Abstract
The [Ir(NH3)5Cl]2[OsCl6]Cl2 binary complex salt has been prepared, and its structure was investigated by single crystal X-ray diffraction. Crystal data: a = 11.1901(13) Å, b = 7.9138(13) Å, c = 13.4384(18) Å; β = 99.640(3)°, V = 1190.0(2), space group C2/m, Z = 2, FW = 1099.47, d x = 3.068 g/cm3. Thermolysis products of [Ir(NH3)5Cl]2[OsCl6]Cl2, [Ir(NH3)5Cl][OsBr6], (NH4)2[OsCl6]x[IrCl6]1−x , and K2[OsCl6]x[IrCl6]1−x were studied by X-ray phase analysis; the unit cell parameters were refined, and the dependence of volume per atom (V/Z) on the composition of the Ir Os1−x solid solution has been plotted.
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Translated from Zhurnal Strukturnoi Khimii, Vol. 46, No. 6, pp.1095–1102, November–December, 2005.
Original Russian Text Copyright © 2005 by I. V. Korolkov, S. A. Gromilov, K. V. Yusenko, I. A. Baidina, and S. V. Korenev
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Korolkov, I.V., Gromilov, S.A., Yusenko, K.V. et al. Crystal structure of [Ir(NH3)5Cl]2[OsCl6]Cl2. Crystal-chemical analysis of the iridium-osmium system. J Struct Chem 46, 1052–1059 (2005). https://doi.org/10.1007/s10947-006-0241-8
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DOI: https://doi.org/10.1007/s10947-006-0241-8