Abstract
Direct determination of uranium in the concentration range of 8 μg L−1 to mg L−1 in water samples originating from different geochemical environments has been done using Inductively Coupled Plasma-Optical Emission Spectroscopy (ICP-OES). Uranium detection with 2–3% RSD (relative standard deviation) has been achieved in water samples by optimizing the plasma power, argon and sheath gas flow. These parameters were optimized for three different emission lines of uranium at 385.958, 409.014 and 424.167 nm. Interference arising due to the variation in concentration of bicarbonate, sodium chloride, calcium chloride, Fe and dissolved organic carbon (DOC) on the determination of uranium in water samples was also cheeked as these are the elements which vary as per the prevailing geochemical environment in groundwater samples. The concentration of NaHCO3, CaCl2 and NaCl in water was varied in the range 0.5–2.0%; whereas Fe ranged between 1 and 10 μg mL−1 and DOC between 0.1–1%. No marked interference in quantitative determination of uranium was observed due to elevated level of NaHCO3, CaCl2 and NaCl and Fe and DOC in groundwater samples. Concentration of uranium was also determined by other techniques like adsorptive striping voltametry (AdSv); laser fluorimetry and alpha spectrometry. Results indicate distinct advantage for uranium determination by ICP-OES compare to other techniques.
Similar content being viewed by others
References
World Health Organization (2008) WHO/SDE/WSH/03.04/118
Singhal RK, Preetha J, Karpe R, Joshi VM, Kumar A, Ranade AK, Hegde AG (2009) J Radioanal Nucl Chem 280(1):141–148
Singhal RK, Joshi VM, Karpe R, Kumar A, Preetha J, Hegde AG (2007) Water Air Soil Pollut 184:17–27
Singhal RK, Joshi S, Tirumalesh K, Gurg RP (2004) J Radioanal Nucl Chem 261(1):73–78
Berner EK, Berner RA (1996) Global environment: water, air, and geo-chemical cycles. Prentical Hall, Upper Saddle River, p 376
Porcelli D, Swarzenski PW (2003) Rev Mineral Geochem 52:317–361
Sylvia S, Wagner W, Henze G (1995) Anal Chim Acta 305:154–158
Singhal RK, Narayanan U, Karpe R, Kumar A, Ranade AK, Ramachandran V (2009) J Appl Rad Isot 67(4):501–505
Pizetaand R, Branica IM (2001) Water Res 35:1915
Djogic R, Branica M (1993) Anal Chim Acta 281:291–297
Dampare SB, Nyorko B, Osae BJB, Anaho S, Serfor EHK, Asietlo DK, Armah Y, Nude Y (2005) J Radioanal Nucl Ch 265–1:53–59
Guogang JT, Innocenzi GP (2004) J Radioanal Nucl Ch 262:433–441
Choppin GR (2007) J Radioanal Nucl Chem 273(3):695–703
Mihai SA, Shaw G, Georgescu II, Hurtgen C (1997) J Radioanal Nuc Chem 221(1–2):203–205
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Singhal, R.K., Basu, H., Bassan, M.K.T. et al. Rapid and interference free determination of ultra trace level of uranium in potable water originating from different geochemical environments by ICP-OES. J Radioanal Nucl Chem 292, 675–681 (2012). https://doi.org/10.1007/s10967-011-1494-z
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10967-011-1494-z