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Evaluation and improvement of the NH3 adsorption capacity of Engelhard titanosilicate (ETS) materials

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Abstract

The purpose of this study was to evaluate and improve the ammonia adsorption performance of Na/K-ETS-10 material using an ion exchange method followed by calcination process to replace its Na+/K+ ions with H+ ions. The Na/K-ETS-10 starting material and the obtained H-type ETS-10 sample were investigated by temperature-programmed desorption of NH3, NH3 breakthrough test and NH3 absorption isotherm (10–30 °C). When the modification method is used, not only the H-type ETS-10 sample showed the highest NH3 adsorption capacity of 6.2 mol/kg at 10 °C, but also there is an overall remarkable improvement in the NH3 breakthrough time in comparison with original one.

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Acknowledgements

This work was supported by the R&D Center for Eco-Innovation R&D Project (2014000150007) funded by Korea Environmental Industry & Technology Institute.

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Authors and Affiliations

  1. E & Chem Soluton Corp., Energy & Environment R&D Center, 200, Gasan-ri, Gasan-myeon, Pocheon-si, Gyeonggi-do, South Korea

    Shin Dong Kim

  2. Department of Chemical and Biochemical Engineering, Dongguk University, Pil-dong 3-ga, Jung-gu, Seoul, South Korea

    Edoardo Magnone & Jung Hoon Park

  3. Department of Urban Environmental Engineering, Kyungnam University, #7 Kyungnam Daehak-Ro, Changwon, Gyeongnam, 51767, South Korea

    Jae Yong Ryu

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  1. Shin Dong Kim
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  2. Edoardo Magnone
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Correspondence to Edoardo Magnone.

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Kim, S.D., Magnone, E., Park, J.H. et al. Evaluation and improvement of the NH3 adsorption capacity of Engelhard titanosilicate (ETS) materials. J Porous Mater 25, 297–302 (2018). https://doi.org/10.1007/s10934-017-0442-x

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