Abstract
The mesoporous silica SBA-15 with short channels was prepared and added into the solution of polyvinyl chloride (PVC) to form the SBA-15-PVC membrane via the phase-inversion process. Under the optimized preparation conditions with 5 (wt%) of SBA-15 and 10 (wt%) of PVC, the adsorption capacity of uranium(VI) can reach 2,519.8 mg/m2 at pH 6. Nine repeated adsorption–desorption cycles were carried out, and the adsorption capacity is almost kept the same in the last eight cycles. Therefore, SBA-15-PVC membrane could be as a promising adsorbent for uranium(VI) from aqueous solutions with large adsorption capacity and reusability.
Similar content being viewed by others
References
Vivero-Escoto JL, Carboni M, Abney CW, deKrafft KE, Lin WB (2013) Organo-functionalized mesoporous silicas for efficient uranium extraction. Microporous Mesoporous Mater 180:22–31
Ozdemir T, Usanmaz A (2009) Use of poly(methyl methacrylate) in radioactive waste management: I. Radiation stability and degradation. Prog Nucl Energy 51:240–245
Manaka M, Seki Y, Okuzawa K, Watanabe Y (2008) Uranium sorption onto natural sediments within a small stream in central Japan. Limnology 9:173–183
Nie BW, Zhang ZB, Cao XH, Liu YH, Liang P (2013) Sorption study of uranium from aqueous solution on ordered mesoporous carbon CMK-3. J Radioanal Nucl Chem 295:663–670
Sarri S, Misaelides P, Zamboulis D, Papadopoulou L, Warchoł J (2013) Removal of uranium anionic species from aqueous solutions by polyethylenimine-epichlorohydrin resins. J Radioanal Nucl Chem 295:1731–1736
Carboni M, Abney CW, Taylor-Pashow KML, Vivero-Escoto JL, Lin WB (2013) Uranium sorption with functionalized mesoporous carbon materials. Ind Eng Chem Res 52:15187–15197
Bae SY, Southard GL, Murray GM (1999) Molecularly imprinted ion exchange resin for purification, concentration and determination of UO2 2+ by spectrophotometry and plasma spectrometry. Anal Chim Acta 397:173–181
Santos AE, Ladeira ACQ (2011) Recovery of uranium from mine waste by leaching with carbonate-based reagents. Environ Sci Technol 45:3591–3597
Koh M, Yoo J, Park Y, Bae D, Park K, Kim H, Kim H (2006) Supercritical CO2 extraction of uranium(VI) from HNO3 solution using N,N,N′,N′-tetrabutyl-3-oxapentanediamide. Ind Eng Chem Res 45:5308–5313
Semiao AJC, Rossiter HMA, Schafer AI (2010) Impact of organic matter and speciation on the behaviour of uranium in submerged ultrafiltration. J Membr Sci 348:174–180
Khedr MG (2013) Radioactive contamination of groundwater, special aspects and advantages of removal by reverse osmosis and nanofiltration. Desalination 321:47–54
Hua M, Zhang S, Pan B, Zhang W, Lv L, Zhang Q (2012) Heavy metal removal from water/wastewater by nanosized metal oxides: a review. J Hazard Mater 11:317–331
Ni Y, Jin L, Zhang L, Hong J (2010) Honeycomb-like Ni@C composite nanostructures: synthesis, properties and applications in the detection of glucose and the removal of heavy-metal ions. J Mater Chem 20:6430–6436
Tripathi A, Melo JS, D’Souza SF (2013) Uranium(VI) recovery from aqueous medium using novel floating macroporous alginate-agarose-magnetite cryobeads. J Hazard Mater 246:87–95
Beck JS, Vartuli JC, Roth WJ, Leonowicz ME, Kresge CT, Schmitt KD, Chu CTW, Olson DH, Sheppard EW (1992) A new family of mesoporous molecular sieves prepared with liquid-crystal template mechanism. J Am Chem Soc 114(27):10834–10843
Vidya K, Gupta NM, Selvam P (2004) Influence of pH on the sorption behaviour of uranyl ions in mesoporous MCM-41 and MCM-48 molecular sieves. Mater Res Bull 39:2035–2048
Zhao D, Feng J, Huo Q, Melosh N, Fredrickson GH, Chmelka BF, Stucky GD (1998) Triblock copolymer syntheses of mesoporous silica with periodic 50 to 300 angstrom pores. Science 279:548–552
Wang XH, Zhu GR, Gao CJ (2013) Adsorption of uranium(VI) on silica mesoporous material SBA-15 with short channels. CIESC J. 64:2480–2487
Wang XH, Zhu GR, Guo F (2013) Removal of uranium(VI) ion from aqueous solution by SBA-15. Ann Nucl Energy 56:151–157
Wang P, Zhu GR, Qi PF (2012) Preparation and adsorption properties of lithium-ion sieve membrane. J Funct Mater 22:3139–3142
Bodzek M, Konieczny K (1991) The influence of molecular mass of poly (vinyl chloride) on the structure and transport characteristics of ultrafiltration membranes. J Membr Sci 61:131–156
St John AM, Cattrall RW, Kolev SD (2012) Transport and separation of uranium(VI) by a polymer inclusion membrane based on di-(2-ethylhexyl) phosphoric acid. J. Membr Sci 409–410:242–250
Kadous A, Didi MA, Villemin D (2009) Extraction of Uranium(VI) using D2EHPA/TOPO based supported liquid membrane. J. Radioanal Nucl Chem 280:157–165
Kadous A, Didi MA, Villemin D (2011) Removal of uranium(VI) from acetate medium using Lewatit TP 260 resin. J Radioanal Nucl Chem 288:553–561
Karve M, Rajgor RV (2008) Amberlite XAD-2 impregnated organophosphinic acid extractant for separation of uranium(VI) from rare earth elements. Desalination 232:191–197
Chen SY, Tang CY, Chuang WT, Lee J, Tsai Y, Chan JCC, Lin C, Liu Y, Cheng S (2008) A facile route to synthesizing functionalized mesoporous SBA-15 materials with platelet morphology and short mesochannels. Chem Mater 20:3906–3916
Savvin SB (1964) Analytical applications of Arsenazo-III-II. Determination of thorium, uranium, protactinium, neptunium, hafnium and scandium. Talanta 11:1–6
Barnett MO, Jardineb PM, Brooksb SC, Selimc HM (2000) Adsorption and transport of uranium(VI) in subsurface media. Soil Sci Soc Am 64:908–917
Zhu GR, Wang P, Qi PF, Gao CJ (2014) Adsorption and desorption properties of Li+ on PVC-H1.6Mn1.6O4 lithium ion-sieve membrane. Chem Eng J 235:340–348
Gabriel U, Gaudet JP, Spadini L, Charlet L (1998) Reactive transport of uranyl in a goethite column: an experimental and modelling study. Chem Geol 151:107–128
Xu JS, Chen MS, Zhang CH, Yi ZJ (2013) Adsorption of uranium(VI) from aqueous solution by diethylenetriamine-functionalized magnetic chitosan. J Radioanal Nucl Chem 298:1375–1383
Xie SB, Zhang C, Zhou XH, Yang J, Zhang XJ, Wang JS (2009) Removal of uranium(VI) from aqueous solution by adsorption of hematite. J Environ Radioactiv 100:162–166
Jamali MR, Assadi Y, Shemirani F, Hosseini MRM, Kozani RR, Masteri-Farahani M, Salavati-Niasari M (2006) Synthesis of salicylaldehyde-modified mesoporous silica and its application as a new sorbent for separation, preconcentration and determination of uranium by inductively coupled plasma atomic emission spectrometry. Anal Chim Acta 579:68–73
Acknowledgments
This work is financially supported by the National Natural Science Foundation of China (No. 20803068, 21276246).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Gao, MW., Zhu, GR., Wang, XH. et al. Preparation of short channels SBA-15-PVC membrane and its adsorption properties for removal of uranium(VI). J Radioanal Nucl Chem 304, 675–682 (2015). https://doi.org/10.1007/s10967-014-3862-y
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10967-014-3862-y