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Magnetic Properties of Cu0.48Ni0.52Fe2O4 and Thermal Process of Precursor

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Abstract

The spinel Cu0.48Ni0.52Fe2O4 was synthesized by calcining Cu0.48Ni0.52Fe2(C2O4)3⋅5H2O above 300 °C in air for 1.5 h. The precursor and its calcined products were characterized by thermogravimetry and differential scanning calorimetry, FT-IR, X-ray powder diffraction, and vibrating sample magnetometer. The result showed that magnetic properties of Cu0.48Ni0.52Fe2O4 were influenced by calcination temperature, and Cu0.48Ni0.52Fe2O4 obtained at 600 °C had a specific saturation magnetization of 40.0 emu g−1. The thermal process of Cu0.48Ni0.52Fe2(C2O4)3⋅5H2O below 450 °C experienced two steps which involved, at first, the dehydration of the five crystal water molecules, then decomposition of Cu0.48Ni0.52Fe2(C2O4)3 into cubic Cu0.48Ni0.52Fe2O4 in air. In the DTG curve, two DTG peaks indicated that precursor experienced mass loss of two steps.

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References

  1. Wu, X.H., Zhou, K.W., Wu, W.W., Cui, X.M., Li, Y.N.: J. Therm. Anal. Calorim. doi:10.1007/s10973-011-2104-6

  2. Li, J.J., Yuan, H.M., Li, G.D., Liu, Y.J., Leng, J.S.: J. Magn. Magn. Mater. 322, 3396–3400 (2010)

    Article  ADS  Google Scholar 

  3. Wu, X.H., Wu, W.W., Zhou, K.W., Cui, X.M., Liao, S.: J. Therm. Anal. Calorim. doi:10.1007/s10973-011-1968-9

  4. Li, F.S., Wang, H.B., Wang, L., Wang, J.B.: J. Magn. Magn. Mater. 309, 295–299 (2007)

    Article  ADS  Google Scholar 

  5. Mendonça, E.C., Jesus, C.B.R., Folly, W.S.D., Meneses, C.T., Duque, J.G.S.: J. Supercond. Nov. Magn. doi:10.1007/s10948-012-1426-3

  6. Satyanarayana, L., Madhusudan Reddy, K., Manorama, S.V.: Mater. Chem. Phys. 82, 21–26 (2003)

    Article  Google Scholar 

  7. Zhang, K., Holloway, T., Pradhan, A.K.: J. Magn. Magn. Mater. 323, 1616–1622 (2011)

    Article  ADS  Google Scholar 

  8. Pervaiz, E., Gul, I.H., Anwar, H.: J. Supercond. Nov. Magn. doi:10.1007/s10948-012-1749-0

  9. Maqsood, A., Faraz, A.: J. Supercond. Nov. Magn. 25, 1025–1033 (2011)

    Article  Google Scholar 

  10. Anis-ur-Rehman, M., Ali Malik, M., Akram, M., Kamran, M., Khan, K., Maqsood, A.: J. Supercond. Nov. Magn. doi:10.1007/s10948-011-1244-z

  11. Khan, K., Maqsood, A.: Anis-ur-Rehman, M., Ali Malik, M., Akram, M.: J. Supercond. Nov. Magn. doi:10.1007/s10948-011-1247-9

  12. Huang, J.W., Su, P., Wu, W.W., Li, Y.N., Wu, X.H., Liao, S.: J. Supercond. Nov. Magn. 25, 1971–1977 (2012)

    Article  Google Scholar 

  13. Wu, W.W., Li, Y.N., Zhou, K.W., Wu, X.H., Liao, S., Wang, Q.: J. Therm. Anal. Calorim. doi:10.1007/s10973-011-2027-2

  14. Wu, W.W., Cai, J.C., Wu, X.H., Liao, S., Huang, A.G.: Powder Technol. 215–216, 200–205 (2012)

    Google Scholar 

  15. Harris, V.G.: IEEE Trans. Magn. 48, 1075–1104 (2012)

    Article  ADS  Google Scholar 

  16. Sivakumar, P., Ramesh, R., Ramanand, A., Ponnusamy, S., Muthamizhchelvan, C.: Mater. Lett. 65, 1438–1440 (2011)

    Article  Google Scholar 

  17. Salavati-Niasari, M., Davar, F., Mahmoudi, T.: Polyhedron 28, 1455–1458 (2009)

    Article  Google Scholar 

  18. Willard, M.A., Kurihara, L.K., Carpenter, E.E., Calvin, S., Harris, V.G.: Int. Mater. Rev. 49, 125–170 (2004)

    Article  Google Scholar 

  19. Satyanarayana, L., Madhusudan Reddy, K., Manorama, S.V.: Mater. Chem. Phys. 82, 21–26 (2003)

    Article  Google Scholar 

  20. Phadatare, M.R., Khot, V.M., Salunkhe, A.B., Thorat, N.D., Pawar, S.H.: J. Magn. Magn. Mater. 324, 770–772 (2012)

    Article  ADS  Google Scholar 

  21. Alarifi, A., Deraz, N.M., Shaban, S.: J. Alloys Compd. 486, 501–506 (2009)

    Article  Google Scholar 

  22. Poddar, A., Bhowmik, R.N., De, A., Sen, P.: J. Magn. Magn. Mater. 321, 2015–2020 (2009)

    Article  ADS  Google Scholar 

  23. Ziemniak, S.E., Anovitz, L.M., Castelli, R.A., Porter, W.D.: J. Phys. Chem. Solids 68, 10–21 (2007)

    Article  ADS  Google Scholar 

  24. Boonchom, B., Maensiri, S.: J. Therm. Anal. Calorim. 97, 879–884 (2009)

    Article  Google Scholar 

  25. Wu, W.W., Hou, S.Y., Liao, S., Wang, M.J., Wu, X.H., Li, S.S.: Chin. J. Nonferr. Met. 62, 39–42 (2010)

    Google Scholar 

  26. Chen, L.Y., Yuan, Y., Peng, H.R., Lu, X.W., Luo, Z.W.: Mater. Lett. 67, 311–314 (2012)

    Article  Google Scholar 

  27. Nawale, A.B., Kanhe, N.S., Patil, K.R., Bhoraskar, S.V., Mathe, V.L., Dasc, A.K.: J. Alloys Compd. 509, 4404–4413 (2011)

    Article  Google Scholar 

  28. Nikumbh, A.K., Nagawade, A.V., Gugale, G.S., Chaskar, M.G., Bakare, P.P.: J. Mater. Sci. 37, 637–647 (2002)

    Article  ADS  Google Scholar 

  29. Kenfack, F., Langbein, H.: J. Mater. Sci. 41, 3683–3693 (2006)

    Article  ADS  Google Scholar 

  30. Xin, X.Q., Zheng, L.M.: J. Solid State Chem. 106, 451–460 (1993)

    Article  ADS  Google Scholar 

  31. Berbenni, V., Milanese, C., Bruni, G., Girella, A., Marini, A.: Thermochim. Acta 521, 218–223 (2011)

    Article  Google Scholar 

  32. Huang, J.W., Su, P., Wu, W.W., Li, Y.N., Wu, X.H., Tao, L.: J. Therm. Anal. Calorim. doi:10.1007/s10973-012-2524-y

  33. Wu, X.H., Wu, W.W., Cui, X.M., Liao, S.: J. Therm. Anal. Calorim. 107, 625–632 (2012)

    Article  Google Scholar 

Download references

Acknowledgements

This study was financially supported by the National Nature Science Foundation of China (Grant No. 21161002) and the Guangxi Nature Science Foundation of China (Grant No. 2011GXNSFA018036).

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Authors and Affiliations

  1. School of Chemistry and Chemical Engineering, Guangxi University, Nanning, 530004, P.R. China

    Yongni Li, Xuehang Wu, Wenwei Wu, Kaituo Wang & Sen Liao

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  1. Yongni Li
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  2. Xuehang Wu
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  3. Wenwei Wu
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  5. Sen Liao
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Correspondence to Wenwei Wu.

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Li, Y., Wu, X., Wu, W. et al. Magnetic Properties of Cu0.48Ni0.52Fe2O4 and Thermal Process of Precursor. J Supercond Nov Magn 26, 2153–2158 (2013). https://doi.org/10.1007/s10948-012-1814-8

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  • DOI: https://doi.org/10.1007/s10948-012-1814-8

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