Abstract
The interactions between the anionic surfactant di-(2-ethylhexyl) phosphate sodium salt (DEP) and two nonionic surfactants, dimethyldecyl phosphineoxide (DDPO) and dimethyltetradecyl phosphineoxide (DTPO), at the interface and in the micellar phases were investigated in the absence and presence of adenosine-5-monophosphoric acid disodium salt (AMP). The mixed systems were DEP–DDPO, DEP–DDPO/AMP (0.001 mol⋅L−1), DEP–DTPO, and DEP–DTPO/AMP (0.001 mol⋅L−1) at different bulk mole fractions of the anionic component (α 1=0.9,0.8,0.6,0.4,0.2). The mixed systems studied were investigated based on the theoretical models of Rubingh and Clint. The results showed surface tension reduction efficiency. The adsorbed mixed monolayer demonstrated stronger interactions than the mixed micelles, whereas AMP increased the interfacial interactions more than those in the micellar phase. The Gibbs energy of mixing suggests that the stability of the mixed micellar phase is greater than that of the micellar phases of the individual components. The synergism that occurred in the different mixed phases is discussed.
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Kwak, J.C.T.: Polymer–Surfactant Systems. Dekker, New York (1998)
Hill, R.M.: Mixed Surfactant Systems. Dekker, New York (1993)
Ghosh, S., Moulik, S.P.: Interfacial and micellization behaviors of binary and ternary mixtures of amphiphiles (Tween-20, Brij-35, and sodium dodecyl sulfate) in aqueous medium. J. Colloid Interface Sci. 208, 357–366 (1999)
Reynders, E.H., Lucassen, J., Giles, D.: Surface and bulk properties of mixed anionic/cationic surfactant systems-equilibrium surface tensions. J. Colloid Interface Sci. 82, 150–157 (1981)
Rosen, M.J., Liu, L.: Surface activity and premicellar aggregation of some novel diquaternary gemini surfactants. J. Am. Oil Chem. Soc. 73, 885–892 (1996)
Rosen, M.J.: Surfactant and Interfacial Phenomena, 2nd edn. Wiley, New York (1989)
Rosen, M.J.: Thermodynamic studies of mixed ionic/nonionic surfactant systems. Langmuir 7, 885–888 (1991)
Rubingh, D.N., Jones, T.: The behaviour of surfactants in concentrated acids. Ind. Eng. Chem. Prod. Res. Dev. 21, 176–182 (1982)
Reif, I., Somasundaran, P.: Asymmetric excess free energies and variable interaction parameters in mixed micellization. Langmuir 15, 3411–3417 (1999)
Wydro, P., Paluch, M.: Surface properties of cationic–nonionic mixed surfactant systems. Colloids Surf. A, Physicochem. Eng. Asp. 245, 75–79 (2004)
Bakshi, M.S., Singh, K.: Synergistic interactions in the mixed micelles of cationic gemini with zwitterionic surfactants: fluorescence and Krafft temperature studies. J. Colloid Interface Sci. 287, 288–297 (2005)
McLachlan, A.A., Marangoni, D.G.: Interactions between zwitterionic and conventional anionic and cationic surfactants interactions between zwitterionic and conventional anionic and cationic surfactants. J. Colloid Interface Sci. 295, 243–248 (2006)
Rubingh, D.N.: Solution Chemistry of Surfactants. Plenum, New York (1979)
Gharibi, H., Javadian, S., Behjatmanesh, R.: Investigation of interaction parameters in mixed micelle using pulsed field gradient NMR spectroscopy. J. Colloid Interface Sci. 285, 351–359 (2005)
Motomura, K., Yamanaka, M., Aratono, M.: Thermodynamic consideration of the mixed micelle of surfactants. Colloid Polym. Sci. 262, 948–955 (1984)
Puvada, S., Blankschtein, D.: Thermodynamic description of micellization, phase behavior, and phase separation of aqueous solutions of surfactant mixtures. J. Phys. Chem. 96, 5567–5579 (1992)
Puvada, S., Blankschtein, D.: Theoretical and experimental investigations of micellar properties of aqueous solutions containing binary mixtures of nonionic surfactants. J. Phys. Chem. 96, 5579–5592 (1992)
Shiloach, A., Blankschtein, D.: Predicting micellar solution properties of binary surfactant mixtures. Langmuir 14, 1618–1636 (1998)
Lee, Y.L., Lin, J.Y., Chang, C.H.: Thermodynamic characteristics and Langmuir–Blodgett deposition behavior of mixed DPPA/DPPC monolayers at air/liquid interfaces. J. Colloid Interface Sci. 296, 647–654 (2006)
Iyota, H., Abe, K., Ikeda, N., Motomura, K., Aratono, M.: Nonideal mixing of alkylammonium chloride and decyldimethylphosphine oxide surfactants in adsorbed films and micelles. J. Colloid Interface Sci. 322, 287–293 (2008)
Renoncourt, A., Vlachy, N., Bauduin, P., Drechsler, M., Touraud, D., Verbavatz, J.M., Dubois, M., Kunz, W., Ninham, B.W.: Specific alkali cation effects in the transition from micelles to vesicles through salt addition. Langmuir 23, 2376–2381 (2007)
Vlachy, N., Drechsler, M., Verbavatz, J.M., Touraud, D., Kunz, W.: Role of the surfactant headgroup on the counterion specificity in the micelle-to-vesicle transition through salt addition. J. Colloid Interface Sci. 319, 542–548 (2008)
Lin, T., Hu, Y., Liu, W.: Thermodynamic theory and dynamic light scattering studies of mixed short-chain lecithin micelles. Langmuir 13, 1422–1429 (1997)
Din, K., Sheikh, M.S., Mir, M.A., Dar, A.A.: Effect of spacer length on the micellization and interfacial behavior of mixed alkanediyl-α,ω-bis(dimethylcetylammonium bromide) Gemini homologues. J. Colloid Interface Sci. 344, 75–80 (2010)
Fainerman, V.B., Zholob, S.A., Leser, M., Michel, M., Miller, R.: Competitive adsorption from mixed non-ionic surfactant/protein solutions. J. Colloid Interface Sci. 274, 496–501 (2004)
Kovalchuk, V.I., Kragel, J., Makievski, A.V., Ravera, F., Liggieri, L., Loglio, G., Fainerman, V.B., Miller, R.: Rheological surface properties of C12DMPO solution as obtained from amplitude and phase-frequency characteristics of oscillating bubble system. J. Colloid Interface Sci. 280, 498–505 (2004)
Miller, R., Leser, M.E., Michel, M., Fainerman, V.B.: Surface dilational rheology of mixed β-lactoglobulin/surfactant adsorption layers at the air/water interface. J. Phys. Chem. 109, 13327–13331 (2005)
Aksenenko, E.V., Kovalchuk, V.I., Fainerman, V.B., Miller, R.: Surface dilatational rheology of mixed adsorption layers at liquid interfaces. Adv. Colloid Interface Sci. 122, 57–66 (2006)
Devinsky, F., Lacko, I., Bitterova, F.B., Tomeckova, L.: Relationship between structure, surface activity and micelle formation of some new bisquaternary isosteres of 1,5-pentane diammonium dibromides. J. Colloid Interface Sci. 114, 314–322 (1986)
Negm, N.A.: Surface activities and electrical properties of long chain diquaternary bola-form amphiphiles. Egypt. J. Chem. 45, 483–499 (2002)
Rosen, M.J.: Surfactants and Interfacial Phenomena, 3rd edn. Willey, New York (2004)
Bai, G., Wang, J., Yan, L.Z., Thomas, R.K.: Thermodynamics of molecular self-assembly of cationic gemini and related double chain surfactants in aqueous solution. J. Phys. Chem. B 105, 3105–3108 (2001)
Junquera, E., Aicart, E.: Mixed micellization of dodecyl ethyldimethyl ammonium bromide and dodecyl trimethyl ammonium bromide in aqueous solution. Langmuir 23, 9250–9258 (2002)
Miller, R., Grigoriev, D.O., Krägel, J., Makievski, A.V., Fainerman, V.B., Kovalchuk, V.I., Liggieri, L., Ravera, F., Ferrari, M., Santini, E., Loglio, G., Dutschk, V., Karapantsios, T.: Project proposal for the investigation of particle-stabilized emulsions and foams by microgravity experiments. Microgravity Sci. Technol. 18, 104–107 (2006)
Miller, R., Dutschk, V., Fainerman, V.B.: Influence of molecular processes at liquid interfaces on dynamic surface tensions and wetting kinetics. J. Adhes. 80, 549–561 (2004)
Grigoriev, D.O., Leser, M.E., Michel, M., Miller, R.: Mixed micelles as delivery systems for enhanced emulsifier adsorption at the air/water interface: sodium stearoyl lactylate (SSL)/Tween80 solutions. Colloids Surf. A, Physicochem. Eng. Asp. 301, 158–165 (2007)
Negm, N.A., Salem, M.A.I., Zaki, M.F.: Solubilization behaviors of nonpolar substrates using double tailed cationic surfactants. J. Dispers. Sci. Technol. 30, 1167–1174 (2009)
Junquera, E., Arranz, R., Aicart, E.: Mixed vesicle formation on a ternary surfactant system: didodecyl dimethyl ammonium bromide/dodecyl ethyldimethyl ammonium bromide/water. Langmuir 20, 6619–6625 (2004)
Acharya, D.P., Gutiérrez, J.M., Aramaki, K., Aratani, K., Kunieda, H.: Interfacial properties and foam stability effect of novel gemini-type surfactants in aqueous solutions. J. Colloid Interface Sci. 291, 236–243 (2005)
Sharma, K.S., Rodgers, C., Palepu, R.M., Rakshit, A.K.: Studies of mixed surfactant solutions of cationic dimeric (gemini) surfactant with nonionic surfactant C12E6 in aqueous medium. J. Colloid Interface Sci. 268, 482–488 (2003)
Din, K., Sheikh, M.S., Dar, A.A.: Interaction of a cationic gemini surfactant with conventional surfactants in the mixed micelle and monolayer formation in aqueous medium. J. Colloid Interface Sci. 333, 605–612 (2009)
Zhou, Q., Rosen, M.J.: Molecular interactions of surfactants in mixed monolayers at the air/aqueous solution interface and in mixed micelles in aqueous media—the regular solution approach. Langmuir 19, 4555–4562 (2003)
Yakovlev, D.S., Boek, E.S.: Molecular dynamics simulations of mixed cationic/anionic wormlike micelles. Langmuir 23, 6588–6597 (2007)
Minones, J., Minones, J., Conde, O., Patino, J.M., Latka, P.D.: Mixed monolayers of amphotericin β-dipalmitoyl phosphatidyl choline: study of complex formation. Langmuir 18, 2817–2827 (2002)
Rodrigues, M.A., Alonso, E.O., Yihwa, C., Farah, J.P.S., Quina, F.H.: A linear solvation free energy relationship analysis of solubilization in mixed cationic–nonionic micelles. Langmuir 15, 6770–6774 (1999)
Rosen, M.J., Sulthana, S.B.: The interaction of alkylglycosides with other surfactants. J. Colloid Interface Sci. 239, 528–534 (2001)
Seredyuk, V., Alami, E., Nyden, M., Holmberg, K., Peresypkin, A.V., Menger, F.M.: Application of the turbidity measurements to study in situ crystallization of calcium phosphates. Colloids Surf. A Physicochem. Eng. Asp. 203, 245–252 (2002)
Seredyuk, V., Alami, E., Nyden, M., Holmberg, K., Peresypkin, A.V., Menger, F.M.: Micellization and adsorption properties of novel zwitterionic surfactants. Langmuir 17, 5160–5165 (2001)
Torres, M.F., Sales, P.S., De Rossi, R.H., Fernndez, M.A.: Aggregation behavior of Brij-35–perfluorononanoic acid mixtures. Langmuir 26, 17858–17866 (2010)
Nagarajan, R.: Mixed Surfactant Systems. Am. Chem. Soc., Washington (1992)
Holland, P.M., Rubingh, D.N.: Nonideal multicomponent mixed micelle model. J. Phys. Chem. B 87, 1984–1990 (1983)
Li, F., Rosen, M.J., Sulthana, S.B.: Surface properties of cationic gemini surfactants and their interaction with alkylglucoside or maltoside surfactants. Langmuir 17, 1037–1042 (2001)
Matsubara, H., Ohta, A., Kameda, M., Villeneuve, M., Ikeda, N., Aratono, M.: Interaction between ionic and nonionic surfactants in the adsorbed film and micelle: hydrochloric acid, sodium chloride, and tetraethylene glycol monooctyl ether. Langmuir 15, 5496–5499 (1999)
Bakshi, M.S., Kaur, G., Kaura, A.: Effect of hydrophobicity of zwitterionic surfactants and triblock polymers on their mixed micelles: a fluorescence study. Colloids Surf. A, Physicochem. Eng. Asp. 269, 72–79 (2005)
Iyota, H., Shimada, K., Abe, K., Ikeda, N., Motomura, K., Aratono, M.: Effect of the head group of surfactant on the miscibility of sodium chloride and surfactant in an adsorbed film and micelle. J. Colloid Interface Sci. 234, 322–327 (2001)
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Negm, N.A., Tawfik, S.M. Studies of Monolayer and Mixed Micelle Formation of Anionic and Nonionic Surfactants in the Presence of Adenosine-5-monophosphate. J Solution Chem 41, 335–350 (2012). https://doi.org/10.1007/s10953-012-9801-z
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DOI: https://doi.org/10.1007/s10953-012-9801-z