Abstract
Carbon-based foams have attracted significant attention because of their unique physical properties, such as low density, fire resistance, and low thermal conductivity. Biomass is a qualified carbon raw material used for the preparation of valuable carbon materials because it is available in high quality and huge quantity and it is an environmentally friendly renewable resource. In this work, carbon foams were developed from a wood foam precursor, by pyrolysis. The characteristics of these foams were studied in order to verify their possible use in thermal insulation. Carbon foams were produced with different wood flour particle sizes and densities. The main results indicate that the wood foam density has significant effect on the carbon foam contraction after pyrolysis and all samples presented a structure predominantly composed of carbon with higher thermal stability than the levels presented by wood foams.
Similar content being viewed by others
References
Z.Y. Wu, C. Li, H.W. Liang, J.F. Chen, S.H. Yu, Ultralight, flexible, and fire-resistant carbon nanofiber aerogels from bacterial cellulose. Angew. Chem.-Int. Ed. 52, 2925–2929 (2013). https://doi.org/10.1002/anie.201209676
M. Inagaki, J. Qiu, Q. Guo, Carbon foam: preparation and application. Carbon 87, 128–152 (2015)
L. Salvo, G. Martin, M. Suard, A. Marmottant, R. Dendievel, J.J. Blandin, Processing and structures of solids foams. C. R. Phys. 15, 662–673 (2014)
M. Bakierska, M. Molenda, D. Majda, R. Dziembaj, Functional starch based carbon aerogels for energy applications. Proced. Eng. 98, 14–19 (2014). https://doi.org/10.1016/j.proeng.2014.12.481
O. Aaltonen, O. Jauhiainen, The preparation of lignocellulosic aerogels from ionic liquid solutions. Carbohydr. Polym. 75, 125–129 (2009). https://doi.org/10.1016/j.carbpol.2008.07.008
X. Chang, D. Chen, X. Jiao, Starch-derived carbon aerogels with high-performance for sorption of cationic dyes. Polymer (Guildf) 51, 3801–3807 (2010). https://doi.org/10.1016/j.polymer.2010.06.018
B. Grzyb, C. Hildenbrand, S. Berthon-Fabry, D. Bégian, N. Job, A. Rigacci, P. Achard, Functionalisation and chemical characterisation of cellulose-derived carbon aerogels. Carbon 48, 2297–2307 (2010). https://doi.org/10.1016/j.carbon.2010.03.005
Y. Yuan, Y. Ding, C. Wang, F. Xu, Z. Lin, Y. Qin, Y. Li, M. Yang, X. He, Q. Peng, Y. Li, Multifuncional stiff carbon foam derived from bread. ACS Appl. Mater. Interfaces 8, 16852–16861 (2016). https://doi.org/10.1021/acsami.6b03985
J. Zhang, B. Li, L. Li, A. Wang, Ultralight, compressible and multifuncional carbon aerogels based on natural tubular cellulose. J. Mater. Chem. A 4, 2069–2074 (2016). https://doi.org/10.1039/C5TA10001A
H. Bi, Z. Yin, X. Cao, X. Xie, C. Tan, X. Huang, B. Chen, F. Chen, Q. Yang, X. Bu, X. Lu, L. Sun, H. Zhang, Carbon fiber aerogel Made from raw cotton: a novel, efficient and recyclable sorbent for oils and organic solvents. Adv. Mater. 25(41), 5916–5921 (2013). https://doi.org/10.1002/adma.201302435
W. Chen, Q. Zhang, K. Uetani, Q. Li, P. Lu, J. Cao, Q. Wang, Y. Liu, J. Li, Z. Quan, Y. Zhang, S. Wang, Z. Meng, H. Hu, Sustainable carbon aerogels derived from nanofi brillated cellulose as high-performance absorption materials. Adv. Mater. 3(10), 1600004 (2016). https://doi.org/10.1002/admi.201600004
L.K. Lazzari, M.V.G. Zimmermann, D. Perondi, V.B. Zampieri, A.J. Zattera, R.M.C. Santana, Production of carbon foams from rice husk. Mater. Res. 22, 1–8 (2019)
L. Zhu, Y. Wang, Y. Wang, L. You, X. Shen, S. Li, An environmentally friendly carbon aerogels derived from waste pomelo peels for the removal of organic pollutants/oils. Microporous Mesoporous Mater. 241, 285–292 (2017). https://doi.org/10.1016/j.micromeso.2016.12.033
M. Guerrero, M.P. Ruiz, M.U. Alzueta, R. Bilbao, A. Millera, Pyrolysis of eucalyptus at different heating rates: studies of char characterization and oxidative reactivity. J. Anal. Appl. Pyrolysis 74, 307–314 (2005). https://doi.org/10.1016/j.jaap.2004.12.008
D. Savova, E. Apak, E. Ekinci, F. Yardim, N. Petrov, T. Budinova, M. Razvigorova, V. Minkova, Biomass conversion to carbon adsorbents and gas. Biomass Bioenergy 21, 133–142 (2001). https://doi.org/10.1016/S0961-9534(01)00027-7
P. Basu, Biomass gaseification and pyrolysis (Academic Press, Boston, 2010)
D. Perondi, P. Poletto, D. Restelatto, C. Manera, J.P. Silva, J. Junges, G.C. Collazzo, A. Dettmer, M. Godinho, A.C.F. Vilela, Steam gasification of poultry litter biochar for bio-syngas production. Environ. Prot. Process Saf. (2017). https://doi.org/10.1016/j.psep.2017.04.029
Acknowledgements
The authors would like to express their gratitude to the National Council of Technological and Scientific Development (CNPq) and the Secretariat of Science, Innovation and Development of Rio Grande do Sul (SCT/RS) for the financial support and the LPOL and LBIO of the Universidade de Caxias do Sul (UCS).
Author information
Authors and Affiliations
Corresponding author
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Zimmermann, M.V.G., Perondi, D., Lazzari, L.K. et al. Carbon foam production by biomass pyrolysis. J Porous Mater 27, 1119–1125 (2020). https://doi.org/10.1007/s10934-020-00888-y
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10934-020-00888-y