Abstract
A new composite (CCSs/MOFs) of carboxyl-rich carbon spheres (CCSs) and copper-based metal–organic frameworks (MOFs) was for the first time prepared. The CCSs/MOFs composite was synthesized by the coordinated growth of high surface area and porous MOFs, [Cu3(BTC)2(H2O)]n (HKUST-1), on the surface of the functionalized CCSs obtained through a one-step hydrothermal carbonization of glucose with acrylic acid at 180 °C for 24 h. The resulting composites showed a core/shell structure with a tunable diameter arranging from 0.6 to 3.0 μm, and possessed high specific surface area of 495 m2/g and nanoporous structures derived from MOFs. Further, the catalytic oxidation of benzylic alcohol to benzaldehyde as its application was studied.
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Acknowledgments
The authors wish to thank the National Natural Science Foundation of China (Nos. 21171081/B0103 and 20971062/B010303), Natural Science Foundation of Liaoning Province (2013020085 and 201202093), Shenyang Science and Technology Plan Project (F13-289-1-00 and F14-231-1-10) for funding.
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Ge, C., Du, Y., Wang, R. et al. A facile strategy to fabricate carboxyl-rich carbon spheres with copper-based MOFs through coordination bond. J Porous Mater 23, 1537–1545 (2016). https://doi.org/10.1007/s10934-016-0214-z
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DOI: https://doi.org/10.1007/s10934-016-0214-z