Skip to main content
SpringerLink
Log in

Effect of γ irradiation on non-isothermal decomposition kinetics, X-ray diffraction pattern, infrared spectrum and antibacterial property of tris(1,2-diaminoethane)nickel(II)oxalate

  • Published:
Journal of Radioanalytical and Nuclear Chemistry Aims and scope Submit manuscript

Abstract

Thermal decomposition, X-ray diffraction pattern, infrared (IR) spectrum and antibacterial property of tris(1,2-diaminoethane)nickel(II)oxalate were studied before and after γ-irradiation. Irradiation enhanced thermal decomposition. From X-ray diffraction studies, unirradiated and irradiated samples of the complex are found to be tetragonal. A change in lattice parameters was observed upon irradiation. Position and intensity of IR bands of –NH2 and >C=O group were found to be changed upon irradiation. Antibacterial studies showed that irradiation induced activity towards B. cereus.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4

Similar content being viewed by others

References

  1. Abd El-Wahab MMM, Mahfouz RM (1996) Thermochim Acta 274:281–287

    Article  CAS  Google Scholar 

  2. Nayak H, Bhatta D (2000) Thermochim Acta 362:99–105

    Article  CAS  Google Scholar 

  3. Samuel J, Surendran A, Culas S (2013) J Radioanal Nucl Chem 295:53–61

    Article  CAS  Google Scholar 

  4. Krishnan G, Jayashri TA (2008) J Radioanal Nucl Chem 277:693–697

    Article  Google Scholar 

  5. Mousa MA, Summan AM, Al Sousi GN (1990) Thermochim Acta 165:23–29

    Article  CAS  Google Scholar 

  6. Krishnan G, Jayashri TA, Geetha Devi K (2009) Radiat Phys Chem 78:184–190

    Article  CAS  Google Scholar 

  7. Krishnan G, Jayashri TA, Sudha P (2009) Radiat Phys Chem 78:933–938

    Article  CAS  Google Scholar 

  8. Jordanovska V, Trojko R, Galesic N (1992) Thermochim Acta 198:369–380

    Article  CAS  Google Scholar 

  9. Vogel AI (1999) Text book of quantitative chemical analysis. Addison Wesley Longman, New York

    Google Scholar 

  10. Coats WA, Redfern JP (1964) Nature 201:68–69

    Article  CAS  Google Scholar 

  11. Freeman ES, Carroll B (1958) J Phys Chem 62:394–397

    Article  CAS  Google Scholar 

  12. Horowitz HH, Metzger G (1963) Anal Chem 35:1464–1468

    Article  CAS  Google Scholar 

  13. Nair SMK, James C (1984) Thermochim Acta 78:357–370

    Article  CAS  Google Scholar 

  14. Wendlandt WW (1986) Thermal analysis. Wiley, New York

    Google Scholar 

  15. Gal O, Petkovic LJ, Draganic I (1968) Int J Appl Radiat Isot 19:645–656

    Article  CAS  Google Scholar 

  16. Sestak J, Berggren G (1971) Thermochim Acta 3:1–12

    Article  CAS  Google Scholar 

  17. Satava V (1971) Thermochim Acta 2:423–428

    Article  CAS  Google Scholar 

  18. Sestak J (1971) Thermochim Acta 3:150–154

    Article  CAS  Google Scholar 

  19. Nair SMK, James C (1985) Thermochim Acta 83:387–389

    Article  CAS  Google Scholar 

  20. Lipson H, Steeple H (1979) Interpretation of X-ray powder diffraction patterns. Macmillan, London

    Google Scholar 

  21. West AR (1984) Solid state chemistry and its applications. Wiley, New York

    Google Scholar 

  22. Matsuhashi S, Kume T (1999) J Sci Food Agric 73:237–241

    Article  Google Scholar 

Download references

Acknowledgments

The authors are thankful to the authorities of Central University, Pondicherry for providing facilities for γ-irradiation. Grateful acknowledgements are also rendered to STIC, Cochin, CESS, Thiruvananthapuram and Department of Chemistry, University of Kerala for instrumental facilities.

Author information

Authors and Affiliations

  1. Department of Chemistry, University of Kerala, Trivandrum, 695581, Kerala, India

    T. A. Jayashri & K. Viji

  2. Department of Chemistry, University College, Trivandrum, 695034, Kerala, India

    G. Krishnan

Authors
  1. T. A. Jayashri
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. G. Krishnan
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. K. Viji
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to T. A. Jayashri.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Jayashri, T.A., Krishnan, G. & Viji, K. Effect of γ irradiation on non-isothermal decomposition kinetics, X-ray diffraction pattern, infrared spectrum and antibacterial property of tris(1,2-diaminoethane)nickel(II)oxalate. J Radioanal Nucl Chem 302, 1021–1026 (2014). https://doi.org/10.1007/s10967-014-3463-9

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10967-014-3463-9

Keywords

Search

Navigation