Abstract
Densities of solutions of glycine, L–alanine, and L–serine have been measured by an oscillating-tube densimeter in 1,2-butanediol–water mixtures with 1,2-butanediol mass fractions ranging from 0 to 0.35 at 298.15 K. Apparent molar volumes and limiting partial molar volumes of each amino acid have been used to obtain the corresponding transfer volumes from water to different concentrations of 1,2-butanediol–water mixtures. The transfer volumes are positive for glycine and L–serine, and both positive and negative for L–alanine over the concentration range studied. The results are interpreted in terms of solute–solvent interactions. Substituent effects are also discussed.
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C. R. Hardt, I. F. Huddleson, and C. D. Ball, An Electrophoretic Analysis of Changes Produced in Blood Serum and Plasma Proteins by Heat in the Presence of Sugars, J. Biol. Chem. 163, 211–220 (1946).
R. B. Simpson and W. Kauzmann, The Kinetics of Protein Denaturation. I. The Behavior of the Optical Rotation of Ovalbumin in Urea Solutions, J. Am. Chem. Soc. 75, 5139–5152 (1953).
J. C. Lee and S. N. Timasheff, The Stabilization of Proteins by Sucrose, J. Biol. Chem. 256, 7193–7201 (1981).
M. M. Santoro, Y. Liu, S. M. A. Khan, L.-X. Hou, and D. W. Bolen, Increased Thermal Stability of Proteins in the Presence of Naturally Occurring Osmolytes, Biochemistry 31, 5278–5283 (1992).
R. Bhat, N. Kishore, and J. C. Ahluwalia, Thermodynamic Studies of Transfer of Some Amino Acids and Peptides from Water to Aqueous Glucose and Sucrose Solutions at 298.15 K, J. Chem. Soc. Faraday Trans. I 84, 2651–2665 (1988).
T. H. Lilley, Interactions in Solutions: The Interplay Between Solute Solvation and Solute–Solute Interactions, Pure Appl. Chem. 66, 429–434 (1994).
Y. Lou and R.-S. Lin, Enthalpy of Transfer of Amino Acids from Water to Aqueous Glucose Solutions at 298.15 K, Thermochim. Acta 316, 145–148 (1998).
S.-Q. Li, X.-G. Hu, R.-S. Lin, and H.-X. Zong, Enthalpic Interaction of Glycine in Aqueous Glucose and Sucrose Solutions at 298.15 K, Thermochim. Acta 342, 1–6 (1999).
X.-L. Ren, R.-S. Lin, Y.-M. Ni, and H.-X. Zong, Apparent Molar Volumes of Glycine, L-Alanine and L-Serine in Water + Ethanol Mixtures at 298.15 K, Can. J. Chem. 77, 387–390 (1999).
X.-L. Ren, R.-S. Lin, X.-G. Hu, and Y.-M. Ni, Enthalpic Pairwise Interactions of Glycine in DMF/Water and Ethanol/Water Mixed Solvents, Acta Chim. Sin. A57, 875–880 (1999).
R.-S. Lin, X.-G. Hu, and X.-L. Ren, Homogeneous Enthalpic Interaction of Amino Acids in DMF–H2O Mixed Solvents, Thermochim. Acta 352/353, 31–37 (2000).
S.-Q. Li, X.-G. Hu, R.-S. Lin, W.-Q. Sang, and W.-J. Fang, Transfer Volumes of Glycine, L-Alanine and L-Serine in Glycerol–Water Mixtures at 25 °C, J. Solution Chem. 30, 365–373 (2001).
S.-Q. Li, W.-Q. Sang, and R.-S. Lin, Volumetric Properties of Glycine in Glucose–Water and Sucrose–Water Mixed Solvents at 298.15 K, Acta Chim. Sin. 60, 1951–1956 (2002).
X. Wang, L. Xu, R.-S. Lin, and D.-Z. Sun, Dilution Enthalpies of Glycine in Aqueous Potassium Chloride Solution, Acta Chim. Sin. 62, 1405–1408 (2004).
G. S. Kell, Density, Thermal Expansivity, and Compressibility of Liquid Water from 0 to 150 °C: Correlations and Tables for Atmospheric Pressure and Saturation Reviewed and Expressed on 1968 Temperature Scale, J. Chem. Eng. Data 20, 97–105 (1975).
T. S. Banipal and G. Singh, Densities and Partial Molar Volumes of Some Amino Acids and Diglycine in Aqueous n-Propanol Solutions at 25 °C, J. Solution Chem. 32, 997–1015 (2003).
R. K. Wadi and P. Ramasami, Partial Molal Volumes and Adiabatic Compressibilities of Transfer of Glycine and DL-Alanine from Water to Aqueous Sodium Sulfate at 288.15, 298.15 and 308.15 K, J. Chem. Soc., Faraday Trans. 93, 243–247 (1997).
A. W. Hakin, M. M. Duke, S. A. Klassen, R. M. Mckay, and K. E. Preuss, Apparent Molar Heat Capacities and Volumes of Some Aqueous Solutions of Aliphatic Amino Acids at 288.15, 298.15, 313.15 and 328.15 K, Can. J. Chem. 72, 362–368 (1994).
C. Jolicoeur and J. Boileau, Apparent Molar Volumes and Heat Capacities of Low Molecular Weight Peptides in Water at 25 °C, Can. J. Chem. 56, 2707–2713 (1978).
K. Belibagli and E. Agranci, Viscosities and Apparent Molar Volumes of Some Amino Acids in Water and in 6 M Guanidine Hydrochloride at 25 °C, J. Solution Chem. 19, 867–882 (1990).
H. L. Friedman and C. V. Krishnan, Water, A Comprehensive Treatise, Vol. 3, Chap. 1, F. Franks, Ed., Plenum, New York, 1973.
R. Bhat and J. C. Ahluwalia, Partial Molar Heat Capacities and Volumes of Transfer of some Amino Acids and Peptides from Water to Aqueous Sodium Chloride Solutions at 298.15 K, J. Phys. Chem. 89, 1099–1105 (1985).
M. Natarajan, R. K. Wadi, and H. C. Gaur, Apparent Molar Volumes and Viscosities of some α- and α,ω-Amino Acids in Aqueous Ammonium Chloride Solutions at 298.15 K, J. Chem. Eng. Data 35, 87–93 (1990).
A. K. Mishra and J. C. Ahluwalia, Enthalpies, Heat Capacities and Apparent Molal Volumes of Transfer of Some Amino Acids from Water to Aqueous t-Butanol, J. Chem. Soc. Faraday Trans. I 77, 1469–1483 (1981).
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Xu, L., Ding, C. & Lin, R. Transfer Volumes of Glycine, L–Alanine, and L–Serine from Water to 1,2-Butanediol–Water Mixtures at 298.15 K. J Solution Chem 35, 191–200 (2006). https://doi.org/10.1007/s10953-006-9378-5
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DOI: https://doi.org/10.1007/s10953-006-9378-5