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Critical and Tricritical Wetting in the Two-Dimensional Blume–Capel model

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Abstract

The two-dimensional Blume–Capel model with free surfaces where a surface field \(H_1\) acts and the “crystal field” (controlling the density of the vacancies) takes a value \(D _s\) different from the value \(D\) in the bulk, is studied by Monte Carlo methods. Using a recently developed finite size scaling method that studies thin films in a \(L \times M\) geometry with antisymmetric surface fields \((H_L=-H_1)\) and keeps a generalized aspect ratio \(c = L^2/M\) constant, surface phase diagrams are computed for several typical choices of the parameters. It is shown that both second order and first order wetting transitions occur, separated by tricritical wetting behavior. The special role of vacancies near the surface is investigated in detail.

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References

  1. Champion, Y., Fecht, H.J. (eds.): Nano-Architectured and Nano-Structured Materials. Wiley-VCH, Weinheim (2004)

    Google Scholar 

  2. Zhang, S. (ed.): Handbook of Nanostructured Thin Films and Coatings, vol. 1–3. CRC, Boca Raton, FL (2010)

  3. de Gennes, P.G.: Wetting: statics and dynamics. Rev. Mod. Phys. 57, 827–863 (1985)

    Article  ADS  Google Scholar 

  4. Abraham, D.B.: Surface Structures and Phase Transitions: Exact Results. In: Domb, X.C., Lebowitz, J.L. (eds.) Phase transitions and critical phenomena, vol. 10, pp. 1–74. Academic Press, New York (1986).

  5. Dietrich, S.: Wetting Phenomena. In: Domb, C., Lebowitz, J.L. (eds.) Phase transitions and critical phenomena, vol. XII, pp. 1–218. Academic Press, New York (1988).

  6. Forgacs, G., Lipowsky, R., Nieuwenhuizen, T.M.: The Behavior of Interfaces in Ordered and Disordered Systems. In: Domb, C., Lebowitz, J.L. (eds.) Phase Transitions and Critical Phenomena, Vol. XIV, pp. 136–363. Academic Press, New York (1991).

  7. Bonn, D., Ross, D.: Wetting transitions. Rep. Program. Phys. 64, 1085–1163 (2001)

    Article  ADS  Google Scholar 

  8. Binder, K., Landau, D., Müller, M.: Monte Carlo studies of wetting, interface localization, and capillary condensation. J. Stat. Phys. 110, 1411–1514 (2003)

    Article  MATH  Google Scholar 

  9. Rauscher, M., Dietrich, S.: Wetting phenomena in nanofluids. Ann. Rev. Mater. Res. 38, 143–172 (2008)

    Article  ADS  Google Scholar 

  10. Bonn, D., Eggers, J., Indekeu, J., Meunier, J., Rolley, E.: Wetting and spreading. Rev. Mod. Phys. 81, 739–805 (2009)

    Article  ADS  Google Scholar 

  11. Dietrich, S., Rauscher, M., Napiorlowski, M.: Wetting Phenomena on the Nanometer Scale. In: Ondarcuhu, T., Aim, J.-P. (eds.) Nanoscale liquid interfaces: wetting, pattering, and force minoscopy on the molecular scale, pp. 83–153. Pan Stanford Publ., Standford CA, (2013).

  12. Abraham, D.B.: Solvable model with a roughening transition for a planar Ising Ferromagnet. Phys. Rev. Lett. 44, 1165–1168 (1980)

    Article  MathSciNet  ADS  Google Scholar 

  13. Abraham, D.B., Smith, E.R.: An exactly solved model with a wetting transition. J. Stat. Phys. 43, 621–643 (1986)

    Article  MathSciNet  ADS  Google Scholar 

  14. Abraham, D.B.: Structure, phase transitions, and dynamics of interfaces and surfaces. J. Phys. A.: Math. Gen. 21, 1741–1751 (1988)

    Article  MathSciNet  MATH  ADS  Google Scholar 

  15. Blume, M.: Theory of the first-order magnetic phase change in UO\(_2\). Phys. Rev. 141, 517–524 (1966)

    Article  ADS  Google Scholar 

  16. Capel, H.W.: On the possibility of first-order phase transitions in Ising sytems of triplet ions with zero-field splitting. Physica 32, 966–988 (1966)

    Article  ADS  Google Scholar 

  17. Binder, K.: Applications of Monte Carlo methods to statistical physics. Rep. Program. Phys. 60, 487–559 (1997)

    Article  ADS  Google Scholar 

  18. Landau, D.P., Binder, K.: A Guide to Monte Carlo Simulatin in Statistical Physics, 3rd edn. Cambridge University Press, Cambridge (2009)

    Book  Google Scholar 

  19. Albano, E.V., Binder, K.: Wetting transition in the two-dimensional Blume-Capel model: a Monte Carlo study. Phys. Rev. E 85, 061601 (2012)

    Article  ADS  Google Scholar 

  20. Lawrie, I.D., Sarbach, S.: Theory of Tricritical Points. In: Domb, C., Lebowitz, J.L. (eds.) Phase transitions and critical phenomena, vol. IX, pp. 1–161. Academic, New York (1984).

  21. Privman, V.P. (ed.): Finite Size Scaling and the Numerical Simulation of Statistical Systems. World Scientific, Singapore (1990)

    Google Scholar 

  22. Cahn, J.W.: Critical point wetting. J. Chem. Phys. 66, 3667–3672 (1997)

    Article  ADS  Google Scholar 

  23. Schmidt, I., Binder, K.: Dynamics of wetting transitions: a time-dependent Ginzburg-Landau treatment. Z. Phys. B 67, 369–386 (1987)

    Article  ADS  Google Scholar 

  24. Lipowsky, R., Kroll, D.M., Zia, R.K.P.: Effective field theory for interface delocalization transitions. Phys. Rev. B 27, 4499–4502 (1983)

    Article  ADS  Google Scholar 

  25. Kroll, D.M., Lipowsky, R., Zia, R.K.P.: Universality classes for critical wetting. Phys. Rev. B 32, 1862–1865 (1985)

    Article  ADS  Google Scholar 

  26. Mc Coy, B.M., Wu, T.T.: The Two-Dimensional Ising Model. Harvard University Press, Cambridge, MA (1968).

  27. Sarbach, S., Lawrie, I.D.: In C. Domb and J.L. Lebowitz (eds.) Phase Transitions and Critical Phenomena, Vol. 9, p. 1 Academic, London (1984).

  28. da Silva, R., Alves, N.A., Drugowich de Felício, J.R.: Phys. Rev. E 66, 026130 (2002)

    Article  ADS  Google Scholar 

  29. Binder, K., Landau, D.P.: Wetting and layering in the nearest neighbor simple cubic Ising lattice: a Monte Carlo investigation. Phys. Rev. B 37, 1745–1766 (1988)

    Article  ADS  Google Scholar 

  30. Binder, K., Landau, D.P., Wansleben, S.: Wetting transitioons near the bulk critical point: Monte Carlo simulations for the Ising model. Phys. Rev. B 40, 6971–6979 (1989)

    Article  ADS  Google Scholar 

  31. Albano, E.V., Binder, K., Heermann, D.W., Paul, W.: Critical wetting in the square Ising model with a boundary field. J. Stat. Phys. 61, 161–178 (1990)

    Article  ADS  Google Scholar 

  32. Fisher, M.E., Nakanishi, H.: Scaling theory for the criticality of fluids between plates. J. Chem. Phys. 75, 3858–3863 (1981)

    Article  Google Scholar 

  33. Albano, E.V., Binder, K., Heermann, D.W., Paul, W.: Adsorption on stepped surfaces. A Monte Carlo Simul. Surf. Sci. 223, 151–178 (1989)

    Google Scholar 

  34. Binder, K., Landau, D.P.: Capillary condensation in the lattice gas model: a Monte Carlo study. J. Chem. Phys. 96, 1444–1454 (1992)

    Article  ADS  Google Scholar 

  35. Fisher, M.E.: The theory of critical point singularities. In: Green, M.S. (ed.) Critical Phenomena, Proc. 1970 E. Fermi Int. School Phys., pp. 1–99. Academic Press, New York (1971).

  36. Binder, K.: Finite Size Effects at phase transitions. In: Gausterer, H., Lang, C.B. Computational methods in field theory, pp. 59–125. Springer, Berlin (1992).

  37. Albano, E.V., Binder, K., Heermann, D.W., Paul, W.: The Ising square lattice in a \(L \times M\) geometry: a model for the effect of surface steps on phase transitions in adsorbed monolayers. Z. Phys. B 77, 445–460 (1989)

    Article  ADS  Google Scholar 

  38. Fisher, M.E.: The renormalization group in the theory of critical behavior. Rev. Mod. Phys. 46, 597–616 (1974)

    Article  ADS  Google Scholar 

  39. Parry, A.O., Evans, R.: Novel phase behavior of a confined fluid or Ising magnet. Physica A 181, 250–296 (1992)

    Article  ADS  Google Scholar 

  40. Maciolek, A.: Magnetization profiles for a \(d=2\) Ising strip with opposite surface fields. J. Phys. A: Math. Gen. 29, 3837–3845 (1996)

    Article  MATH  ADS  Google Scholar 

  41. De Virgiliis, A., Albano, E.V., Müller, M., Binder, K.: Interfaces in the confined Ising system with competing surface fields. Physica A 352, 477–497 (2005)

    Article  ADS  Google Scholar 

  42. Albano, E.V., Binder, K.: Finite size scaling approach for critical wetting: rationalization in terms of a bulk transition with an order parameter exponent equal to zero. Phys. Rev. Lett. 109, 036101 (2012)

    Article  ADS  Google Scholar 

  43. Fytas, N.G., Selke, W.: Wetting and interfacial adsorption in the Blume-Capel model on the square lattice. Eur. Phys. B. 86, 365 (2013)

    Article  ADS  Google Scholar 

  44. Trobo, M., Albano, E.V.: Influence of nonuniform surface magnetic fields in wetting transitions in a confined two-dimensional Ising ferromagnet. Phys. Rev. E 88, 052407 (2013)

    Article  ADS  Google Scholar 

  45. Hryniv, O., Kotecký, R.: Surface tension and the OrnsteinZernike behaviour for the 2D BlumeCapel Model. J. Stat. Phys. 106, 431–476 (2001)

    Article  Google Scholar 

  46. Bricmont, J., Lebowitz, J.L.: Wetting in Potts and BlumeCapel models. J. Stat. Phys. 46, 1015–1029 (1987)

    Article  MathSciNet  ADS  Google Scholar 

  47. Albano, E.V., Binder, K., Heermann, D.W., Binder, K.: Shift of first-order phase transitions in thin films due to boundary fields: a computer simulation. J. Chem. Phys. 91, 3700–3706 (1989)

    Article  ADS  Google Scholar 

  48. Winkler, A., Wilms, D., Virnau, P., Binder, K.: Capillary condensation in cylindrical pores: Monte Carlo study of the interplay of surface and finite size effects. J. Chem. Phys. 133, 164702 (2010)

    Article  ADS  Google Scholar 

Download references

Acknowledgments

One of us (E.V.A) acknowledges partial support form the Alexander von Humboldt Foundation and from the Schwerpunkt für Rechnergestuetzte Forschungsmethoden in den Naturwissenschaften (SRFN) making his visit at the Institut für Physik der Johannes Gutenberg Universität possible. Also the support of the CONICET (Argentina) is acknowledged. We are grateful to W. Selke for stimulating discussions.

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Albano, E.V., Binder, K. Critical and Tricritical Wetting in the Two-Dimensional Blume–Capel model. J Stat Phys 157, 436–455 (2014). https://doi.org/10.1007/s10955-014-1091-y

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