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Electrodeposition of polyaniline-montmorrilonite nanocomposite coatings on 316L stainless steel for corrosion prevention

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Abstract

The synthesis of polyaniline- montmorrilonite (MMT) nanocomposite coatings on 316L stainless steel (316L SS) surface has been investigated by using the galvanostatic method. The synthesized coatings were characterized by Fourier Transform Infrared Spectroscopy (FT-IR), UV-visible absorption spectrometry and Scanning Electron Microscopy (SEM). The anticorrosion performances of polyaniline-MMT nanocomposite coatings were investigated in 0.5 M HCl medium by the potentiodynamic polarization technique and Electrochemical Impedance Spectroscopy (EIS). The corrosion rate of polyaniline-MMT nanocomposite coated 316L SS was found ∼540 times lower than bare 316L SS and potential corrosion increased from −0.386 V versus Ag/AgCl for uncoated 316L SS to −0.040 V versus Ag/AgCl for polyaniline-MMT nanocomposite coated 316L SS electrodes. Electrochemical measurements indicate that polyaniline-MMT nanocomposite coated have good inhibiting properties with mean efficiency of ~99.8 % at 0.75 mA cm−2 current density applied on 316L SS corrosion in acid media. The results of this study clearly ascertain that the polyaniline-MMT nanocomposite has an outstanding potential to protect 316L SS against corrosion in an acidic environment.

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References

  1. Gopi D, Govindaraju KM, Kavitha L, Basha KA (2011) Prog Org Coat 71:11–18

    Article  CAS  Google Scholar 

  2. Shen GX, Chen YC, Lin CJ (2005) Thin Solid Films 489:130–136

    Article  CAS  Google Scholar 

  3. Ganash AA, Al-Nowaiser FM, Al-Thabaiti SA, Hermas AA (2013) J Solid State Electrochem 17:849–860

    Article  CAS  Google Scholar 

  4. Sathiyanarayanan S, Karpakam Kamaraj VK, Muthukrishnan S, Venkatachari G (2010) Surf Coat Technol 204:1426–1431

    Article  CAS  Google Scholar 

  5. Sabirneeza AAF, Subhashini S (2013) J Appl Polym Sci 127:3084–3092

    Article  CAS  Google Scholar 

  6. Negm NA, Ghuiba FM, Tawfik SM (2011) Corros Sci 53:3566–3575

    Article  CAS  Google Scholar 

  7. Mansfeld F, Breslin CB, Pardo A, Perez FJ (1997) Surf Coat Technol 90:224–228

    Article  CAS  Google Scholar 

  8. Ganash AA, Al-Nowaiser FM, Al-Thabaiti SA, Hermas AA (2011) Prog Org Coat 72:480–485

    Article  CAS  Google Scholar 

  9. Tang YC, Katsuma S, Fujimoto S, Hiromoto S (2006) Acta Biomater 2:709–715

    Article  Google Scholar 

  10. Okazaki Y, Gotoh E (2008) Corros Sci 50:3429–3438

    Article  CAS  Google Scholar 

  11. Malik MA, Włodarczyk R, Kulesza PJ, Bala H, Miecznikowski K (2005) Corros Sci 47:771–783

    Article  CAS  Google Scholar 

  12. Armelin E, Pla R, Lies F, Ramis X, Iribarren JI, Aleman C (2008) Corros Sci 50:721–728

    Article  CAS  Google Scholar 

  13. Le DP, Yoo YH, Kim JG, Cho SM, Son YK (2009) Corros Sci 51:330–338

    Article  CAS  Google Scholar 

  14. DeBerry DW (1985) J Electrochem Soc 132:1022–1026

    Article  CAS  Google Scholar 

  15. Kilmartin PA, Trier L, Wright GA (2002) Synth Met 131:99–109

    Article  CAS  Google Scholar 

  16. Galkowski M, Malik MA, Kulesza PJ, Bala H, Miecznikowski K, Wlodarezyk R, Adamezyk L, Chojak M (2003) J Electrochem Soc 150:B249–B253

    Article  CAS  Google Scholar 

  17. Gasparac R, Martin CR (2001) J Electrochem Soc 148:B138–B145

    Article  CAS  Google Scholar 

  18. Wessling B (1994) Adv Mater 6:226–228

    Article  CAS  Google Scholar 

  19. Cook A, Gabriel A, Laycoc NK (2004) J Electrochem Soc 151:B529–B535

    Article  CAS  Google Scholar 

  20. Hermas AA, Nakayama M, Ogura K (2005) Electrochim Acta 50:2001–2007

    Article  CAS  Google Scholar 

  21. Hermas AA, Nakayama M, Ogura K (2005) Electrochim Acta 50:3640–3647

    Article  CAS  Google Scholar 

  22. Somani PR (2002) Mater Chem Phys 77:81–85

    Article  Google Scholar 

  23. Ayad MM, Shenashin MA (2004) Eur Polymer J 40:197–202

    Article  CAS  Google Scholar 

  24. Huang J, Moore JA, Acquaye JH, Kaner RB (2005) Macromolecules 38:317–321

    Article  CAS  Google Scholar 

  25. Lim YS, Tan YP, Lim HN, Huang NM, Tan WT (2013) J Polym Res 20:156–164

    Article  CAS  Google Scholar 

  26. Kraljic M, Mandic Z, Duic L (2003) Corrs Sci 45:181–189

    Article  Google Scholar 

  27. Huh JH, Oh EJ, Cho JH (2005) Synth Met 153:13–16

    Article  CAS  Google Scholar 

  28. Zhang T, Zeng CL (2005) Electrochim Acta 50:4721–47274

    Article  CAS  Google Scholar 

  29. Alvial G, Matencio T, Neves BRA, Silva GG (2004) Electrochim Acta 49:3507–3516

    Article  CAS  Google Scholar 

  30. Trabelsi W, Dhouibi L, Matoussi F, Triki E (2005) Synth Met 151:19–24

    Article  CAS  Google Scholar 

  31. Torres FG, Arroyo OH, Gomez C (2007) J Thermoplast Compos Mater 20:207–223

    Article  CAS  Google Scholar 

  32. Vaisman J, Li L, Marom G, Kim JK (2007) Carbon 45:744–750

    Article  CAS  Google Scholar 

  33. Cong H, Zhang J, Radosz M, Shen Y (2007) J Membr Sci 294:178–185

    Article  CAS  Google Scholar 

  34. Geblinger N, Thiruvengadathan R, Regev O (2007) Compos Sci Technol 67:895–899

    Article  CAS  Google Scholar 

  35. Schmidt D, Shah D, Giannelis EP (2006) Curr Opinion Solid State Mater Sci 6:205–212

    Article  Google Scholar 

  36. Yu YH, Lin CY, Yeh JM, Lin WH (2003) Polymer 44:3553–3560

    Article  CAS  Google Scholar 

  37. Malinauskas A, Malinauskiene J, Ramanavicius A (2005) Nanotechnology 16:R51–R62

    Article  CAS  Google Scholar 

  38. Castagno KRL, Dalmoro V, Mauler RS, Azambuja DS (2010) J Polym Res 17:647–655

    Article  CAS  Google Scholar 

  39. Hackman I, Hollaway L (2006) Compos Part A 37:1161–1170

    Article  CAS  Google Scholar 

  40. Salavagione HJ, Diego CA, Selma T, Mohammed B, Abdelghani B, Emilia M (2008) Eur Polym J 44:1275–1284

    Article  CAS  Google Scholar 

  41. Yeh JM, Liou SJ, Lai CY, Wu PC (2001) Chem Mater 13:1131–1136

    Article  CAS  Google Scholar 

  42. Arora A, Choudhary V, Sharma DK (2011) J Polym Res 18:843–857

    Article  CAS  Google Scholar 

  43. Kim JW, Liu F, Choi HJ, Hong SH, Joo JS (2003) Polymer 44:289–293

    Article  CAS  Google Scholar 

  44. Yoshimoto S, Ohashi F, Ohnishi Y, Nonami T (2004) Synth Met 145:265–270

    Article  CAS  Google Scholar 

  45. Chang KC, Chen ST, Lin HF, Lin CY, Huang HH, Yeh JM, Yu YH (2008) Eur Polym J 44:13–23

    Article  CAS  Google Scholar 

  46. Lai MC, Chang KC, Yeh JM, Liou SJ, Hsieh MF, Chang HS (2007) Eur Polym J 43:4219–4228

    Article  CAS  Google Scholar 

  47. Yeh JM, Yao CT, Hsieh CF, Lin LH, Chen PL, JCh W, Yang HC, Wu CP (2008) Eur Polym J 44:3046–3056

    Article  CAS  Google Scholar 

  48. Shabani-Nooshabadi M, Ghoreshi SM, Behpour M (2011) Corros Sci 53:3035–3042

    Article  CAS  Google Scholar 

  49. Ghoreishi SM, Shabani-Nooshabadi M, Behpour M, Jafari Y (2012) Prog Org Coat 74:502–510

    Article  CAS  Google Scholar 

  50. Tallman DE, Levine KL, Siripirom C, Gelling VC, Bierwagen GP, Croll SG (2008) Appl Surf Sci 254:5452–5459

    Article  CAS  Google Scholar 

  51. Ashassi-Sorkhabi H, Seifzadeh D, Hosseini MG (2008) Corros Sci 50:3363–3370

    Article  CAS  Google Scholar 

  52. Roeper DF, Chidambaram D, Clayton CR, Halada GP (2008) Electrochim Acta 53:2130–2134

    Article  CAS  Google Scholar 

  53. Mulder WH, Sluyters JH, Pajkossy T, Nyikos L (1990) J Electroanal Chem 285:103–115

    Article  CAS  Google Scholar 

  54. Kim CH, Pyun SI, Kim JH (2003) Electrochim Acta 48:3455–3463

    Article  CAS  Google Scholar 

  55. Jorcin JB, Orazem ME, Pebere N, Tribollet B (2006) Electrochim Acta 51:1473–1479

    Article  CAS  Google Scholar 

  56. Sathiyanarayanan S, SyedAzim S, Venkatachari G (2007) Electrochim Acta 52:2068–2074

    Article  CAS  Google Scholar 

  57. Mahmoudian MR, Basirun WJ, Alias Y (2011) Appl Surf Sci 257:3702–3708

    Article  CAS  Google Scholar 

Download references

Acknowledgments

The authors are grateful to University of Kashan for supporting this work by Grant No (159194/7).

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Authors and Affiliations

  1. Department of Analytical Chemistry, Faculty of Chemistry, University of Kashan, Kashan, Iran

    Mehdi Shabani-Nooshabadi, Sayed Mehdi Ghoreishi, Yaser Jafari & Naser Kashanizadeh

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  1. Mehdi Shabani-Nooshabadi
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  2. Sayed Mehdi Ghoreishi
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  3. Yaser Jafari
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  4. Naser Kashanizadeh
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Correspondence to Mehdi Shabani-Nooshabadi.

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Shabani-Nooshabadi, M., Ghoreishi, S.M., Jafari, Y. et al. Electrodeposition of polyaniline-montmorrilonite nanocomposite coatings on 316L stainless steel for corrosion prevention. J Polym Res 21, 416 (2014). https://doi.org/10.1007/s10965-014-0416-5

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