Abstract
From extraction experiments and \( \gamma \)-activity measurements, the exchange extraction constants corresponding to the general equilibrium M+ (aq) + NaL+ (nb) ⇔ ML+ (nb) + Na+ (aq) taking place in the two–phase water–nitrobenzene system (M+= Li+, H3O+, NH4 +; L = calix[4]arene-bis(t-octylbenzo-18-crown-6); aq = aqueous phase, nb = nitrobenzene phase) were evaluated. Furthermore, the stability constants of the ML+ complexes in nitrobenzene saturated with water were calculated; they were found to increase in the following cation order: H3O+ < Li+ < NH4 +.
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Acknowledgments
This work was supported by the Grant Agency of Faculty of Environmental Sciences, Czech University of Life Sciences, Prague, Project No.: 42900/1312/3114 “Environmental Aspects of Sustainable Development of Society”, and by the Czech Ministry of Education, Youth, and Sports (Project MSM 6046137307).
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Makrlík, E., Selucký, P., Vaňura, P. et al. Solvent extraction of Li+, H3O+ and NH4 + into nitrobenzene by using sodium dicarbollylcobaltate and calix[4]arene-bis(t-octylbenzo-18-crown-6). J Radioanal Nucl Chem 295, 2171–2174 (2013). https://doi.org/10.1007/s10967-012-2255-3
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DOI: https://doi.org/10.1007/s10967-012-2255-3