Abstract
The nickel-based metal–organic framework (MOF), referred to as CPO-27-Ni, has been recently proposed as adsorbent for the storage of gaseous fuels. Once an adsorbent has been identified, shaping is an essential step for its industrial implementation. According to that, a study on the influence of shaping on physical–chemical characteristics and CH4 storage properties of CPO-27-Ni was performed. XRD analysis evidenced that tableting till 0.1 GPa slightly modify CPO-27-Ni crystal structure. As a matter of fact, the specific surface area of the compound after tableting was just a little bit lower with respect to the as-synthesised one. Moreover, the tableted MOF exhibited a CH4 specific capacity close to the as-synthesised powder and comparable to medium performing MOFs.
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Acknowledgments
The authors thank Ms. Monica Catrullo, Mr. Carlo E. Barabino, Mr. Angelo Vignati and Mr. Giuseppe Botti for their technical assistance. This work was supported by EU FP6 NMP STREP “MOFCAT” (033335).
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An erratum to this article can be found online at http://dx.doi.org/10.1007/s10934-013-9684-4.
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Tagliabue, M., Rizzo, C., Millini, R. et al. Methane storage on CPO-27-Ni pellets. J Porous Mater 18, 289–296 (2011). https://doi.org/10.1007/s10934-010-9378-0
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DOI: https://doi.org/10.1007/s10934-010-9378-0