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First shrinkage parameters of Slovak bentonites considered for engineered barriers in the deep geological repository of high-level radioactive waste and spent nuclear fuel

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Abstract

The high potential of bentonites to volume changes depending on the water content is considered as their advantage for the engineered barriers in the deep geological repository of high-level radioactive waste and spent nuclear fuel because of swelling and self-healing of cracks in contact with water. On the other hand, drying may lead to opening of cracks and spaces between the bentonite blocks. This would increase the permeability and contamination risk around the hot container with high-level radioactive waste and spent nuclear fuel, especially if the host rock mass is dry. First shrinkage tests on four Slovak bentonites studied for engineered barriers were carried out. The water content at the shrinkage limit and the relative linear shrinkage are the first available shrinkage parameters received for the bentonite paste. The shrinkage hazard is higher in the best bentonites with high swelling potential—from Kopernica and Jelšový potok. The results indicated the necessity of further shrinkage tests to determine the relative linear and volume shrinkage of bentonite elements pressed of the loose bentonite powder of low water content.

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References

  1. Wilson Savage D, Bond A, Watson S, Pusch R, Bennett D (2011) Bentonite: a review of key properties, processes and issues for consideration in the UK context. Quinteesa report QRS-1378ZG-1.1

  2. Shaefers A, Fahland S (2014) In: Proceedings of the international conference on the performance of engineered barriers. Physical and chemical properties, behaviour and evolution. BGR, Hannover, Feb 6–7, p 522

  3. Slaninka I, Hók J, Franzen J (2007) Status and development of deep geological repository in Slovak Republic from geological point of view. Acta Montan Slovaca 1(12):17–23

    Google Scholar 

  4. Bauer V, Šofranko M, Stavnikovič M (2007) Research of the multibarrier system for an underground deposition of radioactive wastes. Acta Montan Slovaca 1(12):217–225

    Google Scholar 

  5. Galamboš M, Rosskopfová O, Rajec P (2011) Geotechnické požiadavky na bentonitové bariéry v hlbinných úložiskách pre rádioaktívny odpad a vyhoreté jadrové palivo. Bezpečnost jaderné energie 19(57) 7/8:38–44

  6. Galamboš M, Daňo M, Rosskopfová O, Šeršeň F, Kufčáková J, Adamcová R, Rajec P (2012) Effect of gamma-irradiation on adsorption properties of Slovak bentonites. J Radioanal Nucl Chem 292(2):481–492

    Article  Google Scholar 

  7. Galamboš M, Magula M, Daňo M, Osacký M, Rosskopfová O, Rajec P (2012) Comparative study of cesium adsorption on dioctahedral and trioctahedral smectites. J Radioanal Nucl Chem 293(3):829–837

    Article  Google Scholar 

  8. Galamboš M, Osacký M, Rosskopfová O, Krajňák A, Rajec P (2012) Comparative study of strontium adsorption on dioctahedral and trioctahedral smectites. J Radioanal Nucl Chem 293(3):889–897

    Article  Google Scholar 

  9. Krajňák A, Galamboš M, Rosskopfová O, Viglašová E, Rajec P (2012) Slovak bentonites as engineering barriers in radioactive waste management. In: European nuclear conference (ENC 2012), pp 135–139

  10. Galamboš M, Krajňák A, Rosskopfová O, Viglašová E, Adamcová R, Rajec P (2013) Adsorption equilibrium and kinetic studies of strontium on Mg-bentonite, Fe-bentonite and illite/smectite. J Radioanal Nucl Chem 298(2):1031–1040

    Article  Google Scholar 

  11. Jesenák K, Galamboš M, Daňo M, Kurek M, Rosskopfová O (2013) Determination of hydraulic properties of bentonite rocks. [Stanovenie hydraulických vlastností bentonitových hornín.] Bezpečnost jaderné energie 21(59) 11/12:332–336

  12. Adamcová R, Galamboš M, Durmeková T, Rosskopfová O, Krajňák A, Ekkertová P (2013) Pilot research on diffusion parameters of U-235 fission products in Slovak bentonites. In: XV international clay conference, 7–11 July

  13. Krajňák A, Viglašová E, Galamboš M (2014) Disposal, storage and deposit of spent nuclear fuel and high-level radioactive waste in Slovak republic. Bezpečnost jaderné energie (in press)

  14. Galamboš M, Krajňák A, Viglašová E (2014) Th final part of nuclear power engineering in Slovak Republic. Beuzpečnost jaderné energie (in press)

  15. Švandová J, Videnská K, Přikryl R (2013) Experimental evaluation of the influence of saturation media on the mineralogical and physicochemical stability of bentonites. Appl Clay Sci 86:1–10

    Article  Google Scholar 

  16. Mockovčiaková A, Orolínová Z, Škvarla J (2010) Enhancement of the bentonite properties. J Hazard Mater 180:274–281

    Article  Google Scholar 

  17. Kolaříková I, Přikryl R, Hanus R, Jelínek E (2005) Thermal loading of smectite-rich rocks: natural processes vs. laboratory experiments. Appl Clay Sci 29:215–223

    Article  Google Scholar 

  18. Přikryl R, Weishauptová Z (2010) Hierarchical porosity of bentonite-based buffer and its modification due to increased temperature and hydration. Appl Clay Sci 41:163–170

    Article  Google Scholar 

  19. Kolaříková I, Švandová J, Přikryl R, Vinšová H, Jedináková-Křižová V, Zeman J (2010) Mineralogical changes in bentonite barrier within Mock-Up-CZ experiment. Appl Clay Sci 47(1–2):10–15

    Article  Google Scholar 

  20. Madsen FT, Müller-Vonmoos M (1989) The swelling behaviour of clays. Appl Clay Sci 4(2):143–156

    Article  CAS  Google Scholar 

  21. Bucher F, Müller-Vonmoos M (1989) Bentonite as a containment barrier for the disposal of highly radioactive wastes. Appl Clay Sci 4(2):157–177

    Article  CAS  Google Scholar 

  22. Montes HG, Duplay J, Martinez L, Geraud Y, Rousset-Tournier B (2003) Influence of interlayer cations on the water sorption and swelling-shrinkage of MX80 bentonite. Appl Clay Sci 23:309–321

    Article  Google Scholar 

  23. Přikryl R, Ryndová T, Boháč J, Weishauptová Z (2003) Microstructures and physical properties of “backfill” clays: comparison of residual and sedimentary montmorillonite clays. Appl Clay Sci 23:149–156

    Article  Google Scholar 

  24. Montes-H G, Duplay J, Martinez L, Mendoza C (2003) Swelling-shrinkage kinetics of MX80 bentonite. Appl Clay Sci 22:279–293

    Article  CAS  Google Scholar 

  25. Montes-H G (2005) Swelling-shrinkage measurements of bentonite using coupled environmental scanning electron microscopy and digital image analysis. J Colloid Interface Sci 284(1):271–277

    Article  CAS  Google Scholar 

  26. Pusch R (1982) Mineral-water interactions and their influence on the physical behavior of highly compacted Na bentonite. Can Geotech J 19(3):381–387

    Article  CAS  Google Scholar 

  27. Komine H, Ogata N (1994) Experimental study on swelling characteristics of compacted bentonite. Can Geotech J 31(4):478–490

    Article  CAS  Google Scholar 

  28. Pusch R (1980) Swelling pressure of highly compacted bentonite. SKBF/KBS technical report no. 80-13

  29. Vejsada J, Jelínek E, Řanda Z, Hradil D, Přikryl R (2005) Sorption of cesium on smectite-rich clays from the Bohemian massif (Czech Republic) and their mixtures with sand. Appl Radiat Isot 62:91–96

    Article  CAS  Google Scholar 

  30. Xiaodong L, Přikryl R, Pusch R (2011) THMC-testing of three expandable clays of potential use in HLW repositories. Appl Clay Sci 52:419–427

    Article  Google Scholar 

  31. Wang Q, Tang AM, Cui Y-J, Delage P, Gatmin B (2012) Experimental study on the swelling behaviour of bentonite/claystone mixture. Eng Geol 124:59–66

    Article  Google Scholar 

  32. Hanuláková D, Zeman J, Vašíček R, Přikryl R, Kuchovský T (2013) Determination of pore water composition during long term interaction of bentonite substrates with water media: comparative study. Appl Clay Sci 80–81:69–75

    Article  Google Scholar 

  33. Subba Rao KS, Tripathy S (2003) Effect of aging on swelling and swell-shrink behaviour of a compacted expansive soil. ASTM Geotech Test J 26(1):36–46

    Google Scholar 

  34. Delage P (2006) Some microstructure effects on the behaviour of compacted swelling clays used for engineered barriers. Chin J Rock Mech Eng 25:721–732

    Google Scholar 

  35. Delage P, Cui YJ, Tang AM (2010) Clays in radioactive waste disposal. J Rock Mech Geotech Eng 2:111–123

    Google Scholar 

  36. Adamcova R, Haasova Y (2005) Selected physical properties of bentonite for the deposit of radioactive waste. Mineralia Slovaca 37:387–389

    Google Scholar 

  37. Mayor JC, Villar MV, Martin PL, Gens A, Velasco M (2014) Water uptake in the bentonite buffer—PEBS case 1. In: Shaefers A, Fahland S (eds) Proceedings of the international conference on the performance of engineered barriers. Physical and chemical properties, behaviour and evolution. BGR, Hannover, Feb 6–7, pp 15–22

  38. Pusch R, Knutsson S, Al-Taie L, Mohammed MH (2012) Optimal ways of disposal of highly redioactive waste. Nat Sci 4:906–918

    Google Scholar 

  39. BS 1377: Part 2 (1990) British standard methods of tests for soils for civil engineering purposes. Part 2. Classification tests

  40. DIN 18122-2 (2000) Deutsche Norm Baugrund. Zustandsgrenzen (Konsistenzgrenzen). Teil 2: Bestimmung der Schrumpfgrenze

  41. ONORM B 4411 (2009) Geotechnik - Untersuchung von Bodenproben. Bestimmung von Fliess-, Plastizitäts- und Schrumpfgrenze unter Einbeziehung der Vornorm ÖNORM CEN ISO/TS 17892-12

  42. Šucha V (2001) Íly v geologických procesoch. Acta Geologica, Universitas Comenianae, Bratislava

  43. Andrejkovičová S, Madejová J, Czímerová A, Galko I, Dohrmann R, Komadel P (2006) Mineralogy and chemistry of Fe-rich bentonite from the Lieskovec deposit (Central Slovakia). Geol Carpathica 57(5):371–378

    Google Scholar 

  44. Stríček I, Šucha V, Uhlík P, Madejová J, Galko I (2009) Mineral stability of Fe-rich bentonite in the Mock-Up-CZ experiment. Geol Carpathica 60(5):431–436

    Google Scholar 

  45. Osacký M, Šucha V, Czímerová A, Madejová J (2010) Reaction of smectites with iron in a nitrogen atmosphere at 75 °C. Appl Clay Sci 50:237–244

    Article  Google Scholar 

  46. Osacký M, Šucha V, Miglierini M, Madejová J (2012) Reaction of bentonites with pyrite concentrate after wetting and drying cycles at 80ºC: relevance to radioactive waste (Radwaste) storage. Clay Miner 47:465–479

    Article  Google Scholar 

  47. Brtáňová A, Melichová Z, Komadel P (2012) Removal of Cu2+ from aqueous solution by Slovak bentonites. Ceram Silik 56(1):55–60

    Google Scholar 

  48. Melichová Z, Hromada L (2013) Adsorption of Pb2+ and Cu2+ ions from aqueous solutions on natural bentonites. Pol J Environ Stud 22(2):457–464

    Google Scholar 

  49. Galamboš M, Kufčáková J, Rajec P (2009) Sorption of strontium on Slovak bentonites. J Radioanal Nucl Chem 281(3):347–357

    Article  Google Scholar 

  50. Galamboš M, Kufčáková J, Rajec P (2009) Adsorption of cesium on domestic bentonites. J Radioanal Nucl Chem 281(3):485–492

    Article  Google Scholar 

  51. Galamboš M, Kufčáková J, Rosskopfová O, Rajec P (2010) Adsorption of cesium and strontium on natrified bentonites. J Radioanal Nucl Chem 283(3):803–813

    Article  Google Scholar 

  52. Galamboš M, Paučová V, Kufčáková J, Rosskopfová O, Rajec P, Adamcová R (2010) Cesium sorption on bentonites and montmorillonite K10. J Radioanal Nucl Chem 284(1):5–64

    Google Scholar 

  53. Galamboš M, Rosskopfová O, Kufčáková J, Rajec P (2011) Utilization of Slovak bentonites in deposition of high-level radioactive waste and spent nuclear fuel. J Radioanal Nucl Chem 288(3):765–777

    Article  Google Scholar 

  54. Galamboš M, Suchánek P, Rosskopfová O (2012) Sorption of anthropogenic radionuclides on natural and synthetic inorganic sorbents. J Radioanal Nucl Chem 293(2):613–633

    Article  Google Scholar 

  55. Adamcova R, Frankovska J, Durmekova T (2009) Engineering geological clay research for a radioactive waste repository in Slovakia. Acta Geol Solvaca 1,2:71–82

  56. STN 72 1019 (1989) Slovak technical standard. Laboratory determination of shrinkage of soils

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Acknowledgments

This research was partly granted by the Ministry of Education, Science, Research and Sports of the Slovak Republic (project VEGA 1/0828/13).

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Authors and Affiliations

  1. Faculty of Natural Sciences, Comenius University in Bratislava, Mlynská Dolina, 842 15, Bratislava, Slovak Republic

    R. Adamcová, V. Suraba, A. Krajňák, O. Rosskopfová & M. Galamboš

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  1. R. Adamcová
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  2. V. Suraba
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Correspondence to M. Galamboš.

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Adamcová, R., Suraba, V., Krajňák, A. et al. First shrinkage parameters of Slovak bentonites considered for engineered barriers in the deep geological repository of high-level radioactive waste and spent nuclear fuel. J Radioanal Nucl Chem 302, 737–743 (2014). https://doi.org/10.1007/s10967-014-3292-x

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