Abstract
Following the expression of the need for an americium (Am) standard and particularly for one with a certified americium-243 (243Am) content, the Commissariat à l’Energie Atomique et aux Energies Alternatives (CEA)/Direction de l’Energie Nucléaire of Marcoule and the European Commission Joint Research Center in Geel carried out a collaborative project for the production of a certified reference material enriched in 243Am. CEA’s Commission d’ETAblissement des Méthodes d’Analyse organized an interlaboratory comparison on this material prior to the issuing of its certificate. The usefulness of an interlaboratory comparison to assess the measurement capabilities in the field and to confirm the provisional certified values for the amount contents of 243Am, 241Am, total Am, the isotopic composition and the molar mass of Am has been demonstrated. Furthermore this interlaboratory comparison enabled to derive an indicative value for the n(242mAm)/n(243Am) isotope amount ratio.
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References
(2012) Cycle du combustible nucléaire: combustibles usés et déchets radioactifs. Les Sélections, Techniques de l’Ingénieur, Editions T.I., Paris
Balsley SD (2014) Report of the 2014 technical meeting on nuclear reference materials for destructive analysis in the nuclear fuel. IAEA SAL, 2–4 Sept 2014, Vienna
The Nuclear Security Summit 2016. http://www.nss2016.org/. Accessed 18 Jan 2019
Lin Z, Berne A, Cummings B, Filiben JJ (2002) Inn KGW. Appl Radiat Isot 56:57–63
Aggarwal SK (2018) Mass Spectrom Rev 37:43–56
ISO 17034:2016, ISO/CASCO, General requirements for the competence of reference material producers
Crozet M, Roudil D, Bertorello C, Maillard C, Rivier C, Jakopič R, Fankhauser A, Aregbe Y, Richter S, Altzitzoglou T (2016) Poster at the European Safeguards Research & Development Association (ESARDA) annual meeting
ISO 13528:2015, ISO/TC69/SC6, Statistical methods for use in proficiency testing by interlaboratory comparison
ISO 5725:1994, ISO/TC69/SC6, Accuracy (trueness and precision) of measurement methods and results, 1994
JMP® 13.0.0 (Statistical Discovery), SAS Institute Inc., http://www.jmp.com/software/
Rivier C, Désenfant M, Crozet M, Rigaux C, Roudil D, Tufféry B, Ruas A (2014) Accred Qual Assur 19:269–274
Cox M (2002) Metrologia 39:589–595
Cox M, Harris PM (2004) Meas Technol 47:102–111
Laboratoire National Henri Becquerel (LNHB) (2015) Mini table de radionucléides, EDP Science
Grubbs FE (1969) Technometrics 11(1):1–21
Jakopič R, Fankhauser A, Aregbe Y, Crozet M, Maillard M, Richter S, Rivier C, Roudil D, Altzitzoglou T, Pommé S, Marouli N. Tzika F (2017) Preparation and certification of 243Am spike reference material: IRMM-0243, certification report EUR 28748 EN. https://doi.org/10.2760/40283. ISBN:978-92-79-72281-3
Acknowledgements
The authors thank all the ILC participants i.e. Karsruhe Institute of Technology (KIT), JRC Karsruhe, Laboratoire d’Analyses d’ATalante (L2AT), Laboratoire de développement Analytique Nucléaire Isotopique et Elémentaire (LANIE), Laboratoire de Valduc, Lawrence Livermore National Laboratory (LLNL), Los Alamos National Laboratory (LANL), Oak Ridge National Laboratory (ORNL).
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Crozet, M., Roudil, D., Maillard, C. et al. Contribution of an interlaboratory comparison to the certification of the STAM/IRMM-0243 243Am reference material. J Radioanal Nucl Chem 319, 717–725 (2019). https://doi.org/10.1007/s10967-018-06404-6
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DOI: https://doi.org/10.1007/s10967-018-06404-6