Abstract
In the paper, poly(methyl methacrylate)(PMMA)/SBA-15 composite materials were prepared by four different methods, that is, in-situ batch emulsion polymerization in the presence of mesoporous SBA-15, PMMA emulsion mixed with SBA-15 powder or dispersion in water, PMMA powder mixed with SBA-15 powder, and the properties of the composite materials were determined and compared. The composites were characterized by infrared spectroscopy (IR), X-ray diffraction (XRD), thermogravimetric analysis (TGA), differential scanning calorimetry (DSC), dynamic mechanics analysis (DMA) and scanning electron microscope (SEM). The results showed that the glass transition temperatures (Tg), the storage modulus and tensile strength of the PMMA/SBA-15 composites were all improved obviously, while the thermal decomposition temperature did not influenced apparently. The composite made by in-situ batch polymerization exhibited the most improvement in the mechanical properties and Tg while the composite prepared by mixing PMMA emulsion and SBA-15 dispersion gave rise to the least improvement in the mechanical properties and Tg. These results were contributed to introducing different amount of voids into polymer matrix which were demonstrated by dielectric constant measurement and SEM morphology observation.
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References
Yang PD, Zhao DY, Margoless DI, Chmelka BF, Stucky GD (1998) Generalized syntheses of large-pore mesoporous metal oxides with semicrystalline frameworks. Nature 396:152–155
Jiao J, Sun X, Pinnavaia TJ (2009) Mesostructured silica for the reinforcement and toughening of rubbery and glassy epoxy polymers. Polymer 50:983–989
Urbach B, Korbakov N, Bar-David Y, Yitzchaik S, Sa’ar A (2007) Composite structures of polyaniline and mesoporous silicon: electrochemistry, optical and transport properties. J Phys Chem C 111(44):16586–16592
He J, Shen YB, Yang J, Evans DG, Duan X (2003) Nanocomposite structure based on silylated MCM-48 and poly(vinyl acetate). Chem Mater 15:3894–3902
Wang N, Shao YW, Shi ZX, Zhang J, Li HW (2008) Influence of MCM-41 particle on mechanical and morphological behavior of polypropylene. Mater Sci Eng, A 497:363–368
Ver Meer MA, Narasimhan B, Shanks BH, Mallapragada SK (2010) Effect of mesoporosity on thermal and mechanical properties of polystyrene/silica composites. ACS Appl Mater Interfaces 2(1):41–47
Kiba S, Okawauchi Y, Yanagihara T, Murakami M, Shimizu T, Yamauchi Y (2009) Mesoporous silica/polymer composites utilizing intelligent caps onto mesopore walls toward practical low-dielectric materials. Chem Asian J 4(12):1798–1801
Kiba S, Suzuki N, Okawauchi Y, Yamauchi Y (2010) Prototype of low thermal expansion materials: fabrication of mesoporous silica/polymer composites with densely filled polymer inside mesopore space. Chem Asian J 5(9):2100–2105
Zhang FA, Lee DK, Pinnavaia TJ (2009) PMMA-mesocellular foam silica nanocomposites prepared through batch emulsion polymerization and compression molding. Polymer 50:4768–4774
Pérez LD, Giraldo LF, Brostow W, López BL (2007) Poly(methyl acrylate) plus mesoporous silica nanohybrids: mechanical and thermophysical properties. Polymers 029:1618–7229
Run MT, Wu SZ, Zhang DY, Wu G (2007) A polymer/mesoporous molecular sieve composite: preparation, structure and properties. Mater Chem Phys 105(2–3):341–347
Ji XL, Hampsey JE, Hu QY, He JB, Yang ZZ, Lu YF (2003) Mesoporous silica-reinforced polymer nanocomposites. Chem Mater 15:3656–3662
Zhang FA, Lee DK, Pinnavaia T (2010) PMMA/mesoporous silica nanocomposites: effect of framework structure and pore size on thermomechanical properties. Polym Chem 1(1):107–113
Zhang FA, Lee DK, Pinnavaia TJ (2009) A comparative study of PMMA/Mesoporous silica, PMMA/Clay, and PMMA/Colloidal SiO2 nanocomposites made by emulsion polymerization. Abstract preprint for the 238th ACS National Meeting & Exposition
Moller K, Bein T, Fischer RX (1998) Entrapment of PMMA polymer strands in micro- and mesoporous materials. Chem Mater 10:1841–1852
Zhou LZ, Zhou FQ, Huang RH, Liu ZH, Jiang FM (2008) Study on adsorption performance of trace Hg on an organic–inorganic mesorporous material. Chin J Anal Lab 27(9):33–36
Zhao DY, Feng JL, Huo QS, Melosh N, Fredrickson GH, Chmelka BF, Stucky GD (1998) Triblock copolymer syntheses of mesoporous silica with periodic 50 to 300 Angstrom pores. Science 279:548–552
Zheng FH, Zang GYW, Xia C, Xia JF (2005) Influence on permittivity of PMMA after electron beam radiation. Journal of Sichuan University 42(2):337–340
Lin JJ, Wang XD (2007) Novel low-k polyimide/mesoporous silica composite films: preparation, microstructure, and properties. Polymer 48:318–329
Wang QS (2007) Effect of nanostructured mesoporous material MCM-41 on the dynamic mechanical behavior of PMMA. Fujian Normal University 23(2):53–57
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Thanks to the financial support of national natural science fund of China (Granted No. 21064002), key laboratory of new material and processing technology of Guangxi Autonomous Region (0842003-5A).
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Zhang, FA., Song, C. & Yu, CL. Effects of preparation methods on the property of PMMA/SBA-15 mesoporous silica composites. J Polym Res 18, 1757–1764 (2011). https://doi.org/10.1007/s10965-011-9582-x
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DOI: https://doi.org/10.1007/s10965-011-9582-x