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Role of Coupling Divalent and Tetravalent Metal Ions on the Elastic and Electric Properties of CoFe2O4 Ferrites Prepared by Sol–Gel Method

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Abstract

The effect of Zn–Ti substitution on the infrared spectroscopy, elastic, dielectric, and resistivity properties of CoZnxTixFe2−2xO4 ferrites (where x= 0.0–0.4 in steps of 0.1) is investigated in the paper. All the samples were synthesized by the sol–gel method. Infrared spectroscopy shows two major absorption bands indicating that the prepared samples are in spinel structure. Elastic properties and dielectric properties are measured at room temperature and Zn–Ti is substitution dependent. The dc resistivity is measured using a two-probe method in the temperature range 300 to 650 K. The dielectric constant decreased whereas dc resistivity increased with the Zn–Ti substitution. The elastic constant decreases with increases in Zn–Ti ions.

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References

  1. Mujasam Batoo, K., Kumar, S., Lee, C.G.: Alimuddin, Study of dielectric and ac impedance properties of Ti doped Mn ferrites. Curr. Appl. Phys. 9, 1397–1406 (2009)

    Article  ADS  Google Scholar 

  2. Ravinder, D., Reddy, P.V.B., Frequency, P.S.: composition dependence of dielectric behavior of copper substituted lithium ferrites. J. Mater. Sci. Lett. 22, 1599 (2003)

    Article  Google Scholar 

  3. Xiao, H.M., Liu, X.M., Synthesis, S.Y. Fu.: magnetic and microwave absorbing properties of core-shell structured MnFe2O4/TiO2 nanocomposites. Comp. Sci. Tech. 66, 2003 (2006)

    Article  Google Scholar 

  4. Patange, S.M., Shirsath, S.E., Jadhav, S.P., Hegade, V.S., Kamble, S.R., Jadhav, K.M.: Elastic properties of nanocrystalline aluminum substituted nickel ferrites prepared by co-precipitation method. J. Mol. Struct. 1038, 40 (2013)

    Article  ADS  Google Scholar 

  5. Hashim, M., Alimuddin, S.K., Shirsath, S.E., Kotnala, R.K., Shah, J.: Ravi Kumar. Influence of Cr3+ ion on the structural, ac conductivity and magnetic properties of nanocrystalline Ni–Mg ferrite. Ceram. Int. 39, 1807 (2013)

    Article  Google Scholar 

  6. Shokrollahi, H., Janghorban, K.: Influence of additives on the magnetic properties, microstructure and densification of Mn–Zn soft ferrites. J. Mater. Sci. Eng. B 141, 91 (2007)

    Article  Google Scholar 

  7. Kaiser, M.: Electrical conductivity and complex electric modulus of titanium doped nickel–zinc ferrites. Physica B 407, 606–613 (2012)

    Article  ADS  Google Scholar 

  8. Rao, B.P., Rao, K.H., Rao, T.V., Paduraru, A.: Pulsed laser deposition of Ni-Zn ferrite thin films, O.F. Caltun. J. Opt. Adv. Mater. 7, 701 (2005)

    Google Scholar 

  9. Patange, S. M., Desai, S. S., Meena, S. S., Yusuf, S. M., Sagar, E.: Shirsath. Random site occupancy induced disordered Néel-type collinear spin alignment in heterovalent Zn2+–Ti4+ion substituted CoFe2O4. RSC Adv 5, 91482 (2015)

    Article  Google Scholar 

  10. Gul, I.H., Ahmed, A., Maqsood, A.: Electrical and magnetic characterization of nanocrystalline Ni–Zn ferrite synthesis by co-precipitation route. J. Magn. Magn. Mater 320, 270 (2008)

    Article  ADS  Google Scholar 

  11. Jadhav, S. S., Shirsath, S. E., Tokshay, B. G., Patange, S. M., Shukla, S. J., Jadhav Intern, K. M.: Structural properties and cation distribution of Co-Zn nano-ferrites. J. Mod. Phys. B 23, 5629 (2009)

    Article  ADS  MATH  Google Scholar 

  12. Amer, M. A., Hitti, M.E.: Mössbauer and X-ray studies for Ni0.2ZnxMg0.8−xFe2O4 ferrites. J. Magn. Magn. Mater. 234, 118–125 (2001)

    Article  ADS  Google Scholar 

  13. Waldron, R.D.: Infrared spectra of ferrites. Phys. Rev. B 99, 1727 (1955)

    Article  ADS  Google Scholar 

  14. Ahmed, M.A., Ateia, E., Salem, F.M.: Spectroscopic and electrical properties of Mg–Ti ferrite doped with different rare-earth elements. Physica B 381, 144–155 (2006)

    Article  ADS  Google Scholar 

  15. Patange, S.M., Shirsath, S.E., Jadhav, S.P., Hogade, V.S., Kamble, S.R., Jadhav, K.M.: Elastic properties of nanocrystalline aluminum substituted nickel ferrites prepared by co-precipitation method. J. Mole. Struct. 1038, 40–44 (2013)

    Article  ADS  Google Scholar 

  16. Abu-Elsaad, N.I.: Elastic properties of germanium substituted lithium ferrite. J. Mole. Struct. 1075, 546–550 (2014)

    Article  ADS  Google Scholar 

  17. Kumar, N., Purushotham, Y., Venugopal Reddy, P., Zaidi, Z.H., Kishan, P.: Elastic behaviour of Zn-substituted LiMg and LiMgTi ferrites. J. Magn. Magn. Mater. 192, 116–120 (1999)

    Article  ADS  Google Scholar 

  18. Shirsath, S.E., Patange, S.M., Kadam, R.H., Mane, M.L., refinement, K.M. Jadhav. Structure, location, cation site: spectral and elastic properties of Zn2+ substituted NiFe2O4. J. Mole. Struct. 1024, 77–83 (2012)

    Article  ADS  Google Scholar 

  19. Algude, S.G., Patange, S.M., Sagar, E., Shirsath, D.R., Mane, K.M.: Jadhav. Elastic behaviour of Cr3+ substituted Co-Zn ferrites. J. Magn. Magn. Mater. 350, 39–41 (2014)

    Article  ADS  Google Scholar 

  20. Anderson, O.L.: A simplified method for calculating the Debye temperature from elastic constants. J. Phys. Chem. Solids 24, 909 (1963)

    Article  ADS  Google Scholar 

  21. Verma, V., Pandey, V., Shukla, V.N., Annapoorni, S., Kotnala, R.K.: Remarkable influence on the dielectric and magnetic properties of lithium ferrite by Ti and Zn substitution. Solid State Commun. 149, 1726–1730 (2009)

    Article  ADS  Google Scholar 

  22. Verwey, E.J.W., de Boer, J.H.: Cation arrangement in a few oxides with crystal structures of the spinel type. Red. Trav. Chim. Phys. Bas. 55, 531–540 (1936)

    Article  Google Scholar 

  23. Eraky, M.R., Attia, S.M.: Transport properties of Ti–Ni spinel ferrites. Physica B 462, 97–103 (2015)

    Article  Google Scholar 

  24. Lotgering, F.K., Semiconduction and cation valencies in manganese ferrites. J. Phys. Chem. Solids 25, 95–103 (1964)

    Article  ADS  Google Scholar 

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Authors and Affiliations

  1. Materials Research Laboratory, Shrikrishna Mahavidyalaya, Gunjoti, MS, 413613, India

    S. S. Desai & S. M. Patange

  2. Department of Physics, Arts, Commerce and Science College, Satral, MS, India

    R. A. Pawar

  3. DSM’s Arts, Commerce and Science College, Parbhani, Jintur, Maharashtra, 431509, India

    S. S. Jadhav

  4. Department of Physics, Vivekanand College, Aurangabad, MS, 431001, India

    Sagar E. Shirsath

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  1. S. S. Desai
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  2. R. A. Pawar
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  3. S. S. Jadhav
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  4. Sagar E. Shirsath
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  5. S. M. Patange
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Correspondence to S. M. Patange.

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Desai, S.S., Pawar, R.A., Jadhav, S.S. et al. Role of Coupling Divalent and Tetravalent Metal Ions on the Elastic and Electric Properties of CoFe2O4 Ferrites Prepared by Sol–Gel Method. J Supercond Nov Magn 29, 2635–2640 (2016). https://doi.org/10.1007/s10948-016-3585-0

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  • DOI: https://doi.org/10.1007/s10948-016-3585-0

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