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Catalytic performance study of nano-cobalt: a catalyst for complement to the Heck coupling reaction

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Abstract

Easy and convenient synthesis of crystalline cobalt-nanoparticles by a seed mediated growth method with cetyltrimethylammonium bromide used as surfactant, KI as an additive and ascorbic acid as reductant; this synthesized Co-nanoparticle are characterized by XRD and TEM analysis, and is used as a coupling catalyst for alkenes with aryl halides in the presence of a base. The yield of the catalyzed product and the method has many advantages such as affordable and ligand-free condition. Hence overall reaction is augmented to the Heck coupling reaction.

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Funding

The funding was provided by University Grants Commission (Grant No. UGC:MRP(S)-0098/12-13/KAKU023/UGC-SWRO/dated:01-10-2013).

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Authors and Affiliations

  1. Department of Chemistry, Sahyadri Science College, Shivamogga, Karnataka, 577203, India

    K. S. Jithendra Kumara, G. Krishnamurthy & N. Sunil Kumar

  2. Department of Industrial Chemistry, Kuvempu University, Shivamogga, Karnataka, India

    B. E. Kumara Swamy & Mohan Kumar

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  1. K. S. Jithendra Kumara
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  2. G. Krishnamurthy
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  3. B. E. Kumara Swamy
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Correspondence to G. Krishnamurthy.

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Jithendra Kumara, K.S., Krishnamurthy, G., Kumara Swamy, B.E. et al. Catalytic performance study of nano-cobalt: a catalyst for complement to the Heck coupling reaction. J Porous Mater 24, 1095–1103 (2017). https://doi.org/10.1007/s10934-016-0350-5

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