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Synthesis and crystal structure of EnH2[IrCl6]

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Abstract

The preparation of EnH2[IrCl6] is described. Crystal data for C2H10Cl6IrN2 are: a = 6.8972(11) Å, b = 6.9435(16) Å, c = 7.3354(11) Å; α = 88.269(3)°, β = 65.495(2)°, γ = 60.305(2)°, V = 270.76(9) Å3, space group P1, Z = 1, d calc = 2.864 g/cm3. Crystal chemical analysis of the general motif of the structure was performed by the translation sublattice identification technique. It has been found that complex anions [IrCl6]2− follow the nodes of a rather regular rhombohedral subcell with the parameters a c = 7.1 Å, αc = 64°.

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk

    I. A. Baidina, S. V. Korenev, E. V. Makotchenko & S.A. Gromilov

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  1. I. A. Baidina
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  2. S. V. Korenev
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  3. E. V. Makotchenko
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  4. S.A. Gromilov
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Original Russian Text Copyright © 2005 by I. A. Baidina, S. V. Korenev, E. V. Makotchenko, and S.A. Gromilov

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Translated from Zhurnal Strukturnoi Khimii, Vol. 46, No. 4, pp.747–752, July–August, 2005.

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Baidina, I.A., Korenev, S.V., Makotchenko, E.V. et al. Synthesis and crystal structure of EnH2[IrCl6]. J Struct Chem 46, 725–731 (2005). https://doi.org/10.1007/s10947-006-0192-0

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  • DOI: https://doi.org/10.1007/s10947-006-0192-0

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