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Molybdenum isotope fractionation in ion exchange reaction by using anion exchange chromatography

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Abstract

The isotope fractionation of Mo(VI) species using benzimidazole-type anion-exchange resins embedded in high-porous silica beads was investigated in various HCl solutions ranging in concentration from 0.1 to 11.2 M (M = mol/dm3) at 298 K. As a result, the plots of the slope coefficients of Mo(VI) species against the corresponding b values, which are parameter of the adsorbent–adsorbate relative affinity in the adsorption process, were found to be a good linear relationship and the isotope fractionation coefficients of Mo(VI) species were also obtained by using the isotope fractionation curve of Mo(VI) species.

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Acknowledgments

This work was partially supported by the Grant-in-Aid for Challenging Exploratory Research (KAKENHI No. 24656567).

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Authors and Affiliations

  1. Department of Nuclear System Safety Engineering, Graduate School of Engineering, Nagaoka University of Technology, 1603-1, Kamitomioka, Nagaoka, Niigata, 940-2188, Japan

    Yu Tachibana, Yuki Yamazaki & Tatsuya Suzuki

  2. Research Laboratory for Nuclear Reactors, Tokyo Institute of Technology, 2-12-1-N1-34, O-okayama, Meguro-ku, Tokyo, 152-8550, Japan

    Masao Nomura

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  1. Yu Tachibana
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  2. Yuki Yamazaki
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  4. Tatsuya Suzuki
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Correspondence to Tatsuya Suzuki.

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Tachibana, Y., Yamazaki, Y., Nomura, M. et al. Molybdenum isotope fractionation in ion exchange reaction by using anion exchange chromatography. J Radioanal Nucl Chem 303, 1429–1434 (2015). https://doi.org/10.1007/s10967-014-3510-6

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  • DOI: https://doi.org/10.1007/s10967-014-3510-6

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