Skip to main content
SpringerLink
Log in

Polyurethane methacrylate/silicone interpenetrating polymer networks synthesis, thermal and mechanical properties

  • Published:
Journal of Polymer Research Aims and scope Submit manuscript

Abstract

The synthesis of an interpenetrating polymer network (IPN) combining a polyurethane methacrylate network (PUMA) and a silicone network is reported. The PUMA network is synthesized by UV-light cure. The silicone network is formed through a condensation between α, ω dihydroxy polydimethyl siloxane and γ-methacryloxypropyl trimethoxy silane (γ-MPS) as a cross-linking agent. The IPN is prepared by different mechanism: radical and condensation types. According to thermogravimetric analysis of the hybrid material, the thermal stability stayed unchanged but the kinetic of degradation changed. Tg decreased with increasing silica content. The thermal cure process under humid atmosphere influence properties just for PUMA/4.2%SiUV+T. Condensation between γ-MPS decreases the penetration depth from 158 to 82 μm and increases the mechanical glass transition temperature from 106 to 141 °C.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Scheme 1
Scheme 2
Scheme 3
Scheme 4
Scheme 5
Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Scheme 6

Similar content being viewed by others

References

  1. Sperling LH (1981) Plenum Press, New York

  2. Zareba-Grodz I, Mista W, Streck W, Bukowska E, Hermanowicz K, Maruszewsk K (2004) Opt Master 26:207

    Article  CAS  Google Scholar 

  3. Wang YB, Huang ZX, Zhang LM (2006) Trans Nonferrous Met Soc China 16:517

    Article  CAS  Google Scholar 

  4. Arakawa M, Sakata K, Shimada M, Agari Y (2006) J Appl Polym Sci 100:4273

    Article  CAS  Google Scholar 

  5. Oprea S, Vlad S, Stanciu A (2001) Polymer 42:7257

    Article  CAS  Google Scholar 

  6. Kukanja D, Golob J, Zupancic VA, Krajnc JM (2000) J Appl Polym Sci 78:67

    Article  CAS  Google Scholar 

  7. Burel F, Lecamp L, Youssef B, Bunel C, Saiter JM (1999) Thermochim Acta 326:133

    Article  CAS  Google Scholar 

  8. Bonilla G, Martinez M, Mendoza AM, Widmaier JM (2006) Eur Polym J 42:2977

    Article  CAS  Google Scholar 

  9. Chen L, Chen S (2004) Prog Org Coat 49:252

    Article  CAS  Google Scholar 

  10. Wu CS, Liu YL, Chiu YS (2002) Polymer 43:4277

    Article  CAS  Google Scholar 

  11. Liao SK, Jang SC, Lin MF (2005) J Polym Res 12(2):103

    Article  CAS  Google Scholar 

  12. Ni H, Aaserud DJ, Simonsick WJ Jr, Soucek MD (2000) Polymer 41:57

    Article  CAS  Google Scholar 

  13. Mouanda B (1997) Polymer 38(21):5301

    Article  CAS  Google Scholar 

  14. Ledru J, Youssef B, Saiter JM, Grenet J (2002) J Therm Anal Cal 68:767

    Article  CAS  Google Scholar 

  15. Ni H, Nash HA, Worden JG, Soucek MD (2002) J Polym Sci A Polym Chem 40:1677

    Article  CAS  Google Scholar 

Download references

Acknowledgement

The authors wish to thank E. Donzdorf to manufacture the penetration clamp and L. Delbreilh for assistance for penetration measurement.

Author information

Authors and Affiliations

  1. Laboratoire PBM, UMR 6522, LECAP Institut des Matériaux de Rouen, Université de Rouen, Faculté des Sciences, Avenue de l’Université BP 12, 76801, Saint Etienne du Rouvray, France

    A. Vuillequez, J. Moreau, M. R. Garda, B. Youssef & J. M. Saiter

Authors
  1. A. Vuillequez
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. J. Moreau
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. M. R. Garda
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. B. Youssef
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. J. M. Saiter
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to B. Youssef.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Vuillequez, A., Moreau, J., Garda, M.R. et al. Polyurethane methacrylate/silicone interpenetrating polymer networks synthesis, thermal and mechanical properties. J Polym Res 15, 89–96 (2008). https://doi.org/10.1007/s10965-007-9147-1

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10965-007-9147-1

Keywords

Search

Navigation