

    Article  CAS  PubMed  Google Scholar 

  9. Mandal S, Nayak D (2010) Production, separation and speciation of no-carrier-added Hg radionuclides using greener methodologies. Radiochim Acta 98:45–51

    Article  CAS  Google Scholar 

  10. Ghosh K, Lahiri S, Maiti M (2016) Separation of no-carrier-added 195m,gHg, 197mHg from Au target by ionic liquid and salt based aqueous biphasic systems. J Radioanal Nucl Chem 310:1381–1396

    Article  CAS  Google Scholar 

  11. Despotopulos JD, Kmak KN, Gharibyan N, Brown TA, Grant PM, Henderson RA, Moody KJ, Tumey SJ, Shaughnessy DA, Sudowe R (2015) Production and isolation of carrier-free homologs of flerovium and element 115 at the Lawrence Livermore National Laboratory Center for Accelerator Mass Spectrometry. J Radioanal Nucl Chem 308:567–572

    Article  CAS  Google Scholar 

  12. Rieman W, Walton HF (1970) Ion exchange in analytical chemistry: international series of monographs in analytical chemistry, vol 38. Pergamon Press, Oxford

    Google Scholar 

  13. National Nuclear Data Center “NNDC” (2013) Brookhaven National Laboratory. http://www.nndc.bnl.gov/. Accessed 4 Mar 2018

  14. Kraus KA, Nelson F (1955) Distribution coefficients for adsorption of elements onto Dowex-A-1 anion exchange resin from hydrochloric acid. Proc of the First U.N. Conf Peac Uses Energy 7:113

    Google Scholar 

  15. Faris JP, Buchanan RF (1964) Anion exchange characteristics of elements in nitric acid medium. Anal Chem 36:1157–1158

    Article  CAS  Google Scholar 

  16. Marsh SF, Alarid JE, Hammond CF, McLeod MJ, Roensch FR, Rein JE (1978) Anion exchange of 58 elements in hydrobromic and in hydroiodic acid. Los Alamos National Laboratory Report LA-7084

  17. Silver GL (1975) The dissolution and recovery of iridium in a nitrate system. J Less Common Met 40:265–267

    Article  CAS  Google Scholar 

  18. Despotopulos JD (2015) Studies of flerovium and element 115 homologs with macrocyclic extractants (Doctoral dissertation). ProQuest Ann Arbor 3715057:224

Download references

Acknowledgements

The authors would like to thank the CAMS facility staff at LLNL, specifically Scott Tumey, Thomas Brown and Graham Bench for providing beam time and expertise to the production of radionuclides used in this study. This study was performed under the auspices of the U.S. Department of Energy by Lawrence Livermore National Laboratory under Contract DE-AC52-07NA27344. This work was funded by the Laboratory Directed Research and Development Program at LLNL under project tracking code 17-LW-035.

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Correspondence to John D. Despotopulos.

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Despotopulos, J.D., Kmak, K.N. & Shaughnessy, D.A. Production and isolation of 197m,gHg. J Radioanal Nucl Chem 317, 985–989 (2018). https://doi.org/10.1007/s10967-018-5927-9

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  • DOI: https://doi.org/10.1007/s10967-018-5927-9

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