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Radionuclide activities and elemental concentrations in sediments from a polluted marine environment (Saronikos Gulf-Greece)

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Abstract

The levels and depth distributions of the natural radionuclides 238U, 232Th, 226Ra, 40K and the man-made 137Cs were analyzed by γ-ray spectrometry, while the concentrations of 26 chemical elements were measured by INAA in sediment samples collected from the organic mud layer that covers the Keratsini–Psitalia strait, Saronikos gulf (Greece). The average activity concentration values of 226Ra, 232Th and 40K were lower when compared, whereas that of 238U was comparable to the average Greek and world values. The elemental contamination of the sediments was estimated on the basis of the calculated EF values. The results revealed high EF values of As, Br, Cr, Ni, Sb, Se, Zn ranging from 160 for Br to 10 for Cr, whose main sources are probable related to contaminated sewage outfall from the area of Athens and the Piraeus Harbour.

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References

  1. Theodorou IA, Perissoratis C (1991) Environmental consideration for design of the Athens Sea Outfall, Saronikos Gulf, Greece. Environ Geol Water Sci 17:223–248

    Article  Google Scholar 

  2. Klironomos D, Kotronakis A, Christodoulou D, Gkaragkouni A, Papatheodorou G, Frentinos G (2004) Marine geographical information system (GIS): an environmental implementation in Psitalia–Keratsini Strait, Saronikos Gulf, Greece. Geogr Conf EGE 1:262–269

    Google Scholar 

  3. Papakostidis G, Grimanis PA, Zafiropoulos D (1975) Heavy metals in sediments from the Athens sewage outfall area. Mar Pollut Bull 6:136–139

    Article  CAS  Google Scholar 

  4. Grimanis PA, Vassilaki-Grimani M, Griggs BG (1977) Pollution studies of trace elements in sediments from the Upper Saronikos Gulf, Greece. J Radioanl Nucl Chem 37:761–773

    Article  CAS  Google Scholar 

  5. Voutsinou-Taliadouri F (1981) Metal pollution in the Saronikos Gulf. Mar Pollut Environ 12:163–168

    Article  CAS  Google Scholar 

  6. Galanopoulou S, Vgenopoulos A, Conispoliatis N (2009) Anthropogenic heavy metal pollution in the surficial sediments of the Keratsini Harbour, Saronikos Gulf, Greece. Water Air Soil Pollut 202:121–130

    Article  CAS  Google Scholar 

  7. Friligos N (1985) Impact on phytoplacton populations of sewage discharges in the Saronikos Gulf (West Aegean). Water Res 19:1107–1118

    Article  CAS  Google Scholar 

  8. Papaefthymiou H, Papatheodorou G, Moustakli A, Christodoulou D, Geraga M (2007) Natural radionuclides and 137Cs distributions and their relationship with sedimentological processes in Patras harbour, Greece. J Environ Radioact 94:55–74

    Article  CAS  Google Scholar 

  9. Linsley G, Sjoblom KL, Cabianca T (2008) Overview of the point sources of anthropogenic radionuclides in the oceans. In: Livingston HD (ed) Marine radioactivity, radioactivity in the environment, vol 6. Elsevier, Amsterdam Series Ed. MS Baxter

    Google Scholar 

  10. Papaefthymiou H, Athanasopoulos D, Papatheodorou G, Iatrou M, Geraga M, Christodoulou D, Kordella S, Fakiris E, Tsikouras B (2013) Uranium and other natural radionuclides in the sediments of a Mediterranean fjord-like embayment, Amvrakikos Gulf (Ionian Sea). J Environ Radioact 122:43–54

    Article  CAS  Google Scholar 

  11. Lysandrou M, Pashalidis I (2008) Uranium chemistry in stack solutions and leachates of phosphogypsum disposed at a coastal area in Cyprus. J Environ Radioact 99:359–366

    Article  CAS  Google Scholar 

  12. Gulin SB, Mirzoyeva NYu, Egorov VN, Polikarpov GG, Sidorof IG, Proskurnin VYu (2013) Secondary radioactive contamination of the Black Sea after Chernobyl accident: recent levels, pathways and trends. J Environ Radioact 124:50–56

    Article  CAS  Google Scholar 

  13. Cao L, Ishii N, Zheng J, Kagami M, Pan S, Tagami K, Uchida S (2017) Vertical distributions of Pu and radio cesium isotopes in sediments from Lake Inba after the Fukushima Daiichi Nuclear Power Plant accident: source identification and accumulation (2017). Appl Geochem 78:287–294

    Article  CAS  Google Scholar 

  14. Folk RL (1974) Petrology of sedimentary rocks. Hemphill’s Austin, Texas

    Google Scholar 

  15. Walkley A (1947) A critical examination of a rapid method for determining organic carbon in soils-effect variation in digestion conditions and of organic soil constituents. Soil Sci 63:251

    Article  CAS  Google Scholar 

  16. Karagiannidi Th, Papaefthymiou H, Papatheodorou G (2009) Radioactive impact of a bauxite beneficiation plant in the Itea Gulf (Gulf of Corinth, Greece). J Radioanal Nucl Chem 279(3):923–934

    Article  CAS  Google Scholar 

  17. Papaefthymiou H, Papatheodorou G, Christodoulou Geraga M, Moustakli A, Kapolos J (2010) Elemental concentrations in sediments of Patras Harbour, Greece, using INAA, ICP-MS and AAS. Microchem J 96:269–276

    Article  CAS  Google Scholar 

  18. Papatheodorou G, Demopoulou G, Lambrakis N (2006) A long-term study of temporal hydrochemical data in a shallow lake using multivariate statistical techniques. Ecol Model 193:759–776

    Article  Google Scholar 

  19. UNSCEAR (2000) Sources and effects of ionizing radiation, United Nations scientific committee on the effects of atomic radiation Report to the General Assembly with Scientific Annexes United Nations, New York

  20. Dowdall M, O’Dea J (2002) 226Ra/228U disequilibrium in an upland organic soil exhibiting elevated natural radioactivity. J Environ Radioact 59:91–104

    Article  CAS  Google Scholar 

  21. Saueia CHR, Mazzilli BP (2006) Distribution of natural radionuclides in the production and use of phosphate fertilizers in Brazil. J Environ Radioact 89:229–239

    Article  CAS  Google Scholar 

  22. Anderson RF, Fleisher MQ (1991) Uranium precipitation in Black Sea sediments. In: Isdar E, Murray JWM (eds) Black sea oceanography. Kluwer Academic Publishers, New York, pp 443–458

    Chapter  Google Scholar 

  23. Zheng Y, Anderson RF, van Geen A, Fleisher MQ (2002) Remobilization of authigenic uranium in marine sediments by bioturbation. Geochim Cosmochim Acta 66(10):1759–1772

    Article  CAS  Google Scholar 

  24. Friligos N (1982) Some consequences of the decomposition of organic matter in the Elefsis Bay, an anoxic basin. Mar Pollut Bull 13(3):103–106

    Article  CAS  Google Scholar 

  25. Laissaoui A, Mas JL, Hurtado S, Ziad N, Villa M, Benmansour M (2013) Radionuclide activities and metal concentrations in sediments of the Sebou Estuary, NW Morocco, following a flooding event. Environ Monit and Assess 185:5019–5029

    Article  CAS  Google Scholar 

  26. Ravisankar R, Chandramohan J, Chandrasekaran A, Prince Prakash Jebakumar J, Vijayalakshmi I, Vijayagopal P, Venkatraman B (2015) Assessments of radioactivity concentration of natural radionuclides and radiological hazard indices in sediment samples from the East coast of Tamilnadu, India with statistical approach. Mar Pollut Bull 97:419–430

    Article  CAS  Google Scholar 

  27. IAEA (1992) Sampling and analytical methodologies for instrumental neutron activation analysis of airborne particulate matter. Training course series No .4. International Atomic Energy Agency

  28. Wedepolh KH (1995) The composition of continental crust. Geochem Cosmochim Acta 59:1217

    Article  Google Scholar 

  29. Cuvier A, Pourcelot L, Probst A, Prunier J, Le Roux G (2016) Trace elements and Pb isotopes in soils and sediments impacted by uranium mining. Sci Total Environ 566–567:238–249

    Article  Google Scholar 

  30. Papaefthymiou H (2008) Elemental deposition in the vicinity of a lignite power plant in Southern Greece. J Radioanal Nucl Chem 275:433–439

    Article  CAS  Google Scholar 

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Correspondence to Helen Papaefthymiou.

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Papaefthymiou, H., Gkaragkouni, A., Papatheodorou, G. et al. Radionuclide activities and elemental concentrations in sediments from a polluted marine environment (Saronikos Gulf-Greece). J Radioanal Nucl Chem 314, 1841–1852 (2017). https://doi.org/10.1007/s10967-017-5600-8

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  • DOI: https://doi.org/10.1007/s10967-017-5600-8

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