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Structure and Magnetic Properties of the Ti-Doped Pyrochlore Molybdate Y2Mo2(1-x)Ti2xO7

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Abstract

The structural, heat capacity, and magnetic properties of Y2Mo2(1-x)Ti2xO7 were investigated in this work. Y2Mo2(1-x)Ti2xO7 maintains the pyrochlore structure, but lattice constants are observed to decrease continuously with the Ti4+ doping. The magnetic measurements indicate a magnetic phase transition at low temperature for all Ti-doped samples, and the Ti4+ doping suppresses the transition temperature. This is ascribed to the diluted effect of nonmagnetic Ti4+ substitution of magnetic Mo4+. The heat capacity data confirm that the low-temperature magnetic phase is spin glass in the Ti4+-doped Y2Mo2(1-x)Ti2xO7 system. The M(H) data reveals the coexistence of antiferromagnetic and ferromagnetic interactions at low temperatures.

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Funding

This work was supported by the National Nature Science Foundation of China through Grant No. U1809215 and the Zhejiang Provincial Natural Science Foundation of China through Grant No. LY18E020016.

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Correspondence to Yao Ying or Shenglei Che.

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Ying, Y., Zhang, W., Yu, J. et al. Structure and Magnetic Properties of the Ti-Doped Pyrochlore Molybdate Y2Mo2(1-x)Ti2xO7. J Supercond Nov Magn 32, 3563–3568 (2019). https://doi.org/10.1007/s10948-019-5132-2

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  • DOI: https://doi.org/10.1007/s10948-019-5132-2

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