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Adsorption of Nb, Ta and Pa on anion-exchanger in HF and HF/HNO3 solutions: Model experiments for the chemical study of Db

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Abstract

Anion-exchange behavior of the group-5 elements, Nb and Ta, and their pseudo homologue Pa in HF and HF/HNO3 solutions was investigated by a batch method to find suitable conditions for the anion-exchange experiment of element 105 (Dubnium, Db). We determined the distribution coefficients of those elements on the anion-exchange resin as a function of the F− and NO −3 concentrations. Clearly different anion-exchange behavior was observed among these elements. Based on the results, we discuss the fluoro-complex formation of each element and suggest experimental conditions for the study of fluoride complexation of Db.

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Authors and Affiliations

  1. Advanced Science Research Center, Japan Atomic Energy Agency, Tokai, Ibaraki, 319-1195, Japan

    Y. Kasamatsu, A. Toyoshima, H. Toume, K. Tsukada & Y. Nagame

  2. Nishina Center for Accelerator Based Science, RIKEN, Wako, Saitama, 351-0198, Japan

    H. Haba

  3. Graduate School of Science and Engineering, Tokyo Metropolitan University, Hachioji, Tokyo, 192-0397, Japan

    K. Akiyama

  4. Graduate School of Science, Osaka University, Toyonaka, Osaka, 560-0043, Japan

    T. Yoshimura

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  1. Y. Kasamatsu
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  2. A. Toyoshima
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  3. H. Haba
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  4. H. Toume
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Correspondence to Y. Kasamatsu.

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Kasamatsu, Y., Toyoshima, A., Haba, H. et al. Adsorption of Nb, Ta and Pa on anion-exchanger in HF and HF/HNO3 solutions: Model experiments for the chemical study of Db. J Radioanal Nucl Chem 279, 371–376 (2009). https://doi.org/10.1007/s10967-007-7320-6

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  • DOI: https://doi.org/10.1007/s10967-007-7320-6

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