Skip to main content
SpringerLink
Log in

Synthesis and X-ray structural investigation of the hafnium(IV) complex with pivalyltrifluoroacetone

  • Published:
Journal of Structural Chemistry Aims and scope Submit manuscript

Abstract

Synthesis and X-ray structural investigation of hafnium(IV) pivalyltrifluoroacetonate were carried out. Crystallographic data for C32H40F12HfO8 are: a = 19.913(3) Å, b = 11.8764(18) Å, c = 16.530(3) Å; β = 95.538(2)°; space group Cc, Z = 4, d calc = 1.637 g/cm3, R = 0.035. The structure is molecular; it is composed of discrete mononuclear Hf(ptac)4 molecules connected with each other by van der Waals interactions. The hafnium atom coordinates eight oxygen atoms belonging to four β-diketonate ligands; Hf-O distances are within the range 2.133–2.199 Å.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. S. V. Volkov, L. E. Miropolskaya, L. A. Melnikova, et al., Ukr. Khim. Zh., 49, No. 7, 682–687 (1983).

    CAS  Google Scholar 

  2. V. Ya. Mishin, C. M. Solov’yov, P. P. Chinenov, et al., Radiokhimiya, No. 3, 354–361 (1985).

  3. M. Balog, M. Schiebe, M. Michman, et al., Thin Solid Films, 41, No. 3, 247–259 (1977).

    Article  CAS  Google Scholar 

  4. K. V. Zherikova, N. B. Morozova, N. V. Kuratieva, et al., Zh. Strukt. Khim., 46, No. 6, 1075–1082 (2005).

    Google Scholar 

  5. K. V. Zherikova, N. B. Morozova, I. A. Baidina, et al., ibid., 47, No. 1, 87–90 (2006).

    Google Scholar 

  6. G. M. Sheldrick, SHELX-97. Release 97-1, Univ. Göttingen, Germany (1997).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk

    K. V. Zherikova, N. B. Morozova, E. V. Peresypkina, I. A. Baidina & I. K. Igumenov

Authors
  1. K. V. Zherikova
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. N. B. Morozova
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. E. V. Peresypkina
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. I. A. Baidina
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. I. K. Igumenov
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Original Russian Text Copyright © 2006 by K. V. Zherikova, N. B. Morozova, E. V. Peresypkina, I. A. Baidina, and I. K. Igumenov

__________

Translated from Zhurnal Strukturnoi Khimii, Vol. 47, No. 3, pp. 581–584, May–June, 2006.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Zherikova, K.V., Morozova, N.B., Peresypkina, E.V. et al. Synthesis and X-ray structural investigation of the hafnium(IV) complex with pivalyltrifluoroacetone. J Struct Chem 47, 570–574 (2006). https://doi.org/10.1007/s10947-006-0339-z

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10947-006-0339-z

Keywords

Search

Navigation