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Extraction distribution of microamounts of cesium in the two-phase water-HCl-nitrobenzene-benzo-18-crown-6-hydrogen dicarbollylcobaltate system

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Summary

Extraction of microamounts of cesium by a nitrobenzene solution of hydrogen dicarbollylcobaltate (H+B-) in the presence of benzo-18-crown-6 (B18C6,L) has been investigated. The equilibrium data have been explained assuming that the HL+, CsL+ and CsL complexes are extracted into the organic phase. The values of extraction and stability constants of the species in nitrobenzene saturated with water have been determined.

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Authors and Affiliations

  1. Faculty of Applied Sciences, University of West Bohemia, Husova 11, 306 14 Pilsen, Czech Republic

    E. Makrlík

  2. Prague Institute of Chemical Technology, Technická 5, 166 28 Prague, Czech Republic

    P. Vaňura

  3. Nuclear Research Institute, 250 68 Řež, Czech Republic

    P. Selucký

Authors
  1. E. Makrlík
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  2. P. Vaňura
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  3. P. Selucký
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Makrlík, E., Vaňura, P. & Selucký, P. Extraction distribution of microamounts of cesium in the two-phase water-HCl-nitrobenzene-benzo-18-crown-6-hydrogen dicarbollylcobaltate system. J Radioanal Nucl Chem 268, 627–629 (2006). https://doi.org/10.1007/s10967-006-0214-6

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  • DOI: https://doi.org/10.1007/s10967-006-0214-6

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