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Adsorption behavior of amino functionalized MCM-41 on chlorogenic acid from Eucommia ulmoides leaves

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Abstract

In this study, an amino-functionalized MCM-41 mesoporous material was prepared via hydrothermal method for the adsorption of chlorogenic acid from Eucommia ulmoides leaf extracts. The as prepared NH2-MCM-41 was characterized by X-ray diffraction, FT-IR spectroscopy and N2 adsorption–desorption isotherms. The results show that have good mesoporous structure. The batch experiments showed that adsorption process was more in line with the pseudo-second order kinetic model, which indicated the chemisorption played an important role in the adsorption process; Isothermal adsorption results showed that the adsorption of chlorogenic acid by NH2-MCM-41 was more consistent with Langmuir model, indicating that multilayer adsorption process occurred. Thermodynamic analyses demonstrated that the chlorogenic acid adsorption on NH2-MCM-41 abided by a spontaneous and exothermic procedure with entropy decreased. The purity of chlorogenic acid could be increased from 17.36 to 85.60% under the optimal conditions t = 9 h, temperature = 333 K, pH 6. These results indicated that NH2-MCM-41 is a promising adsorbent for the separation and purification of chlorogenic acid from Eucommia ulmoides leaf extracts.

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Acknowledgements

We are thankful to the reviewers for their valuable comments to improve the manuscript. This research project was financially supported by the National Natural Sciences Foundation of China (No. 32060326).

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Authors and Affiliations

  1. Key Laboratory of Hunan Forest Products and Chemical Industry Engineering, Jishou University, Zhangjiajie, 427000, Hunan Province, People’s Republic of China

    Xiaofei Xu, Ke Song, Jie Guo, Shima Liu, Xianwu Zhou & Jian He

  2. College of Chemistry and Chemical Engineering, Jishou University, Jishou, 416000, Hunan Province, People’s Republic of China

    Ke Song, Jie Guo, Shima Liu, Xianwu Zhou & Jian He

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  1. Xiaofei Xu
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Contributions

XX is the first author of this study. KS is the corresponding author of this study, and he is supervisor of this project. XX and KS contributed to the study conception and design. JG and SL prepared Figs. 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11 and 12. Material preparation, data collection and analysis were performed by XX, KS, JH and XZ. The first draft of the manuscript was written by XX and all authors commented on previous versions of the manuscript. All authors read and approved the final manuscript.

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Correspondence to Ke Song.

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Xu, X., Song, K., Guo, J. et al. Adsorption behavior of amino functionalized MCM-41 on chlorogenic acid from Eucommia ulmoides leaves. J Porous Mater 30, 71–81 (2023). https://doi.org/10.1007/s10934-022-01323-0

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