Abstract
Ag-doped ZnO inverse opal structures were prepared by electrochemical deposition using polystyrene colloidal crystal templates. The Ag-doped ZnO structures had granular morphology, but this morphology became smooth using a three-dimensional (3D) porous template in the same electrolyte. The Ag-doped ZnO structures were characterized using energy-dispersive X-ray spectroscopy, and the lattice parameter was found to increase compared with undoped ZnO as verified by X-ray diffraction. Strong reflection photonic stop bands centered at 495 and 681 nm were detected from inverse opals templated from microspheres having diameters of 285 and 370 nm. The filling ratio of Ag-doped ZnO inverse opals using the template was lower than that of the uniform film growth of undoped ZnO. Moreover, photochemical cell analysis revealed that doped ZnO inverse opals with n- and p-type conductivities were successfully formed using electrolytes with different silver ion concentrations.
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Acknowledgments
This work was supported by National Science Foundation of China under grants of Nos. 91123025, 50902008, 60825407, 61077044 and the National Basic Research Program of China Nos. 2011CB932700, 2011CB932703, the Fundamental Research Funds for the Central Universities Nos. 2011JBM297, 2010JBZ006.
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Fu, M., Li, S., Yao, J. et al. Preparation and characterization of electrodeposited Ag-doped ZnO inverse opals with a smooth surface. J Porous Mater 20, 1485–1489 (2013). https://doi.org/10.1007/s10934-013-9734-y
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DOI: https://doi.org/10.1007/s10934-013-9734-y