Skip to main content

Advertisement

SpringerLink
Log in

Synthesis and characterization of self-crosslinked polyurethane/polyacrylate composite emulsion based on carbonyl–hydrazide reaction

  • Original Paper
  • Published:
Journal of Polymer Research Aims and scope Submit manuscript

Abstract

Self-crosslinkable aqueous polyurethane (PU)/polyacrylate (PA) composite emulsion was obtained by radical copolymerization. Fourier transform infrared spectroscopy (FT-IR) result shows that the cross-linking reaction between the carbonyl group and the hydrazine group has happened. The influence of the hydrazide-carbonyl molar ratio and the PA content on the properties of the composite emulsions and their films were investigated. The results show that, under the optimal hydrazide-carbonyl molar ratio (n (hydrazine group)/n (carbonyl group) =1:1), the water absorption is 10.56 %, and the mechanical properties and thermal stabilities are both improved. As the PA content increases from 0 wt% to 15 wt%, the tensile strength increases from 5.7 MPa to 7.3 MPa and the gel content increases from 70.3 % to 87 %.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Scheme 1
Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7

Similar content being viewed by others

References

  1. Lu YS, Richard CL (2007) New hybrid latexes from a soybean oil-based waterborne polyurethane and acrylics via emulsion polymerization. Biomacromolecules 8:3108–3114. doi:10.1021/bm700522z

    Article  CAS  Google Scholar 

  2. Biemond GJE, Braspenning K, Gaymans RJ (2008) Polyurethanes with monodisperse rigid segments based on a diamine–diamide chain extender. J Appl Polym Sci 1072:180–2189. doi:10.1002/app.27282

    Google Scholar 

  3. Ioan S, Mihaela L, Epure V, Ioanid A, Macocinschi D (2008) Macromolecular assemblies of segmented poly(ester urethane)s and poly(ether urethane)s. J Appl Polym Sci 107:1414–1422. doi:10.1002/app.24562

    Article  CAS  Google Scholar 

  4. Yang HY, Zhang XM, Duan LJ, Zhang MY, Gao GH, Zhang HX (2012) Synthesis and characterization of fluorescent PEG-polyurethane with free carboxyl groups. J Polym Res 19:1–7. doi:10.1007/s10965-012-9973-7

    Article  Google Scholar 

  5. Potolinca V, Buruiana E, Oprea S (2013) Dielectric behavior of polyurethane and polyurethane-urea elastomers with pyridine moieties in the main chain. J Polym Res 20:1–9. doi:10.1007/s10965-013-0237-y

    Article  CAS  Google Scholar 

  6. Wang L, Shen YD, Lai XJ, Li ZJ, Liu M (2011) Synthesis and properties of crosslinked waterborne polyurethane. J Polym Res 18:469–476. doi:10.1007/s10965-010-9438-9

    Article  CAS  Google Scholar 

  7. Brown RA, Coogan RG, Fortier DG, Reeve MS, Rega JD (2005) Comparing and contrasting the properties of urethane/acrylic hybrids with those of corresponding blends of urethane dispersions and acrylic emulsions. Prog Org Coat 52:73–84. doi:10.1016/j.porgcoat.2004.03.009

    Article  CAS  Google Scholar 

  8. Peruzzo PJ, Anbinder PS, Pardini OR, Vega J, Costa CA, Galembeck F, Amalvy JI (2011) Waterborne polyurethane/acrylate: comparison of hybrid and blend systems. Prog Org Coat 72:429–437. doi:10.1016/j.porgcoat.2011.05.016

    Article  CAS  Google Scholar 

  9. Zhang T, Wu WJ, Wang XJ, Mu YP (2010) Effect of average functionality on properties of UV-curable waterborne polyurethane-acrylate. Prog Org Coat 68:201–207. doi:10.1016/j.porgcoat.2010.02.004

    Article  CAS  Google Scholar 

  10. Nakayama Y (2010) Development of novel aqueous coatings which meet the requirements of ecology-conscious society: novel cross-linking system based on the carbonyl–hydrazide reaction and its applications. Prog Org Coat 51:280–299. doi:10.1016/j.porgcoat.2004.07.010

    Article  Google Scholar 

  11. Tillet G, Boutevin B, Ameduri B (2011) Chemical reactions of polymer cross-linking and post-crosslinking at room and medium temperature. Prog Polym Sci 36:191–217. doi:10.1016/j.progpolymsci.2010.08.003

    Article  CAS  Google Scholar 

  12. DEP Mestach, MJJ Weber, G Delaunoit, WLS Pilaszek, Aqueous crosslinkable polymer compositions for use in coatings. EP Patent 989163

  13. Hirose M, Zhou JH, Nagai K (2000) The structure and properties of acrylic-polyurethane hybrid emulsions. Prog Org Coat 38:27–34. doi:10.1016/S0300-9440(99)00081-8

    Article  CAS  Google Scholar 

  14. Fadida T, Lellouche JP (2012) Poly-N-(4-benzoylphenyl)methacrylamide nanoparticles: preparation, characterization, and photoreactivity features. J Polym Res 19:1–12. doi:10.1007/s10965-012-0023-2

    Article  CAS  Google Scholar 

  15. He LB, Chao DM, Wang XT, Jia XT, Wang C, Liu XC (2012) Synthesis and properties of novel electroactive poly(aryl ether ketone) bearing oligoaniline segments. J Polym Res 19:1–8. doi:10.1007/s10965-012-9999-x

    Article  Google Scholar 

  16. Chai SL, Jin MM, Tan HM (2008) Comparative study between core-shell and interpenetrating network structure polyurethane/polyacrylate composite emulsions. Eur Polym J 44:3306–3313. doi:10.1016/j.eurpolymj.2008.07.038

    Article  CAS  Google Scholar 

  17. Wang C, Chu F, Graillat C, Guyot A, Gauthier C, Chapel JP (2005) Hybrid polymer latexes: acrylics-polyurethane from miniemulsion polymerization: properties of hybrid latexes versus blends. Polymer 46:1113–1124. doi:10.1016/j.polymer.2004.11.051

    Article  CAS  Google Scholar 

  18. Owens DK, Wendt RC (1969) Estimation of the surface free energy of polymers. J Appl Polym Sci 13:1741–1747. doi:10.1002/app.1969.070130815

    Article  CAS  Google Scholar 

  19. Xin H, Shen YD, Li XR (2011) Novel cationic polyurethane-fluorinated acrylic hybrid latexes: Synthesis, characterization and properties. Colloid Surf A 384:205–211. doi:10.1016/j.colsurfa.2011.03.056

    Article  CAS  Google Scholar 

  20. Korpela FJ, Pakkanen TT (2011) Incorporation of polydimethylsiloxane into polyurethanes and characterization of copolymers. Eur Polym J 47:1694–1708. doi:10.1016/j.eurpolymj.2011.06.006

    Article  Google Scholar 

  21. Alarcia F, de la Cal JC, Asua JM (2006) Continuous production of specialty waterborne adhesives: Tuning the adhesive performance. Chem Eng J 122:117–126. doi:10.1016/j.cej.2006.05.015

    Article  CAS  Google Scholar 

  22. Sardon H, Irusta L, Fernández-Berridi MJ (2010) Synthesis of room temperature self-curable waterborne hybrid polyurethanes functionalized with (3-aminopropyl) triethoxysilane (APTES). Polymer 51:5051–5057. doi:10.1016/j.polymer.2010.08.035

    Article  CAS  Google Scholar 

  23. Bai CY, Zhang XY, Dai JB, Zhang CY (2007) Water resistance of the membranes for UV curable waterborne polyurethane dispersions. Prog Org Coat 59:331–336. doi:10.1016/j.porgcoat.2007.05.003

    Article  CAS  Google Scholar 

  24. Rippel MM, Leite CAP, Lee LT, Galembeck FJ (2005) Formation of calcium crystallites in dry natural rubber particles. Colloid Interf Sci 2:449–456

    Article  Google Scholar 

  25. Braga M, Costa CAR, Leite CAP, Galembeck F (2001) Scanning electric potential microscopy imaging of polymer latex films: detection of supramolecular domains with nonuniform electrical characteristics. J PhysChem B 105:3005–3011. doi:10.1021/jp002667d

    CAS  Google Scholar 

  26. Zhu XH, Tu WP, Hu JQ (2006) Preparation and characterization of two-component waterborne polyurethane comprised of water-soluble acrylic resin and HDI biuret. Chin J Chem Eng 14:99–104. doi:10.1016/S1004-9541(06)60044-X

    Article  Google Scholar 

  27. D Mestach, M Weber, G Delaunoit, W Pilaszek, Aqueous crosslinkable polymer compositions for use in coatings, EP Patent 989163

  28. Jia QM, Zheng MS, Shen RJ (2006) Synthesis, characterization and properties of organoclay-modified polyurethane/epoxy interpenetrating polymer network nanocomposites. J Polym Int 55:257–264. doi:10.1002/pi.1931

    Article  CAS  Google Scholar 

  29. Wang X, Xing WY, Zhang P, Song L, Yang HY, Hu Y (2012) Covalent functionalization of graphene with organosilane and its use as a reinforcement in epoxy composites. Compos Sci Technol 72:737–743. doi:10.1016/j.compscitech.2012.01.027

    Article  CAS  Google Scholar 

  30. Lai XJ, Shen YD, Wang L (2011) Preparation and properties of self-crosslinkable polyurethane/silane hybrid emulsion. J Polym Res 18:2425–2433. doi:10.1007/s10965-011-9656-9

    Article  CAS  Google Scholar 

  31. Li XR, Fei GQ, Wang HH (2006) Mechanical and surface properties of membranes prepared from waterborne cationic hydroxyl-terminated polydimethylsiloxane/polyurethane surfactant-free micro-emulsion. J Appl Polym Sci 100:40–46. doi:10.1002/app.22524

    Article  CAS  Google Scholar 

  32. Zhu XL, Zhang QS, Liu LL, Kong XZ, Feng SY (2007) Synthesis and characterization of a new compound bearing ketone and hydroxyl groups for preparation of ambient temperature self-crosslinking waterborne polyurethanes. Prog Org Coat 59:324–330. doi:10.1016/j.porgcoat.2007.05.001

    Article  CAS  Google Scholar 

  33. Liu X, Fan XD, Tang MF (2008) Synthesis and characterization of core-shell acrylate based latex and study of its reactive blends. Int J Mol Sci 9:342–354. doi:10.3390/ijms9030342

    Article  CAS  Google Scholar 

Download references

Acknowledgments

This project was supported by the Graduate Innovation Fund of Shaanxi University of Science and Technology, and the authors thank the National Natural Science Foundation of China (contract grant number: 50973057; 51103081) for financial support.

Author information

Author notes

  1. Yiding Shen

    Present address: Key laboratory of Auxiliary Chemistry & Technology for Chemical Industry, Ministry of Education, Shaanxi University of Science & Technology, Xi’an, Shaanxi, 710021, China

Authors and Affiliations

  1. Key laboratory of Auxiliary Chemistry & Technology for Chemical Industry, Ministry of Education, Shaanxi University of Science & Technology, Xi’an, Shaanxi, 710021, China

    Xiaorui Li, Xiaorong Wang, Xiaojuan Lai & Rui Wang

  2. Research Institute of Oil & Gas Technology, Changqing Oilfield Branch Company, PetroChina, Xi’an, Shaanxi, 710021, China

    Haiyan Lv & Huabo Fan

Authors
  1. Xiaorui Li
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Xiaorong Wang
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Yiding Shen
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Xiaojuan Lai
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Rui Wang
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Haiyan Lv
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. Huabo Fan
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Yiding Shen.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Li, X., Wang, X., Shen, Y. et al. Synthesis and characterization of self-crosslinked polyurethane/polyacrylate composite emulsion based on carbonyl–hydrazide reaction. J Polym Res 20, 270 (2013). https://doi.org/10.1007/s10965-013-0270-x

Download citation

  • Received:

  • Accepted:

  • Published:

  • DOI: https://doi.org/10.1007/s10965-013-0270-x

Keywords

Search

Navigation