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Study of poly(1-trimethylsilyl-1-propyne) aging by gas chromatography

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Abstract

The possibilities of gas chromatography for determination of physicochemical properties of the surface are demonstrated. Changes in the surface properties of poly(1-trimethylsilyl-1-propyne) (PTMSP) with time were investigated. It was found that with the lapse of time the sorption-desorption processes proceed mainly in mesopores due to decreasing the polymer micropore volume. The formation of a chemically more uniform surface strongly increases the symmetry of chromatographic peaks and the column efficiency.

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Authors and Affiliations

  1. G. K. Boreskov Institute of Catalysis, Siberian Division, Russian Academy of Sciences, Novosibirsk, Russia

    V. Yu. Belotserkovskaya & E. Yu. Yakovleva

Authors
  1. V. Yu. Belotserkovskaya
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  2. E. Yu. Yakovleva
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Correspondence to V. Yu. Belotserkovskaya.

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Original Russian Text Copyright © 2010 by V. Yu. Belotserkovskaya and E. Yu. Yakovleva

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Translated from Zhurnal Strukturnoi Khimii, Vol. 51, Supplement, pp. S162–S166, 2010.

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Belotserkovskaya, V.Y., Yakovleva, E.Y. Study of poly(1-trimethylsilyl-1-propyne) aging by gas chromatography. J Struct Chem 51 (Suppl 1), 159–163 (2010). https://doi.org/10.1007/s10947-010-0206-9

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  • DOI: https://doi.org/10.1007/s10947-010-0206-9

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