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Highly active palladium nanoparticles immobilized on knitting microporous organic polymers as efficient catalysts for Suzuki–Miyaura cross-coupling reaction

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Abstract

By encaging the Pd nanoparticles in the interior space of the hypercrosslinked microporous organic polymer, we successfully prepared a novel eco-friendly heterogeneous catalyst for Suzuki cross-coupling reaction. The catalyst afforded fast conversions for the Suzuki cross-coupling reaction even at a loading of 0.05 mmol% Pd, and the turnover frequency for the reaction could be up to 61,353 h−1. Furthermore, this catalyst is stable enough to be reused more than five times with no appreciable activity decrease. This work provides a method for fabricating highly active microporous organic polymer encapsulated Pd catalysts for Suzuki cross-coupling reaction and resolve the problem of industrialization in traditional active carbon catalysts.

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Acknowledgments

We acknowledge the spectroscopic analysis conducted at the Analytical and Testing Centre, Huazhong University of Science and Technology, Wuhan, China. This work was financially supported by National Natural Science Foundation of China (No. 21473064/21474033/51273074), the Natural Science Foundation of Hubei Province of China (2015CFB313), and the Fundamental Research Funds for the Central Universities (2015QN183, 2015QN181).

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Authors and Affiliations

  1. Key Laboratory for Large-Format Battery Materials and System, Ministry of Education, School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Luoyu Road No. 1037, Wuhan, 430074, China

    Kunpeng Song, Peng Liu, Jingyu Wang & Tao Li

  2. Institute of Polymer Science and Engineering, School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Luoyu Road No. 1037, Wuhan, 430074, China

    Bien Tan

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  1. Kunpeng Song
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  2. Peng Liu
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  3. Jingyu Wang
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  4. Bien Tan
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  5. Tao Li
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Correspondence to Bien Tan or Tao Li.

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Song, K., Liu, P., Wang, J. et al. Highly active palladium nanoparticles immobilized on knitting microporous organic polymers as efficient catalysts for Suzuki–Miyaura cross-coupling reaction. J Porous Mater 23, 725–731 (2016). https://doi.org/10.1007/s10934-016-0127-x

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