Abstract
Extensive experiments with rotationally moulded polyethylene halloysite nanocomposites have been conducted. Previous studies regarding the use of filler materials in rotational moulding often report problems with agglomerations or inward migration of the filler. Despite the previous advances in machine adaptations and mould configurations to apply internal pressure, this study has focused mainly on non-pressurized composite production. Halloysite is a natural, nano-size, mineral clay with different reactivities from the internal aluminol and external siloxane surfaces. Due to its morphology and chemical nature, halloysite is easier to process compared to other fillers and achieves good particle dispersion, making it a potential candidate for reinforcing rotationally moulded products. In this study, nanoparticle-reinforced composites containing halloysite with medium density or high density polyethylene were produced by rotational moulding. The influence of halloysite on the melt flow index and mechanical performance, tensile, flexural and impact properties, were investigated.
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References
Crawford R.J. and Throne J.L. (2001) Rotational molding technology. Williams Andrew Publishing/Plastics Design Library, Norwich, USA, 2001
Crawford RJ, Kearns MP (2003) Practical guide to rotational Moulding. Rapra Technology Limited, Telford, UK
Lescher P.E. (2010) Moulding of water-free thermoplastic starch blends. Ph.D. Thesis, The University of Auckland
Yan W, Lin R, Bhattacharyya D (2006) Particulate reinforced rotationally moulded polyethylene composites–mixing methods and mechanical properties. Compos Sci Technol 66(13):2080–2088
Yan W, Lin RJT, Bickerton S, Bhattacharyya D (2003) Rotational moulding of particulate reinforced polymeric shell structures. Mater Sci Forum 437–438:235–238
Ortega Z, Monzón MD, Benítez AN, Kearns M, McCourt M, Hornsby PR (2013) Banana and abaca fiber-reinforced plastic composites obtained by rotational molding process. Mater Manuf Process 28(8):879–883
Torres FG, Aguirre M (2003) Rotational moulding and powder processing of natural fibre reinforced thermoplastics. Int Polym Process 18(2):204–210
Lee SM (1992) Handbook of composite reinforcements. Wiley, California, USA
Gogos G (2004) Bubble removal in rotational molding. Polym Eng Sci 44(2):388–394
Harkin-Jones E, Crawford RJ (1996) Mechanical properties of rotationally molded nyrim. Polym Eng Sci 36(5):615–625
Steinberg AH, Petruccelli F, Lucas ME, Zlatkevich L (1985) Rotational molding multilayered articles. US Patent No 4:548,779
Lin R, Bhattacharyya D, Fakirov S (2006) Mechanical properties of rotationally molded PET microfibril reinforced composites. International Journal of Modern Physics B 20(25n27):4613–4618
Jayaraman K., Lin R., Bose D., Maarouf M. (2007) Natural fibre-reinforced thermoplastics processed by rotational moulding Advanced Materials Research Vol 29 Trans Tech Publications
Yuan X, Easteal A, Bhattacharyya D (2007) Mechanical performance of rotomoulded wollastonite-reinforced polyethylene composites. International Journal of Modern Physics B 21(07):1059–1066
Liu S, Peng K (2010) Rotational molding of polycarbonate reinforced polyethylene composites: processing parameters and properties. Polym Eng Sci 50(7):1457–1465
Joussein E, Petit S, Churchman J, Theng B, Righi D, Delvaux B (2005) Halloysite clay minerals—a review. Clay Miner 40(4):383–426
Yuan P, Tan D, Annabi-Bergaya F (2015) Properties and applications of halloysite nanotubes: recent research advances and future prospects. Appl Clay Sci 112:75–93
Rawtani D, Agrawal YK (2012) Multifarious applications of halloysite nanotubes: a review. Rev Adv Mater Sci 30:282–295
Pedrazzoli D, Pegoretti A, Thomann R, Kristóf J, Karger-Kocsis J (2015) Toughening linear low-density polyethylene with halloysite nanotubes. Polym Compos 36(5):869–883
Guth E (1945) Theory of filler reinforcement. Journal of Applied Physics 16:20–25
Nielsen LE, Landel RF (1994) Mechanical properties of polymers and composites. Marcel Dekker Inc.
Verbeek CJR (2003) The influence of interfacial adhesion, particle size and size distribution on the predicted mechanical properties of particulate thermoplastic composites. Mater Lett 57(13):1919–1924
Nielsen LE (1966) Simple theory of stress–strain properties of filled polymers. J Appl Polym Sci 10:97–103
Nicolais L, Narkis M (1971) Stress–strain behavior of styrene-acrylonitrile/glass bead composites in the glassy region. Polym Eng Sci 11(3):194–199
Scott GD (1960) Packing of spheres. Nature 188:908–909
Joussein E, Petit S, Delvaux B (2007) Behavior of halloysite clay under formamide treatment. Appl Clay Sci 35(1):17–24
Verbeek CJR, Focke WW (2002) Modelling the Young's modulus of platelet reinforced thermoplastic sheet composites. Compos A: Appl Sci Manuf 33(12):1697–1704
Prashantha K, Lacrampe MF, Krawczak P (2011) Processing and characterization of halloysite nanotubes filled polypropylene nanocomposites based on a masterbatch route: effect of halloysites treatment on structural and mechanical properties. Express Polym Lett 5(4):295–307
Kinloch IA, Roberts SA, Windle AH (2002) A rheological study of concentrated aqueous nanotube dispersions. Polymer 43(26):7483–7491
Aladag B, Halelfadl S, Doner N, Maré T, Duret S, Estellé P (2012) Experimental investigations of the viscosity of nanofluids at low temperatures. Appl Energy 97:876–880
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Special thanks to the Ministry of Business, Innovation and Employment for financial support to the project, and to Vision Plastics New Zealand Ltd. for materials supply.
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Höfler, G., Lin, R.J.T. & Jayaraman, K. Rotational moulding and mechanical characterisation of halloysite reinforced polyethylenes. J Polym Res 25, 132 (2018). https://doi.org/10.1007/s10965-018-1525-3
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DOI: https://doi.org/10.1007/s10965-018-1525-3