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Structural and Magnetic Characteristics of Gadolinium Manganite Modified with Barium Gd0.9Ba0.1MnO3

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Abstract

The synthesis conditions for the gadolinium manganite doped with barium (x = 0.1) are determined. The sequence and typical features of phase formation during the synthesis of Gd0.9Ba0.1MnO3 are determined. It is revealed that the β→γ-BaCO3 phase transformation at T = 960 °C leads to an increase in the reactivity of the initial reagents. At this stage, the Gd0.9Ba0.1MnO3 formation centers begin to grow. Intermediate grinding is necessary to homogenize the phase; additional annealing at T = 1250 °C is applied to stabilize the phase. Substitution of Gd for Ba changes the microstructure of the manganite and leads to suppression of grain growth. Modification of the GdMnO3 manganite with barium leads to partial removal of the Jahn-Teller distortions, and as a consequence to a decrease in temperature of the phase transition O’→O. The addition of barium does not affect noticeably the magnetic behavior of the initial manganite but decreases the magnetic moment and stimulates ferromagnetic correlations in its antiferromagnetic manganese subsystem.

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References

  1. Liu, Y.-K., Yin, Y.-W, Li, X.-G.: Colossal magnetoresistance in manganites and related prototype devices. Chin. Phys. B. 22, 087502 (2013)

  2. Trukhanov, S.V., Khomchenko, V.A., Karpinsky, D.V., Silibin, M.V., Trukhanov, A.V., Lobanovsky, L.S., Szymczak, H., Botez, C.E., Troyanchuk, I.O.: A-site ordered state in manganites with perovskite-like structure based on optimally doped compounds Ln0.70Ba0.30MnO3 (Ln = Pr, Nd). J. Rare Earths. 37, 1242 (2019)

  3. Chmaissem, O., Dabrowski, B., Kolesnik, S., Mais, J., Jorgensen, D., Short,S.: Structural and magnetic phase diagrams of La1-xSrxMnO3 and Pr1-ySryMnO3. Phys. Rev. B. 67, 094431 (2003)

  4. Phan, M.-H., Yu, S.-C.: Review of the magnetocaloric effect in manganite materials. J. Magn. Magn. Mater. 308, 325 (2007)

    Article  ADS  Google Scholar 

  5. Aoyama, T., Iyama, A., Shimizu, K., Kimura, T.: Multiferroicity in orthorhombic RMnO3 (R = Dy, Tb, and Gd) under high pressure. Phys. Rev. B. 91(8), 081107 (2015)

  6. Pal, A., Murugavel, P.: Impact of cationic vacancies on the physical characteristics of multiferroic GdMnO3. J. Appl. Phys. 123, 234102 (2018)

  7. Ferreira, W. S., Moreira, J.A., Almeida, A., Chaves, M. R., Araujo, J. P., Oliveira, J. B., Da Silva, J. M. M., Sa, M. A., Mendonca, T. M., Carvalho, P. S., et al.: Spin-phonon coupling and magnetoelectric properties: EuMnO versus GdMnO3. Phys. Rev. B. 79(5), 054303 (2009)

  8. Kumar, P., Lalitha, N., Venugopal, G., Reddy, P.: Specific heat and magnetization studies of RMnO3 (R = Sm, Eu, Gd, Tb and Dy) multiferroics. Phys. Scr. 83, 045701 (2011)

  9. Lin, L., Li, L., Yan, Z.B., Tao, Y.M., Dong, S., Liu, J.M.: Ferroelectricity of polycrystalline GdMnO3 and multifold magnetoelectric responses. Appl. Phys. A. 112, 947 (2013)

    Article  ADS  Google Scholar 

  10. Kadomtseva, A.M., Popov, Yu. F., Vorob’ev, G.P., Kamilov, K.I., Pyatakov, A.P., Ivanov, V. Yu., Mukhin, A.A., Balbashov, A.M.: Specificity of magnetoelectric effects in a new GdMnO3 magnetic ferroelectric. JETP. Let. 81(1), 22 (2005)

  11. Mahana, S., Kumar, S.P., Rakshit, B., Nand, I.P., Basu, R., Dhara, S., Turchini, S., Zema, N., Manju, U., Mahanti, S.D., Topfal, D.: Site substitution in GdMnO3: Effects on structural, electronic, and magnetic properties. Phys. Rev. B. 102, 245120 (2020)

  12. Negi, P., Dixit, G.,· Agrawal, H.M.: Srivastava, R.C.Structural, optical and magnetic properties of multiferroic GdMnO3nanoparticles. J. Supercond. Nov. Magn. 26, 1611 (2013)

  13. Prakash, B.J., Kumar, K.N., Buddhudu, S.: Thermal, magnetic and electrical properties of multiferroic GdMnO3nano particles by a co-precipitation method. Ferroelectr. Lett. Sect. 39, 104 (2012)

    Article  Google Scholar 

  14. Ibrahim, J.E.F.M., Mergen, A., Parlak, U., Kurovics, E., Tihtih, M., Gomze, L.A.: Synthesis and characterizationof iron-doped GdMnO3 multiferroic ceramics. Journal of Silicate Based and Composite Materials. 73(1), 24 (2021)

    Google Scholar 

  15. Pal, A., DhanaSekhar, C., Venimadhay, A., Murugavel, P.: Tailoring of magnetic orderings in Fe substituted GdMnO3 bulk samples towards room temperature. J. Phys. Condens. Mater. 29, 405803 (2017)

  16. Tiwari, P., Kumar, S., Rath, C.: Probing structural transformation and optical and magnetic properties in Cr doped GdMnO3: Jahn-Teller distortion, photoluminescence and magnetic switching effect. Royal Soc. Chem. Adv. 9, 39871 (2019)

    Google Scholar 

  17. Karoblis, D., Zarkov, A., Garskaite, E., Mazeika, K., Baltruna, D., Niaura, G., AldonaBeganskiene, A., AivarasKareiva, A.: Study of gadolinium substitution effects in hexagonal yttrium manganite YMnO3. Sci. Rep. 11, 2875 (2021)

    Article  ADS  Google Scholar 

  18. Vilarinho, R., Almeida A., Machado da Silva, J.M., Oliveira, J.B., Sa, M.A., Tavares, P.B., Agostinho Moreira, J.: Dzyaloshinskii–Moriyanature of ferroelectric ordering in magnetoelectric Gd1-xYxMnO3 system. Solid State Commun. 208, 34 (2015)

  19. Peña, O., Bahout, M., Ghanimi, K., Duran, P., Gutierrez, D., Moure, K.: Spin reversal and ferrimagnetism in (Gd, Ca)MnO3. J. Mater. Chem. 12, 2480 (2002)

    Article  Google Scholar 

  20. Zukrowski, J., Wasniowska, M., Tarnawski, Z., Przewoznik, J., Chmist, J., Kozlowski, A., Krop, K., Sawicki, M.: Magnetic properties GdMnO3 and Gd0.67Ca0.33MnO3 compounds. Acta Phys. Pol. B. 33(2), 1533 (2003)

  21. Cheh, J., Dai, H.Y., Wang, M.M., Ye, F.J., Li, T., Xu, M.S., Chen, Z.P.: An evaluation of the impact of Ca substitution on the structural and magnetic properties of GdMnO3 ceramics. Ceram. Intern. 46, 6360 (2020)

    Article  Google Scholar 

  22. Basith, M.A., Islam M.A., Ahmmad ,B., Hossain, Md.S., Mólhave, K.: Preparation ofhigh crystalline nanoparticles of rare-earth based complex pervoskites and comparisonof their structural and magnetic properties with bulk counterparts. Mat. Res. Exp. 4(7), 075012 (2017)

  23. Sagar, S., Ganesan, V., Joy, P.A., Thomas, S., Liebig, A., Albrecht, M., Anantharaman, M.R.: Colossal thermoelectric power in Gd-Sr manganites. EPL. 91(1), 17008 (2010)

    Article  ADS  Google Scholar 

  24. Zhang, Y., Li, J., Zhang, Z., Liu, F., Zhao, X., Liu, X.: Negative magnetism in perovskite manganites Gd1-xSrxMnO3 (0.1≤x≤0.3). Chem. Res. Chin. Univ. 31(5), 699 (2015)

  25. Zener, C.: Interaction between the d-Shells in the transition metals. II. Ferromagnetic Compounds of Manganese with Perovskite Structure. Phys. Rev. 82(3), 403 (1951)

  26. Sakai, H., Ishiwata, S., Okuyama, D., Nakao, A., Nakao, H., Murakami, Y., Taguchi, Y., Tokura,Y.: Electron doping in the cubic perovskite SrMnO3: isotropic metal versus chainlike ordering of Jahn-Teller polarons. Phys. Rev. B. 82, 180409 (2010)

  27. Dagotto, E., Hotta, T., Moreo, A.: Colossal magnetoresistant materials: the key role of phase separation. Phys. Reports. 344, 1 (2001)

    Article  ADS  Google Scholar 

  28. Haberkorn, N., Larre´gola, S., Franco, D., Nieva, G.: Inhomogeneous ferrimagnetic-like behavior in Gd2/3Ca1/3MnO3 single crystals. J. Magn.Magn. Mat. 321, 1133 (2009)

  29. Trukhanov, S.V., Troyanchuk, L.O., Pushkarev, N.V, Szymczak, H.: Magnetic properties of anion-deficient La1-xBaxMnO3-x/2 (0≤x≤0.3) manganites. J. Exp. Tech. Phys. 96, 110 (2003)

  30. Gates-Rector, S., Blanton, T. The powder diffraction file: a quality materials characterization database . Powder Diffr. 34, 352 (2019)

  31. Kundu, A.K., Seikh, Md.M., Ramesha, K., Rao, C.N.R.: Novel effects of size disorder on the electronic and magnetic properties of rare earth manganates of the type La0.7-xLnxBa0.3MnO3 (Ln=Pr, Nd, Gd or Dy) with large average radius of the A-site cations. J. Phys.: Condens. Matter. 17, 4171 (2005)

  32. Dai, H., Liu, H., Peng, K., Ye, F., Li, T., Chen, J., Chen, Z.: Effect of barium doping on the microstructure, dielectric and magnetic properties of GdMnO3 multiferroic ceramics. J. Mat. Science: Materials in Electronics. 30, 2523 (2019)

  33. Dabrowski, B., Kolesnik, S., Baszczuk, A., Chmaissem, O., Maxwell, T., Mais, J.: Structural, transport and magnetic properties of RMnO3 perovskites (R=La, Pr, Nd, Sm, 153Eu, Dy). J. Solid State Chem. 178(3), 629 (2005)

    Article  ADS  Google Scholar 

  34. Modi, A., Thakur, R.K., Thakur, R., Gaur, N.K., Kaurav, N., Okram, G.S.: Structural and transport properties of orthorhombic GdMnO3. AIP Conf. Proc. 1536, 813 (2013)

    Article  ADS  Google Scholar 

  35. Hedvall, J.A.: Reaktions fahigkeit fester stofe. Z. Anorg. Allg. Chem. 162, 110 (1927)

    Article  Google Scholar 

  36. Alonso, J.A., Martinez-Lope, M.J., Casais, M.T., Fernández-Diaz, M.T.: Evolution of Jahn-Teller distortion of MnO6 octahedra in RMnO3 perovskites (R=Pr, Nd, Dy, Tb, Ho, Er, Y): a neutron diffraction study. Inorg. Chem. 39(5), 917 (2000)

    Article  Google Scholar 

  37. Vedmid’, L.B., Yankin, A.M., Fedorova, O.M., Kozin, V.M.: Phase diagram of the Pr–Mn–O System in composition–temperature–oxygen pressure coordinates. Russ. J. Phys. Chem. A. 90(5), 977 (2016)

  38. Vedmid’, L.B., Yankin, A.M., Fedorova, O.M., Kozin, V.M.: Phase transformations in the Nd–Mn–O system. Russ. J. Inorg. Mat., 51(3), 288 (2015)

  39. Vedmid’, L.B., Fedorova, O.M.: Thermal stability of Nd1–xAxMnO3 (x = 0, 0.15; A = Ba, Sr). Russ. J. Phys. Chem. A. 94(9), 1741 (2020)

  40. Vedmid’, L., Fedorova, O., Balakireva ,V., Balakirev, V.: Influence of temperature and oxygen pressure on the stability ofbarium or strontium doped neodymium manganites. Process. Appl. Ceram. 14(3), 203 (2020)

  41. Fedorova, O.M., Vedmid’, L.B., Balakireva, V.B., Vorotnikov, V.A., Balakirev, V.F.: Effect of barium concentration on the structural properties and electrical conductivity of Pr1– xBaxMnO3 (x = 0, 0.15, 0.25) solid solutions. Russ. J. Inorg. Mat. 57(4), 392 (2021)

  42. Fedorova, O.M., Vedmid’, L.B., Kozhina, G.A., Balakireva, V.B., Balakirev, V.F.: The effect of dopant concentration in the Nd1–xAxMnO3 solid solutions (A = Ba, Sr) on the electrical conductivity and structural transitions in the temperature range 20–1200 °C. Dokl Phys Chem. 492(2), 74 (2020)

  43. Troyanchuk, I.O., Trukhanov, S.V., Khalyavin, D.D., Szymczak, H.: Magnetic properties of anion deficit manganites Ln0.55Ba0.45MnO3-y (Ln=La, Nd, Sm, Gd, y≤0.37). J. Magn. Magn. Mater. 208, 217 (2000)

  44. Samantaray, S., Mishra, D.K., Roul, B.K.: Morpho-structural, electrical and magnetic behavior of chemically synthesized multiferroic GdMnO3 ceramic. J. Nanoscience Nanotechn. 20, 2359 (2020)

    Article  Google Scholar 

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Acknowledgements

The work was carried out according to the state assignmentfor IMET UB RAS. The experiments were performed by using scientific instruments included in the Collective Equipment Center “Ural-M.”

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  1. Institute of Metallurgy, Ural Branch of Russian Academy of Sciences, Ekaterinburg, 620016, Russia

    Larisa Vedmid’, Olga Fedorova, Sergey Uporov & Evgenii Sterkhov

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  1. Larisa Vedmid’
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Correspondence to Larisa Vedmid’.

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Vedmid’, L., Fedorova, O., Uporov, S. et al. Structural and Magnetic Characteristics of Gadolinium Manganite Modified with Barium Gd0.9Ba0.1MnO3. J Supercond Nov Magn 35, 1141–1150 (2022). https://doi.org/10.1007/s10948-022-06159-y

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