Abstract
The presented study reports on the purification of molybdenum oxide, which is one of the important tasks of the Advanced Mo based Rare process Experiment in searching for the neutrinoless double beta (0νββ) decay of 100Mo. Purified MoO3 powder is used as initial material for further growth of radiopure monocrystals. As purification technique, double sublimation, co-precipitation with calcium chloride carrier, and precipitation of polyammonium molybdate from acidic media were used. Concentrations of impurities like Sr, Ba, Pb, Th and U were measured by ICP-MS and radioactive isotopes were checked by a HPGe detector at the YangYang underground Laboratory in Korea.
Similar content being viewed by others
References
Fukuda S et al (2001) Solar 8B and Hep neutrino measurements from 1258 days of super-kamiokande data. Phys Rev Lett 86(25):5651–5655
Mohapatra RN (2007) Theory of neutrinos: a white paper. Rep Prog Phys. doi:10.1088/0034-4885/70/11/R02
Giuliani A, Poves A (2012) Neutrinoless double-beta decay. Adv High Energy Phys. doi:10.1155/2012/857016
Gando A et al (2016) Search for Majorana neutrinos near the inverted mass hierarchy region with KamLAND-Zen. Phys Rev Lett. doi:10.1103/PhysRevLett.117.082503
Abgrall N et al (2014) The Majorana demonstrator neutrinoless double-beta decay experiment. Adv High Energy Phys. doi:10.1155/2014/365432
Alduino C et al (2017) CUORE sensitivity to 0νββ decay. Eur Phys J C. doi:10.1140/epjc/s10052-017-5098-9
Arnold R et al (2015) Result of the search for neutrinoless double-β decay in 100Mo with the NEMO-3 experiment. Phys Rev D. doi:10.1103/PhysRevD.92.072011
Alenkov V et al (2015) Technical design report for the AMoRE 0νββ decay search experiment. https://arxiv.org/pdf/1512.05957.pdf. Accessed 5 Sep 2017
Rahaman S (2008) Q values of the 76Ge and 100Mo double-beta decays. Phys Lett B. doi:10.1016/j.physletb.2008.02.047
Meija J et al (2013) Isotopic compositions of the elements 2013 (IUPAC technical report). Pure Appl Chem. doi:10.1515/pac-2015-0503
Alenkov VV (2013) Ultrapurification of isotopically enriched materials for 40Ca100MoO4 crystal growth. Inorg Mater. doi:10.1134/S0020168513120029
Firestone RB (1996) Table of isotopes, 8th edn. Wiley, New York
Shlegel VN, Berge L, Boiko RS (2014) Purification of molybdenum oxide, growth and characterization of medium size zinc molybdate crystals for the LUMINEU program. EPJ Web Conf. doi:10.1051/epjconf/20136503001
Shubin A, Kulinich Yu, Skorynin G et al (2006) Gas centrifuges in the production of high-purity volatile substances. In: Proc. XI Int Sci Conf physicochemical process in the selection of atoms and molecules and in laser, plasma, and nanotechologies, TsNIIATOMINFORM, Zvenigorod (Rus)
Somorjai G-A (1968) Mechanism of Sublimation. Science 162:755–760
Clarence D, Chiola V (1968) Process for purifying molybdenum trioxide. Patent no. US3393971 A. Patented 23 Jul 1968
Lu WA, Zhang GH, Jie DA, Chou KC (2015) Oxidation roasting of molybdenite concentrate. Trans Nonferr Met Soc. doi:10.1016/S1003-6326(15)64067-5
Kirby HW, Salutsky Murrell L (1964) NAS-NS 3057 the radiochemistry of radium. National Academy of Sciences - National Research Council. Nuclear Science Series
Scadden EM, Ballou NE (1960) NAS-NS 3009 the radiochemistry of molybdenum. National Academy of Sciences - National Research Council. Nuclear Science Series
Kujirai O, Yamada K, Fresenius KM (1991) Simultaneous determination of traces of impurities in high-purity molybdenum and molybdenum trioxide by coprecipitation and inductively coupled plasma-atomic emission spectrometry. J Anal Chem. doi:10.1007/BF00324398
Mogi F, Itoh K, Okamoto N, Narita M, Fujine M (1988) Determination of trace impurities in high-purity molybdenum and tungsten. Denki Seiko 59:263–270
Acknowledgements
We thank J.S. Choi and D. S. Leonard for ICP-MS measurements, and W.G. Kang and G.W. Kim for the HPGe measurements. This research was funded by the Institute for Basic Science (Korea) under project code IBS-R016-D1.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Gileva, O., Aryal, P., Karki, S. et al. Investigation of the molybdenum oxide purification for the AMoRE experiment. J Radioanal Nucl Chem 314, 1695–1700 (2017). https://doi.org/10.1007/s10967-017-5568-4
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10967-017-5568-4