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A new thin film composite nanofiltration membrane based on PET nanofiber support and polyamide top layer: preparation and characterization

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Abstract

The main objective of this study was to prepare thin film nanofibrous composite (TFNC) membranes based on self-support nanofibrous mats. To this end, polyethylene terephthalate nanofibrous supports were produced by electrospinning technique and subsequently heat treatment was performed to increase mechanical stability of the mats. Then, interfacial polymerization procedure was applied for preparation of TFNC nanofiltration membranes. For comparison, the thin film composite (TFC) nanofiltration membrane was prepared by the same conditions based on polyethersulfone ultrafiltration membrane prepared through phase inversion method. Chemical structure, morphology and mechanical properties were studied by using ATR-FTIR, SEM and tensile tests, respectively. Also, filtration performance was investigated by water flux, rejection, water contact angle and MWCO determination. Results showed that the TFNC nanofiltration membrane had higher salt rejection and four times higher water flux than the TFC nanofiltraion membrane (Na2SO4 rejection and pure water flux were (93 ± 3)%, (34 ± 2.3) L./m2h and (67 ± 4)%, (8 ± 0.9) L./m2h for TFNC and TFC, respectively). At the end, the filtration performance of PET TFNC-NF membrane was compared with other nanofibrous nanofiltration membranes.

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References

  1. Gleick PH (1998) The human right to water. Water Policy 1:487–503

    Article  Google Scholar 

  2. Nunes SP, Peinemann KV (2006) Membrane technology: in the chemical industry. John Wiley & Sons 15–38.

  3. Van der Bruggen B, Everaert K, Wilms D, Vandecasteele C (2001) Application of nanofiltration for removal of pesticides, nitrate and hardness from ground water: rejection properties and economic evaluation. J MembrSci 193:239–248

    CAS  Google Scholar 

  4. Schaefer AI, Fane AG, Waite TD (2005) Nanofiltration: principles and applications. Elsevier Advanced Technology, New York

    Google Scholar 

  5. Petersen RJ (1993) Composite reverse osmosis and nanofiltration membranes. J Membr Sci 83:81–150

    Article  CAS  Google Scholar 

  6. Jeong BH, Hoek EM, Yan Y, Subramani A, Huang X, Hurwitz G, Ghosh AK, Jawor A (2007) Interfacial polymerization of thin film nanocomposites: a new concept for reverse osmosis membranes. J Membr Sci 294:1–7

    Article  CAS  Google Scholar 

  7. Mansourpanah Y, Madaeni SS, Rahimpour A (2009) Fabrication and development of interfacial polymerized thin-film composite nanofiltration membrane using different surfactants in organic phase; study of morphology and performance. J MembrSci 343:219–228

    CAS  Google Scholar 

  8. Jin Y, Su Z (2009) Effects of polymerization conditions on hydrophilic groups in aromatic polyamide thin films. J Membr Sci 330:175–179

    Article  CAS  Google Scholar 

  9. Lay WCL, Zhang J, Tang C, Wang R, Liu Y, Fane AG (2012) Factors affecting flux performance of forward osmosis systems. J Membr Sci 394:151–168

    Article  Google Scholar 

  10. Shin M, Ishii O, Sueda T, Vacanti JP (2004) Contractile cardiac grafts using a novel nanofibrous mesh. Biomaterials 25:3717–3723

    Article  CAS  Google Scholar 

  11. Bhatnagar A, Sain M (2005) Processing of cellulose nanofiber-reinforced composites. J Reinf Plast Compos 24:1259–1268

    Article  CAS  Google Scholar 

  12. Gopal R, Kaur S, Ma Z, Chan C, Ramakrishna S, Matsuura T (2006) Electrospun nanofibrous filtration membrane. J Membr Sci 281:581–586

    Article  CAS  Google Scholar 

  13. Qin XH, Wang SY (2006) Filtration properties of electrospinning nanofibers. J Appl Polym Sci 102:1285–1290

    Article  CAS  Google Scholar 

  14. Fong H, Chun I, Reneker DH (1999) Beaded nanofibers formed during electrospinning. Polymer 40:4585–4592

    Article  CAS  Google Scholar 

  15. Wang X, Chen X, Yoon K, Fang D, Hsiao BS, Chu B (2005) High flux filtration medium based on nanofibrous substrate with hydrophilic nanocomposite coating. J Environ Sci Technol 39:7684–7691

    Article  CAS  Google Scholar 

  16. Park SJ, Cheedrala RK, Diallo MS, Kim C, Kim IS, Goddard III WA (2012) Nanofiltration membranes based on polyvinylidene fluoride nanofibrous scaffolds and crosslinked polyethyleneimine networks. J Nanopart Res 14:1–14

    CAS  Google Scholar 

  17. Yoon K, Hsiao BS, Chu B (2009) High flux nanofiltration membranes based on interfacially polymerized polyamide barrier layer on polyacrylonitrile nanofibrous scaffolds. J Membr Sci 326:484–492

    Article  CAS  Google Scholar 

  18. Wang X, Yeh TM, Wang Z, Yang R, Wang R, Ma H, Hsiao BS, Chu B (2014) Nanofiltration membranes prepared by interfacial polymerization on thin-film nanofibrous composite scaffold. Polymer 55:1358–1366

    Article  CAS  Google Scholar 

  19. Kaur S, Sundarrajan S, Gopal R, Ramakrishna S (2012) Formation and characterization of polyamide composite electrospun nanofibrous membranes for salt separation. J Appl Polym Sci 124:E205–E215

    Article  CAS  Google Scholar 

  20. Tang Z, Qiu C, McCutcheon JR, Yoon K, Ma H, Fang D, Lee E, Kopp C, Hsiao BS, Chu B (2009) Design and fabrication of electrospun polyethersulfone nanofibrous scaffold for high-flux nanofiltration membranes. J Polym Sci B Polym Phys 47:2288–2300

    Article  CAS  Google Scholar 

  21. Kaur S, Barhate R, Sundarrajan S, Matsuura T, Ramakrishna S (2011) Hot pressing of electrospun membrane composite and its influence on separation performance on thin film composite nanofiltration membrane. Desalination 279:201–209

    Article  CAS  Google Scholar 

  22. Hao J, Lei G, Li Z, Wu L, Xiao Q, Wang L (2013) A novel polyethylene terephthalate nonwoven separator based on electrospinning technique for lithium ion battery. J Membr Sci 428:11–16

    Article  CAS  Google Scholar 

  23. Ma Z, Kotaki M, Yong T, He W, Ramakrishna S (2005) Surface engineering of electrospun polyethylene terephthalate (PET) nanofibers towards development of a new material for blood vessel engineering. Biomaterials 26:2527–2536

    Article  CAS  Google Scholar 

  24. Veleirinho B, Rei MF, Lopes-DA-Silva JA (2008) Solvent and concentration effects on the properties of electrospun poly (ethylene terephthalate) nanofiber mats. J Polym Sci B Polym Phys 46:460–471

    Article  CAS  Google Scholar 

  25. Mahdavi H, Hosseinzadeh MT (2015) A suitable polyethersulfone membrane support for polyamide thin film composite nanofiltration membrane: preparation and characterization. J Iran Chem Soc 12(8):1347–1356

    Article  CAS  Google Scholar 

  26. Kaur S, Sundarrajan S, Rana D, Matsuura T, Ramakrishna S (2012) Influence of electrospun fiber size on the separation efficiency of thin film nanofiltration composite membrane. J Membr Sci 392:101–111

    Article  Google Scholar 

  27. Choi SS, Lee SG, Joo CW, Im SS, Kim SH (2004) Formation of interfiber bonding in electrospun poly (etherimide) nanofiber web. J Mater Sci 39:1511–1513

    Article  CAS  Google Scholar 

  28. Homaeigohar SS, Buhr K, Ebert K (2010) Polyethersulfone electrospun nanofibrous composite membrane for liquid filtration. J Membr Sci 365:68–77

    Article  CAS  Google Scholar 

  29. Lin JK, Ladisch MR, Patterson JA, Noller CH (1987) Determining pore size distribution in wet cellulose by measuring solute exclusion using a differential refractometer. J Biotechnol Bioeng 29:976–981

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. School of Chemistry, College of Science, University of Tehran, P.O. Box 14155-6455, Tehran, Iran

    Hossein Mahdavi & Mohsen Moslehi

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  1. Hossein Mahdavi
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  2. Mohsen Moslehi
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Correspondence to Hossein Mahdavi.

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Mahdavi, H., Moslehi, M. A new thin film composite nanofiltration membrane based on PET nanofiber support and polyamide top layer: preparation and characterization. J Polym Res 23, 257 (2016). https://doi.org/10.1007/s10965-016-1157-4

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  • DOI: https://doi.org/10.1007/s10965-016-1157-4

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