Abstract
A novel Laser Line Scanning method has been applied to process rectangular cross-section Bi-2212 monoliths containing 2.9 % Ag using a CO2 Laser. Although previous work has suggested the use of nIR lasers (≈0.8–1.1 μm) for melt-processing metal oxide superconductors, the results obtained here demonstrate that mid-IR radiation from a CO2 laser (10.6 μm) may be just as convenient for such a purpose while it enables processing large surface areas. The samples described here were processed at traverse rates ranging between 15 and 60 mm/h, exhibited a complex textured microstructure and yielded highest I c values of 71 A at 77 K.
Similar content being viewed by others
References
Feigelson, R.S., Gazit, D., Fork, D.K., Geballe, T.H.: Superconducting Bi–Ca–Sr–Cu–O fibers grown by the laser-heated pedestal growth method. Science 240, 1642–1645 (1988)
de la Fuente, G.F., Beltrán, D., Ibáñez, R., Martínez, E., Beltrán, A., Segura, A.: Crystal fibers of Bi–Sr–Ca–Cu–O materials grown by the laser floating zone method. J. Less-Common Met. 150, 253–260 (1989)
Mora, M., Martínez, E., Diez, J.C., Angurel, L.A., de la Fuente, G.F.: Phase growth and microstructure modifications induced by annealing in highly textured superconducting Bi-2212 thin rods. J. Mater. Res. 15, 614–620 (2000)
Costa, F.M., Gonçalves, A.P., Abilio, C., Godinho, M.M., Almeida, M., Vieira, J.M.: Crystallization process, phase chemistry and transport properties of superconducting fibers prepared by the LFZ method followed by isothermal annealing. Physica C 235, 513–514 (1994)
Costa, F.M., Silva, R.F., Vieira, J.M.: Influence of epitaxial growth on superconducting properties of LFZ Bi–Sr–Ca–Cu–O fibres. 1. Crystal nucleation and growth. Physica C 289, 161–170 (1997)
Costa, F.M., Silva, R.F., Vieira, J.M.: Influence of epitaxial growth on superconducting properties of LFZ Bi–Sr–Ca–Cu–O fibres. 2. Magnetic susceptibility and transport properties. Physica C 289, 171–176 (1997)
Angurel, L.A., de la Fuente, G.F., Badía, A., Larrea, A., Diez, J.C., Peña, J.I., Martínez, E., Navarro, R.: Textured BSCCO superconductors obtained via laser induced directional solidification. In: Narlikar, A.V. (ed.) Studies of High Temperature Superconductors, vol. 21, pp. 1–31. World Scientific, Singapore (1997)
Larrea, A., Snoeck, E., Badía, A., de la Fuente, G.F., Navarro, R.: Microstructure, interfaces and magnetic behaviour of thick Ag/ BSCCO composite fibres. Physica C 220, 21–32 (1994)
Özkurt, B., Madre, M.A., Sotelo, A., Yakıncı, M.E., Özçelik, B.: Relationship between growth speed, microstructure, mechanical and electrical properties in Bi-2212/Ag textured composites. J. Supercond. Nov. Magn. 25, 799–804 (2012)
Sotelo, A., Mora, M., Madre, M.A., Diez, J.C., Angurel, L.A., de la Fuente, G.F.: Ag distribution in thick Bi-2212 floating zone textured rods. J. Eur. Ceram. Soc. 25, 2947–2950 (2005)
Mora, M., Sotelo, A., Amaveda, H., Madre, M.A., Diez, J.C., Angurel, L.A., de la Fuente, G.F.: Efecto de la adición de Ag en Bi-2212 texturado mediante laser. Bol. Soc. Esp. Ceram. 44, 199–203 (2005)
Angurel, L.A., Diez, J.C., de la Fuente, G.F.: Laser induced cylindrical zone melting of Bi2Sr2CaCu2O8+δ superconductors. Z. Anorg. Allg. Chem. 635, 1767–1772 (2009)
Larrea, A., de la Fuente, G.F., Merino, R., Orera, V.M.: ZrO2−Al2O3 melt growth eutectic plates produced by laser processing. J. Eur. Ceram. Soc. 22, 191–198 (2002)
Mora, M., Diez, J.C., López-Gascón, C.I., Martínez, E., de la Fuente, G.: Laser textured Bi-2212 in planar geometries. IEEE Trans. Appl. Supercond. 13, 3188–3191 (2003)
Mora, M., López-Gascón, C., Angurel, L.A., de la Fuente, G.F.: The influence of support temperature on Bi-2212 monoliths textured by diode laser zone melting. Supercond. Sci. Technol. 17, 1329–1334 (2004)
Mora, M., Gimeno, F., Angurel, L.A., de la Fuente, G.F.: Laser zone melted Bi2Sr2CaCu2O8+δ thick films on (100) MgO substrate. Supercond. Sci. Technol. 17, 1133–1138 (2004)
Lennikov, V.V., Kazin, P.E., Tretyakov, Yu.D., de la Fuente, G.F.: Laser zone melting and texture formation in MgO-doped BSCCO 2212. Z. Anorg. Allg. Chem. 630, 2337–2342 (2004)
de la Fuente, G.F., Diez, J.C., Angurel, L.A., Peña, J.I., Sotelo, A., Navarro, R.: Wavelength dependance of laser floating zone processed Bi–Sr–Ca–Cu–O superconductors. Adv. Mater. 7, 853 (1995)
Sotelo, A., Madre, M.A., Diez, J.C., Rasekh, S., Angurel, L.A., Martinez, E.: The influence of Pb and Ag doping on the J c(H,T) dependence and the mechanical properties of Bi-2212 textured rods. Supercond. Sci. Technol. 22, 034012 (2009)
Sotelo, A., Madre, M.A., Rasekh, Sh., Diez, J.C., Angurel, L.A.: Floating zone Ag doped (Bi1.6Pb0.4)Sr2CaCu2O8+δ textured rods. Adv. Appl. Ceram. 108, 285–289 (2009)
Madre, M.A., Amaveda, H., Mora, M., Sotelo, A., Angurel, L.A., Diez, J.C.: Ag doped (Bi1.6Pb0.4)Sr2CaCu2O8+δ textured rods. Bol. Soc. Esp. Ceram. 47, 148–152 (2008)
Lennikov, V.V., Pedra, J.M., Gómez, J.J., de la Fuente, G.F., Carda, J.B.: In-situ synthesis of composite MTiO3–Al2O3 coatings via laser zone melting. Solid State Sci. 9, 404–409 (2007)
de Francisco, I., Lennikov, V.V., Bea, J.A., Vegas, A., Carda, J.B., de la Fuente, G.F.: In-situ laser synthesis of rare earth aluminate coatings in the system Ln–Al–O (Ln=Y,Gd). Solid State Sci. 13, 1813–1819 (2011)
Angurel, L.A., Diez, J.C., de la Fuente, G.F., Gimeno, F., Lera, F., López-Gascón, C., Martínez, E., Mora, M., Navarro, R., Sotelo, A., Andrés, N., Recuero, S., Arroyo, M.P.: Laser technologies applied to the fabrication and characterization of bulk Bi-2212 superconducting materials for power applications. Phys. Status Solidi A 203, 2931–2937 (2006)
Carrasco, M.F., Silva, R.F., Vieira, J.M., Costa, F.M.: Electrical field freezing effect on laser floating zone (LFZ)-grown Bi2Sr2Ca2Cu4O11 superconducting fibres. Supercond. Sci. Technol. 17, 612–619 (2004)
Acknowledgements
The authors acknowledge the European Commission LIFE Program (LIFE11/ENV/ES 560 “CERAMGLASS”), the Spanish MINECO and European Commission FEDER Program (Projects MAT2008-00429 and MAT2011-22719), Universidad de Zaragoza (Project UZ2011-TEC-03 and Servicio General de Apoyo a la Investigación-SAI), as well as DGA for Groups T87 (Laser Applications Lab) and T13 (Applied Superconductivity).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Lennikov, V., Özkurt, B., Angurel, L.A. et al. Microstructure and Transport Properties of Bi-2212 Prepared by CO2 Laser Line Scanning. J Supercond Nov Magn 26, 947–952 (2013). https://doi.org/10.1007/s10948-012-1934-1
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10948-012-1934-1