Abstract
Extraction of microamounts of calcium, strontium and barium by a nitrobenzene solution of hydrogen dicarbollylcobaltate (H+B−) in the presence of dibenzo-18-crown-6 (DB18C6, L) has been investigated. The equilibrium data have been explained assuming that the complexes HL+, ML2+, ML 2+2 and MHL 3+2 (M2+ = Ca2+, Sr2+, Ba2+) are extracted into the organic phase. The values of extraction and stability constants of the species in nitrobenzene saturated with water have been determined.
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Makrlík, E., Vaňura, P. & Selucký, P. Extraction of microamounts of calcium, strontium and barium into nitrobenzene by using hydrogen dicarbollylcobaltate in the presence of dibenzo-18-crown-6. J Radioanal Nucl Chem 277, 549–554 (2008). https://doi.org/10.1007/s10967-007-7115-1
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DOI: https://doi.org/10.1007/s10967-007-7115-1