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Synergistic extraction of some univalent cations into nitrobenzene by using cesium dicarbollylcobaltate and calix[4]arene-bis(t-octylbenzo-18-crown-6)

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Abstract

From extraction experiments and γ-activity measurements, the exchange extraction constants corresponding to the general equilibrium M+ (aq) + CsL+ (nb) ⇔ ML+ (nb) + Cs+ (aq) taking place in the two–phase water–nitrobenzene system (M+ = K+, Rb+, \( {\text{NH}}_{4}^{ + } \), Ag+, Tl+; L = calix[4]arene-bis(t-octylbenzo-18-crown-6); aq = aqueous phase, nb = nitrobenzene phase) were evaluated. Furthermore, the stability constants of the ML+ complexes in nitrobenzene saturated with water were calculated; they were found to increase in the following cation order: \( {\text{NH}}_{4}^{ + } \) < K+ < Ag+ < Rb+ < Tl+.

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Acknowledgments

This work was supported by the Grant Agency of Faculty of Environmental Sciences, Czech University of Life Sciences, Prague, Project No.: 42900/1312/3114 “Environmental Aspects of Sustainable Development of Society” and by the Czech Ministry of Education, Youth, and Sports (Project MSM 6046137307). The participation of BAM was sponsored by the Division of Chemical Sciences, Geosciences, and Biosciences, Office of Basis Energy Sciences, US Department of Energy.

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Authors and Affiliations

  1. Faculty of Environmental Sciences, Czech University of Life Sciences, Prague, Kamýcká 129, 165 21, Prague 6, Czech Republic

    E. Makrlík

  2. Nuclear Research Institute, 250 68, Řež, Czech Republic

    P. Selucký

  3. Department of Analytical Chemistry, Institute of Chemical Technology, Prague, Technická 5, 166 28, Prague 6, Czech Republic

    P. Vaňura

  4. Chemical Sciences Division, Oak Ridge National Laboratory, P. O. Box 2008, Oak Ridge, TN, 37831-6119, USA

    B. A. Moyer

Authors
  1. E. Makrlík
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  2. P. Selucký
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  3. P. Vaňura
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  4. B. A. Moyer
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Correspondence to E. Makrlík.

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Makrlík, E., Selucký, P., Vaňura, P. et al. Synergistic extraction of some univalent cations into nitrobenzene by using cesium dicarbollylcobaltate and calix[4]arene-bis(t-octylbenzo-18-crown-6). J Radioanal Nucl Chem 295, 1015–1018 (2013). https://doi.org/10.1007/s10967-012-1897-5

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  • DOI: https://doi.org/10.1007/s10967-012-1897-5

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